Printer Friendly

Properties of calcium acetate manufactured with etching waste solution and limestone sludge as a cementitious high-early-strength admixture.

1. Introduction

Several methods such as accelerated curing and the use of precast concrete and construction robots are used for increasing the production rate in ferroconcrete construction [1-7]. In particular, it is important to reduce the concrete curing time to reduce the overall concrete construction period. The overall performance and development of concrete are significantly influenced by both the curing process and the subsequent cast removal. Some of the methods currently used to improve these characteristics include steam curing and the use of high-early-strength admixtures (HESAs) [813]. Accelerated curing however requires the use of costly equipment. On the other hand, in the case of HESAs, an admixture addition of just 1-3 wt% is required to enhance the concrete performance, rendering this method more cost-effective. In addition, with an increase in the use of blended cements and cementitious composites, the use of various HESAs as a supplement to low-early-strength cements such as the ground-granulated blast-furnace slag has increased to improve their performance [14-17]. The primary mechanisms for such HESAs include the enhancement of the production of calcium silicate hydrate (C-S-H) using highly soluble calcium ions or increasing the hydration of amphoteric aluminum ions [18-21]. Generally, calcium nitrate, calcium chloride, and highly soluble calcium formate (CF) are used as HESAs to produce calcium salts, and amine mixtures are used to enhance the hydration of aluminum ions [9, 22, 23].

The semiconductor and steel industries produce a wide array of by-products including acetic acid and calcium salts. The amount of chemical substances used for etching thin film transistor-liquid crystal display boards in the semiconductor industry continues to increase. Etching is used to corrode a material with chemicals such as nitric acid and acetic acid to polish its surface and create a product with desired properties. The chemicals used for etching can be recycled by distillation [24]. Such substances have a lower solid content than the pure substances and use water as a solvent. According to the World Steel Association, the total global steel production in 2014 was over 12,700,000,000 tons [25]. The process of steelmaking commences by cleansing limestone, which is obtained by dehydration of the by-products produced during desulfurization, with water to produce quicklime. The quicklime so obtained is used as a raw material to produce steel. During this process, small limestone particles (<1mm) are separated by precipitation and thus lime stone sludge (LSS) can be manufactured through a filter press process. LSS contains large quantities of water, which renders it uneconomical for recycling [26].

In this study, we manufactured a calcium-containing HESA (calcium acetate, CA), which is a source of calcium ions, by reacting acetic acid with LSS, which is a by-product of various industrial processes and evaluated the performance of the admixture so obtained. For a thorough evaluation, we examined the viscosity, density, pH, calcium content, heavy metal content, and solid content of the resultant admixture. We also added this admixture in different weight ratios to cementitious composites or mortars and examined their fluidity, setting time, pH, and compressive strength. We also carried out an X-ray diffraction (XRD) analysis of the cementitious composites or mortars containing this admixture.

2. Materials and Methods

2.1. Materials

2.1.1. Limestone Sludge. In this study, LSS, which is obtained from industrial by-products, was used to manufacture the calcium-containing HESAs. The XRD pattern and chemical composition analyses of LSS are shown in Figure 1 and Table 1, respectively. The XRD patterns of both CaC[O.sub.3] and LSS showed the presence of a CaC[O.sub.3] peak at approximately 29[degrees]. The structure of LSS appears to be identical to that of CaC[O.sub.3]. However, considering the chemical composition, the CaO content in LSS was approximately 5.84% lesser than that in CaC[O.sub.3]. In addition, LSS also contained Si[O.sub.2] and metallic salts such as [Al.sub.2][O3] and [Fe.sub.2][O.sub.3].

2.1.2. Recycled Acetic Acid. Recycled acetic acid (RAA) was obtained from the previous etching processes by extraction via an acid separation process. In this study, approximately 60% RAA was used. Figure 2 shows the Fourier transform infrared (FT-IR) spectrum of RAA. In the FT-IR spectrum of RAA, the peaks in the range of 3300-2500 [cm.sup.-1] correspond to organic acids containing carboxylic groups. The peaks associated with C=O groups (1760-1690 [cm.sup.-1]) and C-O groups (1320-1210 [cm.sup.-1]) can also be observed in this spectrum. Some examples of carboxylic acids include acetic acid, formic acid, gluconic acid, and propionic acid. Hence, it was confirmed that RAA contained carboxylic acid groups [27].

