Printer Friendly

Selection of the best process stream to remove [Ca.sup.2+] ion using electrodialysis from sugar solution.

1. Introduction

In cane based sugar industry the sugar concentration in the extracted juice after lime (CaO + [H.sub.2]O) treatment and color removal (clarification step) usually reaches around 5% (mass basis). This stream subsequently enters into series of evaporators to get concentrated. Presence of excess calcium in the postfloculation and precipitation stage of clarified sugar juice creates series of nuisance [1] to the subsequent stages (evaporators, etc.) in sugar industries affecting product quality as follows.

(1) Scale formation in the evaporators.

(2) Improper crystallization.

(3) Molasses percentage may increase due to inversion of sugar in alkaline medium.

(4) Storage is hampered because of hygroscopic nature of these metals ions.

(5) Excess calcium is not hygienic as well.

Therefore, removal of it at appropriate stage would drastically reduce operation and maintenance (evaporator scaling) cost and improve product quality. Electrodialysis (ED) was chosen to remove Ca[Cl.sub.2] from its sugar solution. ED was applied earlier in sugar industry to recover tartrate and malate from grape sugar [2] and in demineralisation of beet sugar syrup, juice, and molasses [3, 4]. The technological difficulties arise due to fouling of ion exchange membranes mainly due to deposition of organic/inorganic molecules (sugars, proteins, [Ca.sup.2+], [Mg.sup.2+], etc.). With increase in solution viscosity fouling becomes even severe and affects the current efficiency and ion removal rate. The concentration polarization occurs around membrane surface leading to increase in ion resistance, and this is minimized with the help of suitable spacer design, temperature, pH, and flow rates applied [5-11].

A batch recirculation ED process having a single diluate channel was performed to remove the Ca[Cl.sub.2] from sugar solution. As reported elsewhere [5] during ED process concentration polarization arises around the membrane which limits the net salt transport. This issue was taken up and sorted out using different combination of anolyte and catholyte streams. Different electrolyte streams (NaOH, acetic acid-[Na.sub.2]EDTA mixture) were selected as catholyte keeping anolyte as HCl solution.

In a batch mode electrodialysis with continuous recirculation of feed stream, properties like electrolyte concentration of diluate (feed tank), concentration profiles around that membrane, and all physical properties of the solution change with time. The effect of all these parameters is reflected in ion removal rate and current density of the ED cell. Therefore, an unsteady state model that can closely predict the ion removal rate and overall current density will be quite relevant in application point of view. Nernst-Planck equation (purely based on first principles) and irreversible thermodynamics were used to estimate current density and ion concentration [12].

2. Materials and Methods

2.1. Equipment

2.1.1. Electrodialysis Setup. The experimental setup used for ED application is shown in the Figure 1 [13]. The ED cell and setup were from Berghof, Germany. The electric field was applied across the cell stack by a built-in D.C. source. Voltage and current between the two electrodes were measured by a built-in digital voltmeter and ammeter, respectively. The ED cell consisted of three compartments as shown in the figure. Membranes used were obtained from Permionics, Gujarat, and cross-linked styrene and di-vinyl benzene gel was used as base material. Cation exchange membrane (CEM) separates the cathode compartment and anion exchange membrane (AEM) separates the anode compartment from the feed chamber. The effective membrane area for the cell, [A.sub.m], was 0.0037 [m.sup.2] and the feed compartment thickness, h, was 0.002 m.

2.1.2. Power Supply. The power supply was provided through a voltage stabilizer of 110/220 V A.C. with 50-80 Hz frequency. The same gave an output voltage 0-49.9 V DC and current 0-3.99 A. Four centrifugal pumps were inbuilt with the system for pumping the solution.

2.1.3. Conductivity Meter. Solution conductivity was noted at regular interval through an offline conductivity meter (Systronics India) of 200 mMho with 5 ranges (accuracy [+ or -] 1%).

2.1.4. ED Cell Compartments and Solutions Used. 1000 mL solutions of each stream (feed, catholyte, and anolyte) were taken in three chambers Figure 1), respectively. Each chamber was connected with the respective three compartments of the ED cell through flexi tubing. Solutions were circulated at a constant rate by three centrifugal pumps and the solution flow rates were measured using rotameters connected to each stream. Table 1 indicates membrane parameters obtained from Permionics India Ltd. The composition and flow rates of three streams used are reported in Table 2.

Synthetic solution of 5% sugar and calcium chloride (Ca[Cl.sub.2]) was prepared in distilled water. The concentration of sugar was kept unchanged but that of Ca[Cl.sub.2] was varied. The synthetic solution having Ca[Cl.sub.2] with initial concentrations of 25 mol x [m.sup.3] and 50 mol x [m.sup.3] were used in the diluate channel of ED cell. Dilute solution of HCl (100 mol x [m.sup.3]) was used as anolyte in all experiments while NaOH (100 mol x [m.sup.3]) was used as catholyte in experiment 1 and equimolar mixtures of acetic acid (AA) and [Na.sub.2]EDTA (25 mol x [m.sup.3] and 50 mol x [m.sup.3]) were, respectively, used as catholyte in experiments 2 and 3 (Table 2).

2.1.5. Viscosity Measurement. Viscosity measurement was carried out using Ubbelhood viscometer always fitted in a constant temperature bath to nullify any temperature effect on capillary flow.

2.2. Procedure. The chambers of the ED cell and membranes were washed thoroughly before each experiment was carried out. Initially, the feed solution containing 5% sugar and Ca[Cl.sub.2] was used and was circulated at a constant rate (130 mL/min) through the feed compartment. The feed solution, anolyte, and catholyte were continuously recycled through the ED cell and that caused a continuous change in salt concentration of feed solution. The concentration was measured at regular intervals. For a fixed applied voltage (V), variation of current ("I" through the membrane stack) and concentration of salt ([Ca.sup.2+] ions) was estimated from conductivity measurement and using standard calibration chart (mass concentration versus conductance) and was recorded with time (t).

ED cell was dismantled; membranes were taken out, checked visually to find any deposition over the surfaces after each experiment. Membranes were then washed with distilled water and oven dried at 100[degrees]C for 24 hours and weighed to find any gain or loss in mass of membrane.

