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Research on a Micro-Nano Si/SiGe/Si Double Heterojunction Electro-Optic Modulation Structure.

1. Introduction

With the rapid development of optoelectronic technology, optoelectronic devices have entered the nano era [1, 2], and many nanotechnology has been used in silicon photonics [3-5]. The reduced size of the device can improve the utilization rate of the chip area, but also the higher performance of the device is required, and the silicon epitaxial material is selected to make optoelectronic devices with higher performance. For example, the epitaxial InP material on silicon substrate is used to fabricate laser [6], the epitaxial Ge material is used to make detector [7], the epitaxial SiGe material is used to fabricate modulator [8], and so forth. In optoelectronic integration, the electro-optic modulator is a very important device, which is responsible for the conversion of optical signals and electrical signals [9, 10]. For the electro-optic modulator, the carrier density of waveguide region is one of the key parameters. When the injected carrier density of waveguide region is greater, the change of refractive index is greater, and also the modulator is more easily modulated [11,12]. The traditional method of increasing carrier density is to increase the external modulation voltage, but this way will increase the modulation loss and also is not conducive to photonics integration [8,13]. So SiGe technology is one way to solve this problem in silicon photonics. Photonics Electronics Technology Research Association (PETRA) and University of Tokyo have made a high-speed and highly efficient Si optical modulator with strained SiGe layer and demonstrated highly efficient modulations of 0.67 and 0.81 V x cm for V[pi]L at dc reverse bias voltages of -0.5 and -2 [V.sub.dc], respectively, and also demonstrated a high-speed operation of 25 Gbps for the SiMOD at a wavelength of around 1.3 [micro]m [14]. University of Toronto has made SiGe BiCMOS linear modulator drivers, and the measured differential gain and bandwidth are over 20 dB and 70 GHz, respectively, and [P.sub.1dB] is -2.5 dBm [15]. Ghent University demonstrated single-wavelength, serial and real-time 100 GB/s NRZ-OOK transmission over 500 m SSMF with a GeSi EAM implemented on a silicon photonics platform. The device was driven with 2 Vpp without 50 [ohm] termination, allowing a low-complexity solution for 400 GbE short-reach optical interconnects [16].

This paper presents a micro-nano Si/SiGe/Si double heterojunction electro-optic modulation structure, which can greatly improve the carrier injection concentration and decrease modulation voltage and loss. It is an ideal electrooptic modulator, which is conducive to the photonics integrated circuit miniaturization and integration and also provides a new way for the research of micro-nano optoelectronic devices based on silicon.

2. Structure and Energy Band

Based on the SOI PIN electro-optic modulation structure, a micro-nano Si/SiGe/Si double heterojunction electro-optic modulation structure is presented, which is abbreviated as Silicon/Silicon Germanium/Silicon-On-Insulator (Si/SiGe/ Si-OI) structure, as shown in Figure 1. The bottom of the structure is On-Insulator (OI) material, the P+ and N+ regions in the top layer are silicon materials, and the I region is SiGe material in Figure 1. P+ region is doped by B element, and the doping concentration is 1 x [10.sup.19] [cm.sup.-3]. N+ region is doped by P element, and the doping concentration is also 1 x [10.sup.19] [cm.sup.-3]. I region is N type intrinsic SiGe, and the doping concentration is 1 x [10.sup.15] [cm.sup.-3] . In Figure 1, structure parameters are H = 220 nm, h = 50 nm, W = 400-600 nm, and the width between active region and waveguide (Ws) is a variable value.

In order to facilitate comparison and analysis, two kinds of PIN modulation structures with Si and SiGe materials are established. One is the PIN modulation structure with Si based on the SOI PIN structure, which is abbreviated as SOI structure, as shown in Figure 2(a). The other is the PIN modulation structure with SiGe based on the Silicon Germanium-On-Insulator (SiGe-OI) PIN structure, which is abbreviated as SiGe-OI structure, as shown in Figure 2(b). The doping concentration and structure parameters of two structures are the same as Si/SiGe/Si double heterojunction electro-optic modulation structure.

Si/SiGe/Si-OI structure is composed of P type Si with the high doping concentration, N type SiGe with the low doping concentration, and N type Si with the high doping concentration. Capital P and N represent Wide Band Gap Semiconductor, and lowercase n represents Narrow Band Gap Semiconductor. So the PIN structure can be equivalent as a Pn heterojunction and a nN heterojunction structure, and the band diagram is shown in Figure 3 under the equilibrium state.