2.1.3. Binder and Sand. A comparison between the properties of the conventional HESAs and the admixture produced in this study was performed by using mortar specimens. The mortar specimens consisted of class I ordinary Portland (OPC). The chemical compositions and physical properties of these materials are given in Tables 2 and 3, respectively. A description of the sand used in this study is given in Table 4.

2.2. Methods

2.2.1. Overview. In this study, we manufactured both the CA and the mortars containing CA in different weight ratios (0, 1.2, and 3 wt%) and evaluated the performance of these mortars. The viscosity, density, and pH of these mortars were evaluated. Their inductively coupled plasma mass spectroscopy (ICP-MS) analyses were also performed. In addition, an existing HESA (CF) was also added to mortar in different weight ratios (0, 1, 2, and 3wt%) to obtain CF-mortars and their CF content, setting time, XRD patterns, and pH were also investigated. The flowbehavior and compressive strength of the mortars were also measured. Table 5 summarizes these experiments. The flow chart for the synthesis of CA is shown in Figure 3.

2.2.2. Manufacturing CA with LSS and RAA. Here, RAA and LSS reacted to yield CA in accordance with (1). The yield was maximum when the ratio of acetic acid to CaC[O.sub.3] was 2: 1 with 1 mol each of CA, water, and carbon dioxide per mol of CaC[O.sub.3]:

2C[H.sub.3]COOH + CaC[O.sub.3] = Ca [(C[H.sub.3]COO).sub.2] + [H.sub.2]O + C[O.sub.2] (1)

Calcium carbonate and RAA were used to compare the solubility of the LSS and acetic acid together. To 60% solid acetic acid, LSS was added in different weight ratios (1, 1.5, or 2) as shown in Table 6. This mix was reacted for 12 h. Upon mixing, the unreacted particles were removed via filtering and acetic acid was separated for future use.

2.2.3. Cementitious Composites with HESAs. The mix proportions of the cementitious composites (cement paste and mortar) that were mixed with HESAs are given in Table 7. The CA (used as a HESA) was weighed such that the weight ratio of LSS to acetic acid was 2: 1 and the pH of the overall mixture was 5.9. The manufactured specimen underwent steam curing at a temperature of 20[degrees]C and a relative humidity of 60%.

The paste specimens were produced by mixing 0,1,2, and 3% of CA and CF each with 100 g of OPC at a water to binder ratio of 0.32 for 3 min. The setting time and pH of these specimens were evaluated. Their XRD patterns were also analyzed. The setting time was measured according to ASTM C191. The pH measurements were performed by collecting 10 mL of each material after binding and subsequently immersing them in 100 g of distilled water. The results were recorded at 60 min and 24 h, in triplicate. For the XRD analysis, 30 g of the cured paste specimen was collected after 18 and 24 h, following which it was broken down into particles of < 300 [micro]m diameter of the particles and finally immersed in acetone. The X-ray diffractometer was operated at 45 KV and 40 mA with Cu radiation. A scan rate of 5[degrees]/min was maintained over a range of 5-60[degrees].

The cement mortar was manufactured by adding 135 g of sand to the paste composites. The sand and paste composites were mixed for 3 min, allowed to rest for 2 min, and finally mixed for additional 2 min. The flow of the mixed specimen was measured according to ASTM C230. For each mixture, molds with the dimensions of 4 cm x 4 cm x 16 cm were formed, cured for 18 h, and were immediately removed. The compressive strength was measured according to ASTM C109 at the intervals of 1, 3, 7, and 28 days, in triplicate.