3. Modeling of Ion Transport

Current density and limiting current density (LCD) of an ED cell is a function of a series of parameters, for example, physical (cell geometry, flow dynamics, spacer spacing, solution density, and viscosity) and chemical (ion concentration, transport number, and diffusivity) for a given set of membrane pairs. Precise estimate of these parameters and application of Nernst-Planck equation (assuming zero ion concentration on the membrane surface) would give a theoretical estimate of LCD which can also be determined experimentally from plot of I versus V characteristics of the electrolyte in the ED cell [7, 9].

3.1. Determination of Bulk Concentration of Diluate Compartment. Concentration of ions was obtained through unsteady mass balance over diluate, catholyte, and anolyte compartments. The following assumptions were made [18].

(i) The ED cell and the feed tank are approximated to be a perfectly mixed flow reactor.

(ii) Back diffusion of ions was ignored.

(iii) Electroneutrality condition is always maintained.

The mass balance equation of diluate compartment in the ED cell can be expressed as

[V.sub.dilC] d[C.sup.dil]/dt = [Q.sup.dil] ([C.sup.dil.sub.T] - [C.sup.dil]) - [eta]i[A.sub.m]/zF, (1)

where [V.sub.dilC] is the volume of the diluate compartment ([m.sup.3]) and t is time (s), [C.sup.dil.ub.T] and [C.sup.dil] represent diluate concentrations leaving feed tank and leaving cell compartment (mol x [m.sup.3]), [Q.sup.dil] is the diluate volumetric flow rate ([m.sup.3]/s), [eta] is the current efficiency, i is the current density (A x [m.sup.-2]), and [A.sub.m] is the effective membrane area ([m.sup.2]).

[eta] can be obtained from the following equation 18,19]:

[eta] = [t.sub.+,CEM] + [t.sub.-,AEM] - 1, (2)

where [t.sub.+,CEM] is the transport number of cation in cation exchange membranes and [t.sub.-,AEM] is the transport number of anion in anion exchange membrane.

Similarly, unsteady state mass balance around feed tank can be written as

d([V.sub.T][C.sup.dil.sub.T])/dT = [Q.sup.dil] ([C.sup.dil] - [C.sup.dil.sub.T]), (3)

where [V.sub.T] is the volume of feed tank ([m.sup.3]). During electrodialysis water transport occurs across the membranes due to electroosmosis and osmosis [19]. Volume change (due to water transport) was ignored as there was no net volume change noted experimentally.

3.2. Determination of the Current Density

3.2.1. Overall Flux Equation. A pictorial representation of different concentration profiles possibly developed around the membrane is described in Figure 2. The flux of ions passing through the membrane can be expressed by generalized Nernst Planck equation as [7]

[N.sub.j] = -[D.sub.j] [partial derivative][C.sub.j]/[partial derivative]x - [z.sub.j][C.sub.j]F[D.sub.j]/RT [partial derivative][psi]/[partial derivative]x, (4)

where x is the distance measured from boundary layer in contact with the bulk solution in diluate channel towards the membrane, [D.sub.j] is the diffusivity of ion ([m.sup.2] x [s.sup.-1]), [C.sub.j] is the concentration of ion j (mol x [m.sup.3]), R is the universal gas constant (8.314 J x [mol.sup.-1] x [k.sup.-1]), T is the temperature (K), [z.sub.j] is the charge of diffusing species j, and [partial derivative][psi]/[partial derivative]x is the potential gradient (V x [m.sup.-1]) and F is the Faraday constant (C x [geqv.sup.-1]).

The total molar flux of ion "j" through the ion exchange membrane, [N.sub.j,m], can be related to the current density, i, as [7]

[N.sub.j,m] = [t.sub.j,m]i/[z.sub.j]F, (5)

where [t.sub.j,m] is the transport number of ion j in the membrane, i is current per unit area of membrane or current density (A x [m.sup.-2]), and [z.sub.j] is the charge of the ion.

At steady state [N.sub.j] and [N.sub.j,m] are equal; that is,

[t.sub.j,m]i/[z.sub.j]F = [D.sub.j] [partial derivative][C.sub.j]/[partial derivative]x - [z.sub.j][C.sub.j]F[D.sub.j]/RT[.sup. [partial derivative][psi]/[partial derivative]x. (6)

Assuming that a linear profile of the concentration distribution exists along the boundary layer, the linearized NernstPlanck equation could be used instead of (6). Expression for the linearized Nernst-Planck equation when applied in the diluate chamber is [7]

[t.sub.j,m]i/[z.sub.j]F = [D.sub.j]([C.sup.dil.sub.j,b] - [C.sup.dil.sub.j,m])/[delta] - [z.sub.j][D.sub.j]F[xi][C.sup.dil.sub.j,m]/RT, (7)

where [delta] is the boundary layer thickness (m), [C.sup.dil.sub.j,b] and [C.sup.dil.sub.j,m] are concentrations of ions in bulk and at the membrane surface, respectively, of the diluatecompartment, and [xi] is the potential gradient (V x [m.sup.-1]) and is expressed as

[xi] = [psi]/[delta]. (8)

In (7) the first part, that is, [D.sub.j]([C.sup.dil.sub.j,b] - [C.sup.dil.sub.j,m])/[delta], denotes flux due to molecular diffusion flux of ion arising out of concentration variation between solution bulk and boundary layer over membrane surface. The second part, that is, [z.sub.j][D.sub.j]F[xi][C.sup.dil.sub.j,m]/RT, shows flux due to externally applied potential over the membrane.