When the PIN structure is working, the main carriers of n region are composed of electron from the P region and hole from the N region, and the barrier height is a key parameter who can influence injection efficiency of electron and hole. After heterojunction band of Si/SiGe/Si-OI structure is analyzed, the hole barrier height of Pn heterojunction of the Si/ SiGe/Si-OI structure is represented by the following formula [17]:

-q[V.sub.D] = -[k.sub.0]T ln [n.sub.i(Si)][n.sub.i(SiGe)]/[N.sub.D][N.sub.A] - 0.73x/2, (1)

where q[V.sub.D] is the barrier height, [k.sub.0] is the Boltzmann constant, T is the absolute temperature, [n.sub.i(Si)] is the intrinsic carrier concentration of silicon, [n.sub.i(SiGe)] is the intrinsic carrier concentration of Silicon Germanium, [N.sub.D] is the doping concentration of n region, [N.sub.A] is the doping concentration of P region, x is the Ge content. Formula (1) indicates that the hole barrier height of Pn heterojunction is related to the doping concentration of P region and n region, the band gap of materials, the temperature, and the Ge content. When the temperature is constant, the lower the doping concentration of P region and n region, the lower the hole barrier height. The narrower the band gap, the higher the intrinsic carrier concentration, and the lower the hole barrier height. The bigger the Ge content, the lower the hole barrier height.

Assuming that [N.sub.A] = [10.sup.19] [cm.sup.-3], [N.sub.D] = [10.sup.15] [cm.sup.-3], and the Ge content is 0.2, so the hole barrier height of Pn heterojunction can be calculated equal to -q[V.sub.D] = 0.7 eV at room temperature. For SOI structure and SiGe-OI structure, the Pn junction is homojunction, and the hole barrier height can be analyzed according to the following formula [17]:

-q[V.sub.D1,2] = [E.sub.FP] - [E.sub.Fn] = -kT ln [n.sup.2.sub.i]/[N.sub.D][N.sub.A], (2)

where [E.sub.FP] is the Fermi level of the P region and [E.sub.Fn] is the Fermi level of the n region. The hole barrier height of Pn homojunctions of the SOI structure can be calculated equal to -q[V.sub.D1] = 0.82 eV, and the hole barrier height of Pn homojunctions of the SiGe-OI structure can be calculated equal to -q[V.sub.D2] = 0.733 eV. In the same conditions, the hole barrier height of the Si/SiGe/Si-OI structure is lowest, and the hole barrier height of the SOI structure is highest. This result can be verified by Silvaco CAD software, as shown in Figure 4 [17].

The electron barrier height of nN heterojunction of the Si/SiGe/Si-OI structure can be represented by the following formula [17]:

-q[V'.sub.D] = -kT ln [N'.sub.D][n.sub.i(SiGe)/[N.sub.D][N.sub.i(Si)] - 0.73x/2, (3)

where [N'.sub.D] is the carrier concentration of N region and [N.sub.D] is the carrier concentration of n region. Formula (3) indicates that the electron barrier height of the nN heterojunction of Si/SiGe/Si-OI structure is also related to the doping concentration of N region and n region, the band gap of materials, the temperature, and the Ge content. When the temperature is constant, the lower the doping concentration of N region, the lower the hole barrier height. The higher the doping concentration of n region, the lower the hole barrier height. The wider band gap of n region, the lower the intrinsic carrier concentration, and the lower the hole barrier height. The narrower the band gap of N region, the higher the intrinsic carrier concentration, and the lower the hole barrier height. The smaller the Ge content, the lower the hole barrier height.

Assuming that [N'.sub.D] = [10.sup.19] [cm.sup.-3], [N.sub.D] = [10.sup.15] [cm.sup.-3], and the Ge content is 0.2, so the electron barrier height of nN heterojunction can be calculated equal to q[V'.sub.D] = 0.2 eV at room temperature. For SOI structure and SiGe-OI structure, the nN junction is homojunction, and the electron barrier height can be analyzed according to the following formula [17]:

q[V'.sub.D1,2] = [E.sub.FN] - [E.sub.Fn] = kT ln [N'.sub.D]/[N.sub.D]. (4)

The electron barrier height of nN homojunctions of the SOI structure can be calculated equal to q[V'.sub.D1] = 0.24 eV, and the electron barrier height of nN homojunctions of the SiGe-OI structure can be calculated equal to q[V'.sub.D2] = 0.24 eV. In the same conditions, the electron barrier height ofthe Si/SiGe/Si-OI structure is lowest, and the electron barrier height of the SOI structure is highest. This result can be verified by Silvaco CAD software, as shown in Figure 4.