3. Results and Discussion

3.1. CA

3.1.1. pH and Density of CA. The results of the viscosity and density measurements of the manufactured CA are shown in Figure 4. The viscosity and density of the CA solutions (containing CaC[O.sub.3] and LSS in weight ratios) showed similar trends. The viscosity and density of the CA solutions increased with an increase in the weight ratios of CaC[O.sub.3] and LSS. The density of acetic acid is 1.049 g/[cm.sup.3] and that of the CA is 1.509 g/[cm.sup.3]. Thus, as a greater quantity of acetic acid reacts with CaC[O.sub.3] to produce the CA, the density of this reactant increases.

3.1.2. pH and Ca Ion-ICP Analysis. Figure 5 shows the results of the pH measurement and Ca Ion-ICP analysis of the manufactured CA. The pH appeared to increase slightly when calcium carbonate was used. Conversely, the pH was low when LSS was used as it contains small quantities of Ca. However, when the weight ratio of LSS was greater than 2, the pH of the CA produced using CaC[O.sub.3] was similar to that obtained when LSS was used for producing the CA.

3.1.3. Microelement Analysis. Table 8 shows the results of the ICP analysis of heavy metals of the manufactured CA. The microelements and solid contents of the manufactured CA are listed in Table 8. Heavy metals were not detected, indicating that the CA manufactured in this work is less hazardous to the environment than the other similar materials [34].

3.2. Cement Composites

3.2.1. Flow and Setting Time of Mortar. Figures 6 and 7 display the flow and setting times, respectively, of the cement mortar obtained by mixing CA with cement. It was found that, for the CA-mortar, the fluidity increased with an increase in the CA content, as shown in Figure 6. However, in the case of the CF-mortar, the fluidity decreased with an increase in the CF content.

From Figure 7, it can be observed that when CF was used and the mixing ratio was identical for the CA- and CF-mixed mortars, the initial and finish setting times were reduced. In the case of the CA-mortar, the initial setting time was reduced when the mixing ratio increased. At a CA content of 1%, a minimum final setting time was obtained, which increased as the mixing ratio increased. In case of the CF-mortar, no reversible change in the setting time was observed with a change in the mixing ratio, and the setting time decreased proportionally with a decrease in the mixture ratio.

3.2.2. Change in pH of Cement Paste. The pH values of the cement pastes, as a function of time, are given in Table 9. In the case of the paste containing the CA, the pH initially decreased with an increase in the CA content. On the other hand, in the case of the paste containing CF, the pH remained relatively constant regardless of the CF content. When the CA content exceeded 1%, the setting time was reduced. Bortoluzzi et al. reported that when Ca[Cl.sub.2] (pH = 4.4) is mixed with cement, the pH of the cement decreases. The pH subsequently recovers because of the production of [Ca.sup.2+], which reduces the setting time [35]. When 3% CA is mixed, the hydration time decreases to 24 h and a retarding phenomenon can be observed. When CA content is more than 2%, both initial pH decrease and setting time delay were observed because of the high solubility of CA and residual acetic acid.

3.2.3. Compressive Strength of Mortar. Figure 8 shows the compressive strengths of the CA- and CF-mortar specimens at different curing times. When a CA content of 1% was used, the compressive strength of the resulting mixture was 22% greater than that obtained when no admixture was added (i.e., for a standard specimen). When the CF content in the mortar was 2%, similar strengths were obtained. When 3% CF was mixed and the mix was cured for seven days, the strength of the resulting mortar was found to be greater than that of the standard material. However, the strength started decreasing after 28 days. When 1% CA was mixed and the mix was cured for three days, the strength of the resulting mortar was over 40% greater than that of the standard specimen and was still 14% greater even after 28 days. However, when the CA content exceeded 2%, the compressive strength of the material diminished because of the reduction in both the pH of the cement paste and the hydration of acetic acid.