3.2.2. Boundary Layer Thickness, [delta] Estimation. [delta] is estimated using film theory (equation (9)) and salt mass-transfer coefficient [7, 20]. Salt mass-transfer coefficient is usually determined based on salt diffusivity and suitable mass-transfer correlation, which in-turn is dependent on flow profile and physical properties of-the fluids, cell geometry, and surface morphology of membranes used in ED cell [7, 9, 21, 22]:

[delta] = [D.sub.j]/[kappa], (9)

where, [D.sub.j] and k are diffusivity and mass transfer coefficient of diffusing species in solution. Each of these parameters was separately estimated using standard correlations. The mass transfer coefficient was obtained from Sherwood number [7, 20, 21] as:

Sh = [kappa] x l/[D.sub.j], (10)

where l is the characteristic length (m). Sherwood number, Sh, is expressed as a function of Reynolds number, Re, and Schmidt number, Sc [7, 20]. The empirical expression of Sherwood number is based on cell geometry and spacer configuration chosen for the present cell as indicated in the following [17, 20, 23]:

Sh = a x [Re.sup.b] - [Sc.sup.c], (11)

where Sc (Schmidt number, [mu]/[rho][D.sub.j]) is estimated from physical properties (viscosity and density) of the medium while Reynolds number ([rho]vl/[mu]) indicates flow characteristics of the medium and channel spacing as "l" and a, b, c are the empirical constants, which are determined by fitting the data (Sh/[Sc.sup.c] versus Re) for experiments where flow rate is varied. In this work, the values of a, b, and c are taken from literature [17] and are given in Table 3.

Ionic diffusivity is entirely dependent on the size of hydrodynamic diameter of ions. Assuming infinite dilution this ionic diffusivity is estimated using the Nernst-Haskel equation (12) [14] as

D[degrees] = RT[(1/[z.sub.+]) + (1/[z.sub.-])]/ [F.sup.2] [(1/[[lambda].sub.+]) + (1/[[lambda].sub.-])], (12)

where [z.sub.+] and [z.sub.-] denote charges of cation and anion, respectively, while [[lambda].sub.+] and [[lambda].sub.-] denote limiting ionic conductance in the solvent. Other parameters bearing meaning and units are as reported in the nomenclature.

Diffusivity is a strong function of viscosity which was corrected using equation proposed by Yuan-Hui and Gregory [15]

D/D[degrees] = [mu][degrees]/[mu]. (13)

3.2.3. Estimation of Membrane Surface Concentration. The membrane surface concentration of ions is dependent on current density under an applied voltage. As long as the ED operation is executed below limiting current (surface concentration becomes zero), the surface concentration on either side can be estimated from bulk concentration measurement (diluate/concentrate), current density, and limiting current density using (14) and (15) [19, 24]:

[C.sup.conc.sub.j,m] = [C.sup.conc.sub.j,b] (1 + i/[i.sub.j,lim]), (14)

[C.sup.dil.sub.j,m] = [C.sup.dil.sub.j,b] (1 + i/[i.sub.j,lim]), (15)

where [C.sup.conc.sub.j,m] and [C.sup.conc.sub.j,b] are the concentrations of ion j, on the membrane surface and in bulk of the concentrate compartment, respectively, in the ED cell. [C.sup.dil.sub.j,m] and [C.sup.dil.sub.j,b] are the concentrations of ion j, on the membrane surface and in the bulk of the diluate side, respectively, in the ED cell.

3.2.4. Estimation of Current Density and Limiting Current Density (i and [i.sub.j,lim]). LCD(of a single electrolyte) is estimated using the following equation [5, 9]:

[i.sub.j,lim] = [C.sup.dil.sub.j,b][D.sub.j][z.sub.j]F/[delta]([t.sub.j,m] - [t.sub.j,b]), (16)

where [t.sub.j,m] and [t.sub.j,b] are transport numbers of ion j in membrane and electrolyte solution, respectively.

Considering ion flux in the diluate side of the IEM, (15) is used to calculate concentration of ion j, at the membrane surface of diluate side [C.sup.dil.sub.j,m].

The current density can be expressed by (17) after substitution of (15) and (16) in (6):


where [xi] the potential gradient can be estimated from Nernst equation given as follows [18,19]:

[xi] = -([2t.sub.j,m] - 1) RT/[delta]F ln ([[gamma].sup.dil.b] [C.sup.dil.j,b]/[[gamma].sup.dil.m] [C.sup.dil.j,m]), (18)

where [[gamma].sup.dil.m] and [[gamma].sup.dil.b] are the mean ionic activity coefficients corresponding to the ions at the wall of IEM and in the bulk of solution, respectively, within the diluate channel and they can be estimated using Debye-Huckel limiting law [25].

4. Numerical Estimation of Parameters

The sequence of steps followed to obtain theoretical estimate of concentration variation is described using flow chart (Figure 3). The differential equations (1) and (3) were integrated using Euler method with 1 s time step. Few crucial parameters and their evaluation method are presented below.

4.1. Determination of Transport Number of Ion in Solution. Bulk transport number [t.sub.j,b] is the fraction of total current carried by the ion type which is a function of diffusion coefficient and ionic mobility of hydrated species. Ions in solution get hydrated with solvent molecules and difference in hydration ability causes variation in size, diffusivity, and mobility of such species. Thus, ions do not transport current equally in solution. The transport number was estimated using following equation [7]:

[t.sub.j,b] = [absolute value of ([z.sub.j])][D.sub.j]/ [[summation].sup.n.sub.j=1]] [absolute value of ([z.sub.j])][D.sub.j] (19)

For a binary-ion salt solution, n = 2, j = 1 for cation and j = 2 for anion, respectively.

4.2. Determination of Current from Resistance Measurement. Initial current density estimation is essential to obtain salt concentration at membrane surface and start numerical integration which may be evaluated either experimentally or from applied potential and solution resistance using Ohm's law. The potential applied may be expressed as

[E.sub.tot] - [E.sub.el] = [R.sub.tot] x J, (20)

where [E.sub.el] is the potential drop near the electrodes, [R.sub.tot] is the overall resistance (ohm) of the ED cell, and J is the current (A). The overall resistance is the sum of resistances of individual chambers:

[R.sub.tot] = [R.sub.anolyte] + [R.sub.diluate] + [R.sub.catholyte], (21)

where resistance of anolyte, catholyte, and diluate channel are determined either directly from conductivity measurement or from extended Kohlrausch-equation [19, 25]. The conductivity and the resistance are related as

Resistance = 1/[LAMBDA] L/[A.sub.m], (22)

where [LAMBDA] is the conductivity of solution (mho x [m.sup.-1]), L is the gap between membranes or the compartment thickness (m), and [A.sub.m] is the effective membrane area ([m.sup.2]).