When the forward bias voltage is set between P region and N region, the original balance between carrier diffusion motion and drift motion is broken, and the PIN device is under nonequilibrium state. Because the doping concentration of the I region is very small, the resistance is very large. The doping concentration of the P region and the N region is very large, and the resistance is very small, so the external positive bias voltage is basically born in the I region. The forward bias voltage produces an electric field opposite to the Built-in Electric Field in the I region, which weakens the intensity of the electric field in the I region and reduces the space charge, so the barrier height decreases. Because the hole barrier height of Pn heterojunction and the electron barrier height of nN heterojunction of Si/SiGe/Si-OI structure all are lower than the barrier height of SiGe-OI structure and SOI structure, so the band of Si/SiGe/Si-OI structure is flattened first under the forward bias voltage. In other words, the Si/SiGe/Si-OI structure has the higher carrier injection at the same forward bias voltage. At 1 V forward voltage, the band simulations of three type modulation structures are shown in Figure 5 [17].

3. Result Analysis

In order to verify that the Si/SiGe/Si-OI structure has better characteristics, the carrier concentration of the SOI structure, the SiGe-OI structure, and the Si/SiGe/Si-OI structure are shown in Figure 6. Figure 6(a) shows the relationship between the electron concentration and modulation voltage for three structures, and Figure 6(b) shows the relationship between the hole concentration and modulation voltage. It can be seen from Figure 6 that, with the increase of modulation voltage, the carrier concentration of three kinds of modulation structure all are gradually increased. When the modulation voltage exceeds 0.6 V, the carrier concentration of the Si/SiGe/Si-OI structure is significantly greater than the carrier concentration of the SOI structure; when the modulation voltage is greater than 0.75 V, the carrier concentration of the Si/SiGe/Si-OI structure is significantly greater than the carrier concentration of SiGe-OI structure; when the modulation voltage is up to 0.9 V, the carrier concentration of the Si/SiGe/Si-OI structure is 6 x [10.sup.18] [cm.sup.-3], but the SOI structure and the SiGe-OI structure reach the same carrier concentration at 2 V modulation voltage; when the modulation voltage reaches 2 V, the carrier concentration of the Si/SiGe/Si-OI structure could increase to 1.5 x [10.sup.19] [cm.sup.-3]. Assuming the SOI structure and the SiGe-OI structure all work at 2 V modulation voltage, so the Si/SiGe/Si-OI structure can work only at 0.9 V modulation voltage. From that we can see the modulation voltage of electro-optic modulator effectively is reduced, and the injection efficiency of electro-optic modulator effectivelyis improved for the Si/SiGe/Si-OI structure.

In order to verify the correctness of the theoretical analysisandsimulationresults, wehavemadethemicro-nano Si/SiGe/Si double heterojunction electro-optic modulation, as shown in Figure 7. For the modulation of the optical part, the micro-ring modulation structure is selected. Figure 7(a) shows schematic diagram of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation, Figure 7(b) shows Laser Scanning Confocal Microscopy (LSCM) picture of device by LEXT-OLS4000, Figure 7(c) shows Scanning Electron Microscope (SEM) picture of micro-ring structure by JSM-6700F, and Figure 7(d) shows SEM of device. The waveguide width is 450 nm, the ridge waveguide height is 220 nm, the planar waveguide height is 50 nm, the gap between waveguide and micro-ring is 200 nm, the micro-ring radius is 10 [micro]m, the doping concentration of P+ region is 1 x [10.sup.19] [cm.sup.-3], the doping concentration of N+ region is 1 x [10.sup.19] [cm.sup.-3], and the doping concentration of I region is 1 x [10.sup.15] [cm.sup.-3]. At the same processing conditions and device parameters, the micro-nano SOI micro-ring electrooptic modulation is also made for testing comparison.

The transmission spectrum of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation has been tested, as shown in Figure 8. From that we can see the Free Spectrum Range (FSR) is 9.44 nm, and the 3dB Bandwidth of the resonant peak is 0.12 nm, near the 1549 nm. The corresponding Q value is 12900, and the extinction ratio of the resonant peak is 11.2 dB.

At the same testing conditions, the transmission spectrum of the micro-nano SOI micro-ring electro-optic modulation has also been tested, as shown in Figure 9. From that we can see the Free Spectrum Range (FSR) is 9.41 nm, and the 3 dB Bandwidth of the resonant peak is 0.13 nm, near the 1548 nm. The corresponding Q value is 11900, and the extinction ratio of the resonant peak is 7.0 dB.

From the comparison of testing results between the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation and the micro-nano SOI micro-ring electro-optic modulation, we can see that Free Spectrum Range, 3 dB Bandwidth, Q value, extinction ratio, and other parameters of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation are better than that of the micro-nano SOI micro-ring electro-optic modulation, and Q value and the extinction ratio are especially greater than that of the micro-nano SOI micro-ring electro-optic modulation.

The test result of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation is shown in Figure 10. The forward bias voltages are 0,1,1.1,1.2 V, respectively. From that we can see the resonant peak has obviously been blue-shifted after the forward bias voltage is set. When the forward bias voltage is 1V, the value of blue-shift is 0.71 nm.