3.2.4. XRD. The XRD analysis was performed on the CA-and CF-mortars. Figure 9 shows the XRD patterns of the CA-mortars with different CA contents after a curing period of one day. When 1% CA was mixed, the intensity of the Ca[(OH).sub.2] peak decreased, while that of the calcium aluminosilicate hydrate (C-A-S-H) and C-S-H peaks increased, indicating rapid hydration. The CA-mortar having a CA content of 3% showed a weaker Ca[(OH).sub.2] peak than that of the mortar containing no admixture. However, in the case of the CA-mortar containing 1% admixture, this peak was more intense, and the intensity of the C-A-S-H and C-S-H peaks was also lower. In contrast, the intensity of the ettringite peak increased as the CA content increased.

The XRD patterns of the CF-mortars with different CF contents after a curing period of one day are shown in Figure 10. When 1% CF was mixed, the intensity of both the Ca[(OH).sub.2] and C-A-S-H peaks increased. When 3% CF was mixed, the intensity of both the Ca[(OH).sub.2] and C-A-S-H peaks decreased, while that of the ettringite and C-S-H peaks increased. As reported by Heikal [36], the diffusion rate of HCOO- ions is greater than that of [Ca.sup.2+] ions. Therefore, it is possible for HCO[O.sup.-] ions to penetrate into the protective layer of C-S-H. As a result, the C-S-H decomposition is directly proportional to the deposition of Ca[(OH).sub.2]. In addition, Ramachandran [37] stated that the presence of COOH- ions promotes the hydration of C3S by interfering with the protective layer of cement particles, which ultimately leads to the formation of ettringite. It was found that the structure of the CA- and CF-mortars containing 1% CA and CF, respectively, was similar, and both the mortars enhanced the production of C-A-S-H, ettringite, and C-S-H during the initial early stages of concrete formation [38].

The XRD patterns of the CA- and CF-mortars cured for three days are shown in Figures 11 and 12, respectively. In the case of the CA-mortar containing 1% CA, ettringite, the Ca[(OH).sub.2], and C-A-S-H peaks were more intense, as shown in Figure 11. When 3% CA was mixed, the intensity of the Ca[(OH).sub.2] and C-A-S-H peak decreased, while that of the ettringite and C-S-H peaks increased. In the case of the CA-mortar containing 1% CF, ettringite, the Ca[(OH).sub.2], and C-AS-H peaks were more intense, as shown in Figure 11. When 3% CA was mixed, the intensity of the Ca[(OH).sub.2] and C-A-SH peak decreased, while that of the ettringite peaks increased as shown in Figure 12.

When Al ion content is the same, Ca[(OH).sub.2] and C-A-SH increase according to the increase of Ca ion [39]. Thus, when CA and CF contents are 1%, Ca[(OH).sub.2] and C-A-S-H increased. On the other hand, according to the increase of CA and CF contents, Ca[(OH).sub.2] and C-A-S-H peaks decreased.

While the pH of CF is 7.0 and its solubility is 166 g/L, the pH of CA is about 5.9 and its density is 247 g/L. High solubility of CA affected both ettringite generation and decrease of Ca[(OH).sub.2] and C-A-S-H peaks [40].

4. Conclusions

CA was manufactured using acetic acid and LSS obtained from industrial by-products, and its characteristics were examined. The performances of the cementitious composites mixed with this manufactured CA were evaluated. On the basis of the results obtained, the following conclusions were made:

(1) The pH of the CA manufactured via the reaction of CaC[O.sub.3] and LSS was found to be the same as that of the CA manufactured using CaC[O.sub.3] (5.9). The microelemental analysis showed that the heavy metal content in the manufactured CA was lower than the detection limits.

(2) The compressive strength of the CA-mortars was maximum when 1% CA was mixed. This value of compressive strength was more than that obtained when no admixture was added even when the specimens were cured for 28 days. In particular, on the 28th day, the CA-mortar showed a higher compressive strength than that of the CF-mortar.

(3) For the cement pastes mixed with CF, the pH remained constant at all the mixing ratios. However, when the CF content exceeded 1%, CA, which is more acidic, had a greater influence on the mixture, leading to a reduction in the pH and strength of the cement, for the hydrates of the hardened cement pastes mixed with the CA and CF, which is advantageous for the enhancement of the C-S-H and ettringite.