4.3. Determination of Specific Energy Consumption. The specific energy consumption, [E.sub.sp] (kWh x [kg.sup.-1]), was obtained using the following equation:


where [epsilon] is the applied potential in V, [A.sub.m] is the area of the membrane in [m.sup.2], i(t) is the current density as a function of time in A x [m.sup.-2], [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] is the molecular mass of Ca[Cl.sub.2] (=111.02 g/mol), and [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII](t) is the number of moles of Ca[Cl.sub.2] removed from the feed solution at various time intervals.

5. Results and Discussions

5.1. Role of Sugar and Ca[Cl.sub.2] Concentration on Solution Viscosity and Influence of Temperature. Sugar solution viscosity increases nonlinearly (Figure 4) with increase in sugar concentration (5 to 20wt%). Viscosity values range between 0.72 and 1.5mPa-s with increase in sugar concentration. These values were very much comparable with the literature reported data [16]. Solution viscosity does not show any appreciable change with Ca[Cl.sub.2] concentration (0-50 mol/[m.sup.3]) (Figure 5). Influence of temperature on Ca[Cl.sub.2] solution viscosity was recorded at 20, 25, 32, 37, and 42[degrees]C and viscosity decreases between 1.22 and 0.7 mPa-s. Nearly ~43% lowering in solution viscosity with temperature rise between 20 and 42[degrees]C is noted in Figure 5.

5.2. Role of Sugar and Ca[Cl.sub.2] Concentration on Electrical Conductivity of Electrolyte. Figure 6 shows plot of Ca[Cl.sub.2] concentration on the electrical conductivity, which was estimated in presence and absence of sugar. Electrical conductivity increases almost linearly with rise in Ca[Cl.sub.2] concentration (5 to 50 mol x [m.sup.-3]). The Ca[Cl.sub.2], being a strong electrolyte, dissociates completely in solution, thus increasing number of ions per unit volume available for ionic conductance. On the contrary, sugar addition dampens the conductivity value. This is possibly because sugar is a water soluble nonelectrolyte which does not change the number of ionic species responsible for current carriage; thus, presence of inert sugar molecules basically increases crowding in solution.

5.3. Effect of Applied Potential on Ion-Removal Rate. The applied potential is a crucial parameter to define removal rate and efficiency. With increased potential, ion removal rate increases causing rapid lowering of batch time [26]. In a batch operation, with gradual lowering of ion concentration the current density keeps dropping. Once, the concentration reaches below limiting value the solution resistance becomes very high and heating starts. At this increased temperature electrolysis of water starts and a major portion of applied potential gets consumed without much gain in ion removal. Thus, overall energy consumption increases affecting process efficiency [5, 22].

Three different voltages (4 V, 8 V, and 12 V) were applied keeping other process parameters unchanged. Figure 7 shows effect of applied potential on [Ca.sup.2+] ion removal rate. With higher potential, the ion removal rate increases. This is quite obvious because with increased electrical driving force (potential), more current passes through the solution as long as resistance remains unchanged. It is interesting to note that at lower potential, the ion removal rate remains linear for a long duration (>240 min) indicating Ohm's law might be applicable. This is not observed with higher potentials. With -8 V, the nonlinearity appears at time ~180 min while the same happens at time ~120 min for -12 V. Possibly unwanted electrode reactions (water splitting) initiate at early stages with increased potential. This certainly influences the ion removal rate showing variation in slope of the concentration drop curve. This indicates that at higher voltage rapid depletion of ions and a nonlinear rise in resistance occurs. Rapid nonlinear rise in solution resistance was also observed earlier by different scientists [8, 9].

5.4. Effect of Flow Rate on Ion Removal Rate. Change in ion removal rate with variation in feed flow rate, without disturbing catholyte and anolyte streams conditions (flow rate, components, concentration, etc.), was analyzed and reported in Figure 8. Feed flow rates were varied as 80, 130, and 180 mL/min and change in ion removal rate was noted after nearly 60 min of ED operation. A slow rise in removal rate with increased flow rate was observed. Increased flow rate possibly increased turbulence which reduced thickness of stationary boundary film over membrane surface. This lowered the overall ion transfer resistance and increased ion removal rate.

5.5. Model Prediction of Experimental "i" and [Ca.sup.2+] Ion Concentration. The batch mode of electrodialysis with continuous recirculation under an applied potential becomes an unsteady state process. The electrolyte concentrations of diluate (feed tank) and concentrate streams, solution resistance (conductivity), concentration profile around membrane, and bulk physical properties of the solution become time dependent. The cumulative effects of all these parameters are reflected in diluate (feed tank) concentration and overall current density of the ED cell. Therefore, the mathematical model emphasizes two crucial parameters: (i) electrolyte (Ca[Cl.sub.2]) concentration of the diluate stream (feed tank) and (ii) overall current density of the cell. Unsteady state mass balance around the diluate channel/tank is written in terms of important process variables, for example, vessel volume, flow rate, concentration, current density, current efficiency, and membrane area. Nernst Planck equation and irreversible thermodynamics are used to estimate the ionic flux through the boundary layer over the membrane. The model proposed closely predicts experimental data between the chosen range of process condition of [Ca.sup.2+] ion (Figures 9 and 10) and current density with time (Figure 9) in the ED cell.

Molar concentration of the recirculating feed solution was obtained by solving coupled differential equations. Equations (1) and (3) and physical process parameters values are listed in Table 3. Solution steps (using MATLAB code) are discussed in Figure 3. The concentration estimates so obtained were used to estimate current density, i (17). The theoretical model could closely predict the experimental data (Experiments 1, 2, and 3) of concentration variation (Figures 9 and 10). Experiments 2 and 3, performed with two different concentrations of Ca[Cl.sub.2] (25 and 50 mol x [m.sup.3]) in feed solution, behaved in the same manner (Figure 10). This supports the fact that the method adopted in concentration estimation was correct and reproducible.

Initially solute concentration (25 mol x [m.sup.3]) of the feed solution drops steadily in experiment 1, the rate of which slows down after nearly 200 min (Figure 9). The experimental current density also follows same trend (Figure 9). A steady drop in current density from 120 A x [m.sup.-2] to 40 A x [m.sup.-2] during first 200 min was recorded possibly due to rapid lowering in ionic concentration in the diluate under applied potential of 4 V.