When the forward bias voltages are 0, 1.5, 1.8, 2 V, respectively, the transmission spectrum of the micro-nano SOI micro-ring electro-optic modulation has been tested, as shown in Figure 11. From that we can see the resonant peak has also obviously been blue-shifted after the forward bias voltage is set, but the modulation effect is worse than Si/SiGe/Si modulation. Only when the forward bias voltage is up to 2 V, the value of blue-shift is 0.71 nm.

From the comparison of testing results between the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation and the micro-nano SOI microring electro-optic modulation, we can see that the modulation efficiency of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation is better than that of the micro-nano SOI micro-ring electro-optic modulation at the same processing conditions and testing conditions. In other words, the modulation voltage of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation is lower than that of the micro-nano SOI microring electro-optic modulation, and the modulation power of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation is lower too. So the testing results are consistent with previous theoretical analysis and simulation results.

4. Conclusions

This paper presents a micro-nano Si/SiGe/Si double heterojunction electro-optic modulation structure. Based on the band theory of single heterojunction, the barrier height of the new structure is quantitatively analyzed, and the formulas of barrier height are gotten using the numerical calculus and derivation. The reason of carrier injection enhancement in thenewstructureisanalyzed. On thesimulationplatform, the new structure, SiGe-OI structure, and SOI structure are simulated. From the comparison of simulation results, when the modulation voltage is up to 0.9 V, the carrier concentration of the new structure is 6 x [10.sup.18] [cm.sup.-3], but the SOI structure and the SiGe-OI structure reach the same carrier concentration at 2 V modulation voltage. Finally, the micro-nano Si/SiGe/Si double heterojunction electro-optic modulation is made and tested. Comparison of testing results between the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation and the micro-nano SOI micro-ring electrooptic modulation, Free Spectrum Range, 3 dB Bandwidth, Q value, extinction ratio, and other parameters of the micronano Si/SiGe/Si double heterojunction micro-ring electrooptic modulation are better than others, and the modulation voltage and the modulation power are lower. So, the micronano Si/SiGe/Si double heterojunction electro-optic modulation structure is an ideal device structure to replace the traditional SOI and SiGe-OI electro-optic modulators structure. https://doi.org/10.1155/2018/8297650

Conflicts of Interest

The authors declare that they have no conflicts of interest.

Acknowledgments

This work was financially supported by National Natural Science Foundation of China (Grant no. 61204080), Natural Science Foundation of Shaanxi Province of China (Grant no. 2017JM6075), Foundation of Shaanxi Provincial Education Department (Grant no. 17JK0335), State Key Laboratory of Functional Materials for Informatics (Grant no. SKL201804), and Shaanxi Province Ordinary University Key Disciplines Construction Projects of Special Funds (Grant no. (2008)169).

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Song Feng (iD), (1, 2) Lian-bi Li (iD), (1) and Bin Xue (1)

(1) School of Science, Xi'an Polytechnic University, Xi'an 710048, China

(2) State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, 865 Changning Road, Shanghai 200050, China

Correspondence should be addressed to Lian-bi Li; xpu_lilianbi@163.com

Received 26 October 2017; Accepted 20 March 2018; Published 2 May 2018

Academic Editor: Zaiquan Xu

Caption: Figure 1: Si/SiGe/Si-OI structure.

Caption: Figure 2: Two type modulation structures: (a) SOI structure and (b) SiGe-OI structure.

Caption: Figure 3: The band diagram of Si/SiGe/Si-OI structure under the equilibrium state.

Caption: Figure 4: The band simulation of three type modulation structures: (a) Si/SiGe/Si-OI structure, (b) SiGe-OI structure, and (c) SOI structure.

Caption: Figure 5: At 1V forward voltage, the band simulation of three type modulation structures: (a) Si/SiGe/Si-OI structure, (b) SiGe-OI structure, and (c) SOI structure.

Caption: Figure 6: The relationship between the carriers concentration and modulation voltage: (a) electron concentration and (b) hole concentration for three structures.

Caption: Figure 7: (a) Schematic diagram of device, (b) LSCM of device, (c) SEM of micro-ring structure, and (d) SEM of device.

Caption: Figure 8: The transmission spectrum of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation.

Caption: Figure 9: The transmission spectrum of the micro-nano SOI micro-ring electro-optic modulation.

Caption: Figure 10: The static modulation of the micro-nano Si/SiGe/Si double heterojunction micro-ring electro-optic modulation.

Caption: Figure 11: The static modulation of the micro-nano SOI micro-ring electro-optic modulation.
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Title Annotation:Research Article
Author:Feng, Song; Li, Lian-bi; Xue, Bin
Publication:Advances in Condensed Matter Physics
Article Type:Report
Geographic Code:1USA
Date:Jan 1, 2018
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