(4) Finally, we can conclude that the CA is manufactured using the recycled industrial by-products functions as an effective HESA for cement composites.

http://dx.doi.org/10.1155/2016/2920370

Competing Interests

The authors declare that there are no competing interests regarding the publication of this paper.

Acknowledgments

This research was supported by a Grant (15CTAP-C07792902) from Technology Advancement Research Program funded by Ministry of Land, Infrastructure and Transport of Korean government.

References

[1] ACI, "Accelerated curing of concrete at atmospheric pressure-state of the art," ACI Committee 5172R-87, American Concrete Institute, 1992.

[2] ACI, Building Code Requirements for Structural Concrete, ACI Committee 318, American Concrete Institute, Farmington Hills, Mich, USA, ACI 318-95 edition, 1995.

[3] ACI, Building Code Requirements for Structural Concrete, ACI Committee 318, American Concrete Institute, Farmington Hills, Mich, USA, ACI 318-99 edition, 1999.

[4] ACI, Building Code Requirements for Structural Concrete, ACI Committee 318, American Concrete Institute, Farmington Hills, Mich, USA, ACI 318-02 edition, 2002.

[5] ACI, Building Code Requirements for Structural Concrete, ACI Committee 318, American Concrete Institute, Farmington Hills, Mich, USA, ACI 318-05 edition, 2005.

[6] ACI, Building Code Requirements for Structural Concrete, ACI Committee 318, American Concrete Institute, Farmington Hills, Mich, USA, ACI 318-08 edition, 2008.

[7] T Soleymani, V. Trianni, M. Bonani, F Mondada, and M. Dorigo, "Bio-inspired construction with mobile robots and compliant pockets," Robotics and Autonomous Systems, vol. 74, pp. 340-350, 2015.

[8] A. M. Ramezanianpour, K. Esmaeili, S. A. Ghahari, and A. A. Ramezanianpour, "Influence of initial steam curing and different types of mineral additives on mechanical and durability properties of self-compacting concrete," Construction and Building Materials, vol. 73, pp. 187-194, 2014.

[9] S. Aggoun, M. Cheikh-Zouaoui, N. Chikh, and R. Duval, "Effect of some admixtures on the setting time and strength evolution of cement pastes at early ages," Construction and Building Materials, vol. 22, no. 2, pp. 106-110, 2008.

[10] K. Hoang, H. Justnes, and M. Geiker, "Early age strength increase of fly ash blended cement by a ternary hardening accelerating admixture," Cement and Concrete Research, vol. 81, pp. 59-69, 2016.

[11] F. Messina, C. Ferone, F. Colangelo, and R. Cioffi, "Low temperature alkaline activation of weathered fly ash: influence of mineral admixtures on early age performance," Construction and Building Materials, vol. 86, pp. 169-177, 2015.

[12] C. Cetin, S. T. Erdogan, and M. Tokyay, "Effect of particle size and slag content on the early hydration of interground blended cements," Cement and Concrete Composites, vol. 67, pp. 39-49, 2016.

[13] G. Le Saout, B. Lothenbach, A. Hori, T. Higuchi, and F. Winnefeld, "Hydration of Portland cement with additions of calcium sulfoaluminates," Cement and Concrete Research, vol. 43, no. 1, pp. 81-94, 2013.

[14] H. Huang and X.-D. Shen, "Interaction effect of triisopropanolamine and glucose on the hydration of Portland cement," Construction and Building Materials, vol. 65, pp. 360-366, 2014.

[15] T.-B. Min, I.-S. Cho, W.-J. Park, H.-K. Choi, and H.-S. Lee, "Experimental study on the development of compressive strength of early concrete age using calcium-based hardening accelerator and high early strength cement," Construction and Building Materials, vol. 64, pp. 208-214, 2014.

[16] B. E. I. Abdelrazig, D. G. Bonner, D. V. Nowell, J. M. Drans-Field, and P. J. Egan, "Effects of accelerating admixtures on cement hydration, admixture for concrete," in Improvement of Properties, pp. 120-136, Chapman and Hall, Barcelona, Spain, 1990.