5.6. Role of Catholyte Composition and a Probable Mechanism for Smooth Operation of ED. Ca[Cl.sub.2] is a strong electrolyte and preferentially exists in ionized ([Ca.sup.2+] and 2[Cl.sup.-1]) state in the aqueous solution containing sugar (5%). Water molecules form a hydration sphere around each dissociated ion and stabilize it. On application of external potential these hydrated species start crossing polar membranes charged with counter ions and cause concentration polarization buildup across the polar membrane.

The approach adopted here is to minimize the concentration polarization. [Ca.sup.2+] ion crosses the cation exchange membrane. This was accomplished by either (i) precipitating out the ions or by (ii) complexing out before a back diffusion sets in. Two different catholyte streams were chosen with a definite purpose, for example, (i) 0.1 N NaOH (which forms an insoluble precipitate of [Ca.sup.2+] ion (23)) and (ii) a mixture of acetic acid and di-sodium salt of EDTA ([Na.sub.2]EDTA, a well-known complexing agent for bivalent cation ([Ca.sup.2+]) after it crosses the CEM, (24)). Hydrated [Ca.sup.2+] ions cross cation exchange membrane (CEM) and reaches catholyte compartment where it may precipitate or dissolve based on the electrolyte (s) and pH of the catholyte stream. [Ca.sup.2+] ions react with the NaOH of catholyte stream and forms Ca[(OH).sub.2]. As the solubility product of Ca[(OH).sub.2] in water is very low (~10-6), it experiences high probability of precipitation over membrane surface facing higher pH. Once this precipitate comes in contact with electrolyte containing [Na.sub.2]EDTA, it reacts and forms a stable complex, Ca[Na.sub.2]EDTA, which washes out the precipitate formed and cleans the membrane surface. The scheme of overall reaction is presented as follows:


[Ca.sup.2+] + [Na.sub.2]EDTA Ca[Na.sub.2]EDTA + 2[H.sup.+] (25)

Bivalent cation are well known for their low solubility at high pH and often precipitate out as metal hydroxides [27]. This precipitation problem was also observed with calcium ion reported here when NaOH was used in catholyte stream. Figure 11 shows NaOH (100 mol x [m.sup.3]) as catholyte streams although increases ion removal rate initially, but vigorous fouling prevented the process from running for long duration. With NaOH as catholyte, Ca[(OH).sub.2] precipitation was extensive which turned the membrane color from brownish yellow to white and probably blocked the swollen membrane pores on the rare side. Although this approach completely arrested the reverse transport of [Ca.sup.2+] ions but continuous operation was limited due to membrane fouling, increased resistance, and drop in current density. Frequent acid wash helped in improving the membrane performance but continuous operation was not feasible.

Formation of white solid powder was noted over the membrane (CEM) surface facing catholyte stream (NaOH, higher pH) in experiment 1 and experiment 3. The white powder over membrane was investigated further to have better understanding of the problem which arose after ED operation for specified duration. Quantitative estimations of the fouled membrane were made by gravimetric method. The CEM membrane after ED experimentation was taken out, washed, and weighed, after drying and equilibration. The used membrane (equilibrated 24 hours at 100[degrees]C) was found to increase in mass over its initial mass (equilibrated) before ED. Gain of mass in used membrane is reported in Table 4.

The white deposit on the membrane surface could be removed by immersing the membrane in a dilute HCl (10% in water) solution. Immediately after immersion bubbling from the fouled surface of the membrane was observed. For complete dissolution of the white deposit, the membrane was left immersed in the solution for ~30 minutes until bubbling stopped. Subsequently the membrane was removed, washed repeatedly with deionized water, and dried in oven (100[degrees]C for 24 hours) and weighed. A blank test was simultaneously performed using a fresh membrane to record the difference between used and fresh membrane. For an applied potential the dry mass of the used membrane was found to be dependent on its duration of application, electrolyte concentration, and electrolyte stream pH.

Multiple samples of the used membrane were tested and formation of bubbles was confirmed. Once the bubbling stopped after immersing the membrane in dilute HCl solution, the piece was taken out, washed, dried, and equilibrated before weighing. Mass of the membrane did not deviate much from its initial value. This indicated possibility of C[O.sub.2] evolution from the reaction of HCl with CaC[O.sub.3]. The most probable sequence of the overall reaction occurring over the membrane surface and its subsequent cleaning with dilute HCl may be explained by the following scheme:

C[O.sub.2] (air) + 2O[H.sup.-] [right arrow] C[O.sub.3.sup.2-] + [H.sub.2]O (26)

Ca[(OH).sub.2] + C[O.sub.2] [right arrow] CaC[O.sub.3] (s) + [H.sub.2]O (27)

CaC[O.sub.3] (s) + HCl [right arrow] Ca[Cl.sub.2] + C[O.sub.2] (g) + [H.sub.2]O (28)

At higher pH, solubility of C[O.sub.2] (air) increases in NaOH solution (catholyte stream) which results in formation of HC[O.sub.3.sup.-1]/C[O.sub.3.sup.2-]. These ions subsequently react with NaOH to form [Na.sub.2]C[O.sub.3] providing the source for CaC[O.sub.3] precipitation from Ca[(OH).sub.2]. Conversion of Ca[(OH).sub.2] to C[O.sub.3.sup.-2] is (27) is thermodynamically favorable and moves forward. Nearly 1000 times higher value of solubility product of Ca[(OH).sub.2] [5.5 x [10.sup.-6]] over CaC[O.sub.3] [3.39 x [10.sup.-9] [28] drives the process faster.

Formation of CaC[O.sub.3] not only increased membrane resistance to ion transport but also made the ED operation discontinuous. The process was made uninterrupted by changing the electrolyte composition of the catholyte stream. Here we report application of [Na.sub.2]EDTA-acetic acid solution as catholyte stream; the chelating agent continuously complexes with the precipitated CaC[O.sub.3] and formed corresponding salt Ca[Na.sub.2]EDTA. The pH of catholyte stream was adjusted between 3.5-5.0 (Table 2) and the anolyte was maintained as HCl (100 mol x [m.sup.3]). This combination showed negligible fouling even after long (240 min) operation time (Table 4).