[17] R. Chidara, R. Nagulagama, and S. Yadav, "Achievement of early compressive strength in concrete using Sporosarcina pasteurii bacteria as an admixture," Advances in Civil Engineering, vol. 2014, Article ID 435948, 7 pages, 2014.

[18] X. Zhu, H. Hou, X. Huang, M. Zhou, and W. Wang, "Enhance hydration properties of steel slag using grinding aids by mechanochemical effect," Construction and Building Materials, vol. 29, pp. 476-481, 2012.

[19] J. Han, K. Wang, J. Shi, and Y. Wang, "Mechanism of triethanolamine on Portland cement hydration process and microstructure characteristics," Construction and Building Materials, vol. 93, pp. 457-462, 2015.

[20] E. Erdem, M. E. Gunay, and R. Donat, "Hydration and mechanical properties of Portland cement containing eloxal waste from aluminium industry," Journal of Materials Processing Technology, vol. 136, no. 1-3, pp. 35-38, 2003.

[21] W. Li, S. Ma, Y. Hu, and X. Shen, "The mechanochemical-process and properties of Portland cement with the addition of new alkanolamines," Powder Technology, vol. 286, pp. 750-756, 2015.

[22] H. Justnes and E. C. Nygaard, "Technical calcium nitrate as set accelerator for cement at low temperatures," Cement and Concrete Research, vol. 25, no. 8, pp. 1766-1774, 1995.

[23] P. C. Hewlett, Lea's Chemistry of Cement and Concrete, Arnold, London, UK, 4th edition, 1988.

[24] C.-H. Shin, J.-Y. Kim, J.-Y. Kim et al., "Recovery of nitric acid from waste etching solution using solvent extraction," Journal of Hazardous Materials, vol. 163, no. 2-3, pp. 729-734, 2009.

[25] World Steel Association, "November 2015 crude steel production," 2015, https://www.worldsteel.org/media-centre/pressreleases/2015/November-2015-crude-steel-production-.html.

[26] S. K. Seo, Y. S. Chu, K. B. Shim, J. K. Lee, H. Song, and Y. M. Yun, "A study on the application limestone sludge to the flue gas desulfurization process," Journal of the Korean Ceramic Society, vol. 51, no. 6, pp. 575-583, 2014.

[27] N. A. Aslam and S. A. Babu, "Direct lactonization of a-amino [gamma], [delta]-unsaturated carboxylic acid esters via olefin activation: stereo- and regioselective production of homoserine lactone scaffolds having contiguous stereocenters," Tetrahedron, vol. 70, no. 37, pp. 6402-6419, 2014.

[28] ASTM, "Standard Test Methods for Rheological Properties of Non-Newtonian Materials by Rotational Viscometer," ASTM D 2196, 2015.

[29] ASTM, "Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter," ASTM D 4052-11, 2011.

[30] ASTM, "Standard practice for preparation of water samples using reductive precipitation preconcentration technique for ICP-MS analysis of trace metals," ASTM D 6800-12, 2012.

[31] ASTM, "Standard test Method for time of Setting of Hydraulic cement by Vicat needle," ASTM C 191, 2006.

[32] ASTM, "Standard specification for flow table for use in tests of hydraulic cement," ASTM C230/230M-14, 2014.

[33] ASTM, "Test method for compressive strength of hydrolic cement mortars," ASTM C109, 2006.

[34] Japan Society of Civil Engineers, Concrete Library 111, Leaching Minor Elements from Concrete, Japan Society of Civil Engineers, Tokyo, Japan, 2005.

[35] E. A. Bortoluzzi, N. J. Broon, M. A. Hungaro Duarte, A. C. C. de Oliveira Demarchi, and C. M. Bramante, "The use of a setting accelerator and its effect on pH and calcium ion release of mineral trioxide aggregate and white portland cement," Journal of Endodontics, vol. 32, no. 12, pp. 1194-1197, 2006.

[36] M. Heikal, "Effect of calcium formate as an accelerator on the physicochemical and mechanical properties of pozzolanic cement pastes," Cement and Concrete Research, vol. 34, no. 6, pp. 1051-1056, 2004.