The mass transfer coefficients estimated from Sherwood number correlation (11) showed higher values while NaOH (100 mol x [m.sup.3]) was used as catholyte stream compared to [Na.sub.2]EDTA-acetic acid (AA) combination (Table 4). Reduced mass transfer coefficient with [Na.sub.2]EDTA-acetic acid stream may be attributed to higher solution resistance arising possibly due to weak dissociation of acetic acid of [Na.sub.2]EDTA + AA combination than that of NaOH. The dissociation constant can get further affected due to [Na.sub.2]EDTA (a bulky diffusing species). Thus, reduction in mass transfer coefficient lowered [Ca.sup.2+] ion removal rate.

As of now, we have understood that chemical composition and concentration of anolyte/catholyte streams play crucial role in controlling overall resistance and ion removal rate. The specific energy consumption, [E.sub.sp], estimated from (23) (Table 4) shows lower value with NaOH compared to the streams containing [Na.sub.2]EDTA + AA.

The average running cost to remove unit mass of Ca[Cl.sub.2] is reported in Table 4. The cost is dependent on concentration of the electrolyte stream and time of ED operation. Cost is inversely proportional to initial concentration of the stream and directly proportional to operation time. Energy due to pumping is the major contribution to the overall costs estimate in a batch ED operation for a given time.

6. Conclusions

Calcium ion (Ca[Cl.sub.2], 25 mol x [m.sup.3]) removal rate depends on feed flow rates, electrolyte (anolyte/catholyte) components, concentrations, applied potential, and so forth. NaOH as catholyte showed higher removal rate and increased mass transfer coefficient over mixed electrolyte (AA-[Na.sub.2]EDTA). Specific energy consumption ([E.sub.sp], kWh x [kg.sup.-1]) estimates for three typical set of experiments (Table 4) also support the above observation of easy ion removal rate. Based on this it may be concluded that although NaOH shows better performance for the duration chosen in this report, but an uninterrupted mode ED operation would be feasible with mixed electrolyte only but of course energy consumption will be partly increasing. The unsteady state model used could effectively predict the current density and concentration change with an accuracy of 95%.


Density values of 5% sugar solution with varying concentration of Ca[Cl.sub.2] were estimated from the fitted equation (Density (kg x [m.sup.3]) = 0.323 x Concentration (mol x [m.sup.3]) + 1017.5; [R.sup.2] =.98) obtained from the experimental data of density versus concentration of Ca[Cl.sub.2] in 5% sugar solution (Figure 12).


List of Symbols

a: Sh number empirical equation constant

[A.sub.m]: Area of the membrane, [m.sup.2]

b: Sh number empirical equation constant

c: Sh number empirical equation constant

C: Concentration, mol x [m.sup.3]

D: Diffusivity of the salt or ion in the solution

at temperature, T

D[degrees]: Diffusivity of the salt or ion at infinite dilution at temperature, T

[D.sub.j]: Diffusivity of ion "j"

[E.sub.el]: Electrode potential, V

[E.sub.tot]: Total electric potential applied, V

[E.sub.sp]: Specific energy consumption, kWh x [kg.sup.-1]

F: Faraday constant, C x [gm-eq.sup.-1]

i: Current density, A x [m.sup.-2]

[i.sub.j,lim]: Limiting current density of ion "j"

I: Ionic strength

J: Current, A

[kappa]: Mass transfer coefficient, m/s

L: Characteristic length, m

[m.sub.j]: Molality of ion "j"

Q: Volumetric flow rate, [m.sup.3] x [s.sup.-1]

R: Gas constant, J x [kg.sup.-1] x [K.sup.-1]

[R.sub.anolyte]: Resistance of anolyte chamber

[R.sub.catholyte]: Resistance of catholyte chamber

[R.sub.diluate]: Resistance of diluate chamber

[R.sub.tot]: Total Resistance of the electrodialysis cell

Re: Reynolds number

Sc: Schmidt number

Sh: Sherwood number

t: Time, s

T: Temperature, K

[t.sub.+,CEM]: Transport number of cation in cation exchange membrane

[t.sub.-,AEM]: Transport number of anion in anion exchange membrane

[t.sub.j,m]: Transport number of ion "j" in the membrane

[t.sub.j,b]: Transport number of ion "j" in the bulk solution

v: Velocity, m/s

V: Volume, [m.sup.3]

z: Ion charge.


AEM: Anion exchange membrane

b: Bulk solution

CEM: Cation exchange membrane

C: Compartment

j: Ion, "j"

T: Feed tank

[+ or -]: Cation or anion.


Conc: Concentrate

dil: Diluate

lim: Limiting.

Greek Symbols

[eta]: Current efficiency

[epsilon]: Applied voltage, V

[mu]: Viscosity of the solution at the same temperature T, Pa x s

[mu][degrees]: Viscosity of the pure water at a temperature T, Pa x s

[LAMBDA]: Conductivity, S

[[lambda].sub.+], [[lambda].sub.-]: Limiting (zero concentration) ionic conductance, (A x [cm.sup.-2]) x (V x [cm.sup.-1])(g-eqv x [cm.sup.3])

[rho]: Density, kg-[m.sup.3]

[delta]: Diffusion boundary layer thickness, m

[xi]: Potential gradient, V x [m.sup.-1]

[psi]: Potential drop in the diffusion boundary layer, V

[[gamma].sub.[+ or -]]: Mean ionic activity coefficient.

Conflict of Interests

The authors declare that there is no conflict of interests regarding to the publication of this paper.


Financial support to execute the experimental work is gratefully acknowledged to IIT Roorkee (no. IITR/SRIC/244/FIG Sch-A).


[1] R. B. L. Mathur, Handbook of Cane Sugar Technology, Oxford and IBH Publishing, New Delhi, India, 1978.

[2] F. Smagghe, J. Mourgues, J. L. Escudier, T. Conte, J. Molinier, and C. Malmary, "Recovery of calcium tartrate and calcium malate in effluents from grape sugar production by electrodialysis," Bioresource Technology, vol. 39, no. 2, pp. 185-189, 1992.

[3] A. Elmidaoui, L. Chay, M. Tahaikt et al., "Demineralisation of beet sugar syrup, juice and molasses using an electrodialysis pilot plant to reduce melassigenic ions," Desalination, vol. 165, p. 435, 2004.

[4] G. Tragardh and V. Gekas, "Membrane technology in the sugar industry," Desalination, vol. 69, no. 1, pp. 9-17, 1988.

[5] H. Strathmann, Ion-Exchange Membrane Separation Processes, Elsevier, 2004.

[6] J. J. Krol, M. Wessling, and H. Strathmann, "Concentration polarization with monopolar ion exchange membranes: current-voltage curves and water dissociation," Journal of Membrane Science, vol. 162, no. 1-2, pp. 145-154, 1999.

[7] V. Geraldes and M. D. Afonso, "Limiting current density in the electrodialysis of multi-ionic solutions," Journal of Membrane Science, vol. 360, no. 1-2, pp. 499-508, 2010.

[8] H. Strathmann, J. J. Krol, H.-J. Rapp, and G. Eigenberger, "Limiting current density and water dissociation in bipolar membranes," Journal of Membrane Science, vol. 125, no. 1, pp. 123-142, 1997

[9] H.-J. Lee, H. Strathmann, and S.-H. Moon, "Determination of the limiting current density in electrodialysis desalination as an empirical function of linear velocity," Desalination, vol. 190, no. 1-3, pp. 43-50, 2006.

[10] Y. Tanaka, "Limiting current density of an ion-exchange membrane and of an electrodialyzer," Journal of Membrane Science, vol. 266, no. 1-2, pp. 6-17, 2005.

[11] A. Elmidaoui, F. Lutin, L. Chay, M. Taky, M. Tahaikt, and M. R. A. Hafidi, "Removal of melassigenic ions for beet sugar syrups by electrodialysis using a new anion-exchange membrane," Desalination, vol. 148, no. 1-3, pp. 143-148, 2002.

[12] Y. Tanaka, "Irreversible thermodynamics and overall mass transport in ion-exchange membrane electrodialysis," Journal of Membrane Science, vol. 281, no. 1-2, pp. 517-531, 2006.

[13] S. Chattopadhyay, Removal of Calcium Ion from Sugar Solution through Electrodialysis, Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur, India, 1994.

[14] B. E. Poling, J. M. Prausnitz, and J. P. O'Connell, The Properties of Gases and Liquids, McGraw-Hill, New York, NY, USA, 5th edition, 2000.

[15] L. Yuan-Hui and S. Gregory, "Diffusion of ions in sea water and in deep-sea sediments," Geochimica et Cosmochimica Acta, vol. 38, no. 5, pp. 703-714, 1974.


[17] M. S. Isaacson and A. A. Sonin, "Sherwood number and friction factor correlations for electrodialysis systems, with application to process optimization," Industrial & Engineering Chemistry Process Design and Development, vol. 15, no. 2, pp. 313-321, 1976.

[18] J. M. Ortiz, J. A. Sotoca, E. Exposito et al., "Brackish water desalination by electrodialysis: batch recirculation operation modeling," Journal of Membrane Science, vol. 252, no. 1-2, pp. 65-75, 2005.

[19] F. S. Rohman, M. R. Othman, and N. Aziz, "Modeling of batch electrodialysis for hydrochloric acid recovery," Chemical Engineering Journal, vol. 162, no. 2, pp. 466-479, 2010.

[20] R. E. Treybal, Mass-Transfer Operations, McGraw-Hill, New York, NY, USA, 3rd edition, 1980.

[21] R. B. Bird, W. E. Stewart, and E. N. Lightfoot, Transport Phenomenon, John Wiley & Sons, 2nd edition, 2002.

[22] J. Balster, M. H. Yildirim, D. F. Stamatialis et al., "Morphology and microtopology of cation-exchange polymers and the origin of the overlimiting current," The Journal of Physical Chemistry B, vol. 111, no. 9, pp. 2152-2165, 2007.

[23] O. V. Grigorchuk, V. I. Vasileva, and V. A. Shaposhnik, "Local characteristics of mass transfer under electrodialysis demineralization," Desalination, vol. 184, no. 1-3, pp. 431-438, 2005.

[24] V. M. Barragan and C. Ruiz-Bauzo, "Current-voltage curves for ion-exchange membranes: a method for determining the limiting current density," Journal of Colloid and Interface Science, vol. 205, no. 2, pp. 365-373, 1998.

[25] J. Koryta, J. Dvorak, and L. Kavan, Principles of Electrochemistry, John Wiley & Sons, New York, NY, USA, 2nd edition, 1993.

[26] N. Kabay, M. Demircioglu, E. Ersoz, and I. Kurucaovali, "Removal of calcium and magnesium hardness of electrodialysis," Desalination, vol. 149, no. 1-3, pp. 343-349, 2002.

[27] M. Araya-Farias and L. Bazinet, "Electrodialysis of calcium and carbonate high-concentration solutions and impact on membrane fouling," Desalination, vol. 200, no. 1-3, p. 624, 2006.


Jogi Ganesh Dattatreya Tadimeti, (1) Shilpi Jain, (1) Sujay Chattopadhyay, (1) and Prashant Kumar Bhattacharya (2)

(1) Polymer and Process Engineering Department, IIT Roorkee, Saharanpur Campus, Saharanpur 247 001, India

(2) Chemical Engineering Department, Indian Institute of Technology, Kanpur 208 016, India

Correspondence should be addressed to Sujay Chattopadhyay;

Received 30 July 2014; Revised 3 November 2014; Accepted 14 November 2014; Published 14 December 2014

Academic Editor: Sergio Ferro

TABLE 1: Membrane parameters as obtained from Permionics India Ltd.