[37] V. S. Ramachandran, Concrete Admixtures Handbook: Properties, Science and Technology, chapter 3, Noyes Publications, New York, NY, USA, 2nd edition, 1995.

[38] S. Popovics, "Admixtures," in Concrete Materials: Properties, Specifications, and Testing, chapter 6, pp. 236-246, William Andrew Publishing/Noyes Publications, 2nd edition, 1992.

[39] K. Scrivener, R. Snellings, and B. Lothenbach, A Practical Guide to Microstructural Analysis of Cementitious Material, CRC Press, New York, NY, USA, 2016.

[40] V. Dodson, Concrete Admixtures, chapter 4, Van Nostrand Reinhold, New York, NY, USA, 1990.

Deuck-Mo Kim, (1) Hwa-Sung Ryu, (1) Sang-Heon Shin, (1) and Won-Jun Park (2)

(1) Hanyang Experiment and Consulting, Hanyang University, ERICA Campus, Ansan 15588, Republic of Korea

(2) Department of Building System Engineering, Kangwon National University, Samcheok 25913, Republic of Korea

Correspondence should be addressed to Hwa-Sung Ryu; rhsung73@hanyang.ac.kr

Received 1 February 2016; Revised 12 May 2016; Accepted 17 May 2016

Academic Editor: Kaveh Edalati

Caption: Figure 1: XRD patterns of CaC[O.sub.3] and LSS.

Caption: Figure 2: FT-IR spectrum of RAA.

Caption: Figure 3: Flow diagram for CA synthesis.

Caption: Figure 4: Viscosity and density of calcium acetate.

Caption: Figure 5: pH and Ca ion concentration of calcium acetate.

Caption: Figure 6: Flow test results.

Caption: Figure 7: Setting time tests results.

Caption: Figure 8: Compressive strength of specimens.

Caption: Figure 9: Specimen incorporating calcium acetate (1 day).

Caption: Figure 10: Specimen incorporating calcium formate (1 day).

Caption: Figure 11: Specimen incorporating calcium acetate (3 days).

Caption: Figure 12: Specimen incorporating calcium formate (3 days).
Table 1: Chemical composition of CaCO3 and LSS (%).

                     CaO     Si[O.sub.2]     MgO

CaC[O.sub.3]        96.08        0.98        2.06
Limestone sludge    90.46        3.81        1.06

                    [Al.sub.2]     S[O.sub.3]    [Fe.sub.2]
                     [O.sub.3]                    [O.sub.3]

CaC[O.sub.3]           0.39           0.02          0.36
Limestone sludge       2.06           0.08          1.35

                     [P.sub.2]    [K.sub.2]O    [Na.sub.2]O
                     [O.sub.5]

CaC[O.sub.3]           0.00          0.11           0.00
Limestone sludge       0.70          0.45           0.04

Table 2: Chemical composition of binder (%).

CaO       Si[O.sub.2]     MgO     [Al.sub.2]    S[O.sub.3]
                                   [O.sub.3]

63.85        21.09        3.32       4.84          3.09

CaO       [Fe.sub.2]    [P.sub.2]     [K.sub.2]O    [Na.sub.2]O
           [O.sub.3]    [O.sub.5]

63.85        2.39          0.36          0.73           0.14

Table 3: Physical properties of ordinary Portland cement (OPC).

                                            Setting time
Specific        Blaine specific
gravity     surface ([cm.sup.2]/g)      Initial        Final
                                       set (min)    set (hour)

3.15                 3400                 400            7

            Compressive strength of mortar (MPa)

Specific
gravity     3 days    7 days    28 days

3.15          20        23         38

Table 4: Properties of fine aggregate.

Maximum     Unit weight    Specific        Water        Solid volume
size (mm)      (kg/l)      gravity    absorption (%)   percentage (%)

<1.2            1.5          2.62          0.40             58.1

Table 5: Measurements and methods.