Physical parameters              Cation exchange    Anion exchange
                                     membrane          membrane

Transport number                       0.91               0.9
Experimental resistance              2.0-3.5              --
  (ohm [cm.sup.-2])
Max. pressure allowed                  3.0                3.0
Thickness (mm)                     0.11 to 0.15        0.09-0.11
Max. temperature ([degrees]C)           60                60

TABLE 2: Different process variables chosen during ED experimentation

Expt.       Feed solution           Feed flow
number                                 rate
                                (mL x [min.sup.-1])

1        25 mol x [m.sup.-3]            130
         Ca[Cl.sub.2] in 5%
            sugar solution
2        25 mol x [m.sup.-3]            130
         Ca[Cl.sub.2] in 5%
            sugar solution

3        50 mol x [m.sup.-3]            130
         Ca[Cl.sub.2] in 5%
            sugar solution

Expt.      Anolyte solution         Anolyte flow
number                                  rate
                                 (mL x [min.sup.-1])

1        100 mol x [m.sup.-3]            830
             HCl solution

2        100 mol x [m.sup.-3]            830
             HCl solution

3        100 mol x [m.sup.-3]            830
             HCl solution

Expt.     Catholyte solution       Catholyte flow       Voltage
number                                  rate           applied (V)
                                 (mL x [min.sup.-1])

1        100 mol x [m.sup.-3]            830                4
             NaOH solution

2        25 mol x [m.sup.-3]             830                4
         [Na.sub.2]EDTA + 25
           mol x [m.sup.-3]
              AA solution
3        50 mol x [m.sup.-3]             830                4
           [Na.sub.2]EDTA +
         50 mol x [m.sup.-3]
              AA solution

Expt.    Time
number   (min)

1         685

2         240

3         240

TABLE 3: Values of different physical parameters used in the model.

Parameter                                        Value

Temperature, T                                   298 K
Transport number of the cation                   0.91
  in CEM, [t.sub.+,CEM]
Transport number of the anion in                  0.9
  AEM, [t.sub.-,AEM]
Transport number of cation in                   0.4387
  the solution, [MATHEMATICAL
Transport number of anion in the                0.5613
  solution, [MATHEMATICAL
Diffusivity of Ca[Cl.sub.2] in           1.198 x [10.sup.-9]
  5% sugar solution at                  [m.sup.2] x [s.sup.-1]
  25[degrees]C, [MATHEMATICAL
Diffusivity of [Ca.sup.2+] ions          7.92 x [10.sup.-10]
  at infinite dilution and at           [m.sup.2] x [s.sup.-1]
  25[degrees]C, [MATHEMATICAL
Diffusivity of [Ca.sup.2+] ions          7.11 x [10.sup.-10]
  in 5% sugar solutions at              [m.sup.2] x [s.sup.-1]
  25[degrees]C, [MATHEMATICAL
Diffusivity of [Cl.sup.-] ions           18.2 x [10.sup.-10]
  in 5% sugar solutions at              [m.sup.2] x [s.sup.-1]
  25[degrees]C, [MATHEMATICAL
Distance between adjacent                  2 x [10.sup.-3] m
  membranes, l
Area of the membrane, [A.sub.m]       3.7 x [10.sup.-3] [m.sup.2]

Charge on the calcium ion,                         2
Viscosity of 5% sugar solution,        9.92 x [10.sup.-4] Pa x s
Velocity of the feed stream, v     3.1 x [10.sup.-2] m x [s.sup.-1]

Applied voltage, [E.sub.tot]                      4V
Current density initial value,            122 A x [m.sup.-2]
Current efficiency, [eta]                        0.81
Sh number empirical equation           0.46 for catholyte NaOH
  constant, a                             0.25 [+ or -] 0.03
                                    for catholyte AA-[Na.sub.2]EDTA
Sh number empirical equation      0.63 for any anolyte and catholyte
  constant, b
Sh number empirical equation      0.33 for any anolyte and catholyte
  constant, c

Parameter                             Reference

Temperature, T                        This work
Transport number of the cation         Table 1
  in CEM, [t.sub.+,CEM]
Transport number of the anion in       Table 1
  AEM, [t.sub.-,AEM]
Transport number of cation in       This work [7]
  the solution, [MATHEMATICAL
Transport number of anion in the    This work [7]
  solution, [MATHEMATICAL
Diffusivity of Ca[Cl.sub.2] in    This work [14, 15]
  5% sugar solution at
  25[degrees]C, [MATHEMATICAL
Diffusivity of [Ca.sup.2+] ions     This work [14]
  at infinite dilution and at
  25[degrees]C, [MATHEMATICAL
Diffusivity of [Ca.sup.2+] ions   This work [14, 15]
  in 5% sugar solutions at
  25[degrees]C, [MATHEMATICAL
Diffusivity of [Cl.sup.-] ions    This work [14, 15]
  in 5% sugar solutions at
  25[degrees]C, [MATHEMATICAL
Distance between adjacent             This work
  membranes, l
Area of the membrane, [A.sub.m]       This work

Charge on the calcium ion,            This work
Viscosity of 5% sugar solution,          16]
Velocity of the feed stream, v        This work
Applied voltage, [E.sub.tot]          This work
Current density initial value,        This work
Current efficiency, [eta]             This work
Sh number empirical equation        [17] This work
  constant, a

Sh number empirical equation             [17]
  constant, b
Sh number empirical equation             [17]
  constant, c

TABLE 4: Specific energy consumption, mass transfer coefficient,
average running cost estimated, and gravimetric analysis.

         Specific energy      Average running
Expt.    consumption for      cost (INR/g of
          Ca[Cl.sub.2]         Ca[Cl.sub.2]
             removal,            removed)
        (kWh x [kg.sup.-1])

    1         2.4023                4.7
    2         2.4027                3.4
    3         2.4027                1.9

          Mass transfer         % weight
Expt.      coefficient,       gained by CEM
        k (m x [s.sup.-1])    due to fouling
           x [10.sup.5]

    1          1.928                22
    2          1.174                3
    3          1.173                17
COPYRIGHT 2014 COPYRIGHT 2010 SAGE-Hindawi Access to Research
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2014 Gale, Cengage Learning. All rights reserved.

Article Details
Printer friendly Cite/link Email Feedback
Title Annotation:Research Article
Author:Tadimeti, Jogi Ganesh Dattatreya; Jain, Shilpi; Chattopadhyay, Sujay; Bhattacharya, Prashant Kumar
Publication:International Journal of Electrochemistry
Article Type:Report
Date:Jan 1, 2014
Previous Article:Faster-than-real-time simulation of lithium ion batteries with full spatial and temporal resolution.
Next Article:Solvent effects on the electrochemical behavior of TAPD-based redox-responsive probes for cadmium(II).

Terms of use | Privacy policy | Copyright © 2020 Farlex, Inc. | Feedback | For webmasters