Experiment              Measurement sample      Properties measured

Calcium acetate          Calcium acetate          Viscosity (cps)
using limestone                               Density (kg/[m.sup.3])
sludge and recycled                                     ph
acetate                                           ICP-MS analysis

Cement matrix using        Cement paste            Setting time
accelerator                                             pH
                                                        XRD
                          Cement mortar                Flow
                                               Compressive strength

Experiment              Measurement sample           Standards

Calcium acetate          Calcium acetate         ASTM D 2196 [28]
using limestone                                 ASTM D 4052-11 [29]
sludge and recycled                                     --
acetate                                         ASTM D 6800-12 [30]

Cement matrix using        Cement paste           ASTM C191 [31]
accelerator                                             --
                                                        --
                          Cement mortar       ASTM C 230/230M-14 [32]
                                                  ASTM C109 [33]

Table 6: Reaction ratio according to weight ratio of RAA: CaCO3.

RAA : CaC[O.sub.3]         1:0.5     1:1     1:1.5     1:2

Reaction yield (%)           52       42       31     24.97
Reacted acetic acid (%)              80.8     91.6    99.86

Table 7: Mixtures for paste and mortar specimens.

Mixture number     OPC    Water     Calcium    Calcium     Sand
                                    acetate     formate

OPC                100      32         0                    135
OPC-A1 (a)         100      32         1                    135
OPC-A2             100      32         2                    135
OPC-A3             100      32         3                    135
OPC-F1 (b)         100      32                     1        135
OPC-F2             100      32                     2        135
OPC-F3             100      32                     3        135

(a) A = calcium acetate, 1 = cement x 1 wt%.

(b) F = calcium formate, 1 = cement x 1 wt%.

Table 8: ICP Analysis of heavy metals (mg/1).

                     Recycled           Limestone sludge :
                   acetic acid         recycled acetic acid

                                        2:1             2:1.5

Cd                 Not detected     Not detected    Not detected
Cr                 Not detected     Not detected    Not detected
Cu                      3               1.5             1.62
Hg                 Not detected     Not detected    Not detected
Pb                 Not detected     Not detected    Not detected
Mn                 Not detected     Not detected    Not detected
Zn                      3               1.5              1.7
As                 Not detected     Not detected    Not detected
Solid contents         62%              22%              27%

                    Limestone      Standard(A)
                    sludge :
                    recycled
                   acetic acid

                       2:2

Cd                Not detected        <0.1
Cr                Not detected         <2
Cu                    1.61             <3
Hg                Not detected       <0.005
Pb                Not detected         <1
Mn                Not detected         --
Zn                     1.9             <5
As                Not detected        <0.5
Solid contents         29%

(A) Water quality standards of Japan.

Table 9: pH of cement paste as a function of time.

                                          pH of cement paste as a
HESA                                         function of time

           Admixture proportion
               (cement x %)

                                  Immediate    60 minutes    24 hours

                   OPC               12.2         12.4         12.4

Calcium           OPC-A1             11.8         12.2         12.3
acetate           OPC-A2             10.2         11.0         12.1
                  OPC-A3             9.0          10.2         11.9

Calcium           OPC-F1             12.3         12.2         12.4
formate           OPC-F2             12.2         12.3         12.3
                  OPC-F3             12.1         12.2         12.1
COPYRIGHT 2016 Hindawi Limited
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2016 Gale, Cengage Learning. All rights reserved.

Article Details
Printer friendly Cite/link Email Feedback
Title Annotation:Research Article
Author:Kim, Deuck-Mo; Ryu, Hwa-Sung; Shin, Sang-Heon; Park, Won-Jun
Publication:Advances in Materials Science and Engineering
Date:Jan 1, 2016
Words:5061
Previous Article:Effects of calcination on the crystallography and nonbiogenic aragonite formation of ark clam shell under ambient condition.
Next Article:Experimental tests and analytical modelling of a scaled isolated structure on sliding and elastomeric bearings.
Topics:

Terms of use | Privacy policy | Copyright © 2019 Farlex, Inc. | Feedback | For webmasters