Photo-graftable UV absorber gets the yellow out.
Made by Clariant Corp., Charlotte, N.C., Sanduvor PR-25 is a non-staining, highly absorptive, photo-graftable stabilizer based on benzylidene malonate ester chemistry. It boasts much lower color development than traditional hydroxy-substituted benzophenones and benzotriazoles. It is said to have three times higher absorptivity than these uv absorbers and to also outperform hydroxyphenyltriazines. The latter represent another relatively new uv-absorber chemistry that is now available from a number of suppliers, including Ciba Specialty Chemicals, Tarrytown, N.Y., and Cytec Industries, West Patterson, N.J.
Keeps the yellow out
Clariant's product-development technical manager for additives, Joseph Webster, says PR-25 has a maximum uv absorptivity at least twice as high as that of hydroxy-substituted triazines and three times as great as traditional benzotriazoles and benzophenones.
Clariant initially introduced photoreactive chemistry in the form of Sanduvor PR31, a low-molecular-weight, methylated, monomeric HALS. Sanduvor PR25 has the same backbone chemistry as Sanduvor PR-31, minus the HALS (piperidine) functionality. Like PR-31, PR-25 remains mobile within the polymer until it becomes permanently grafted into place under the influence of light. PR25 is a white crystalline powder with a melting point of 131-134 F.
The four accompanying graphs show the performance of PR-25 in retarding color development compared with traditional uv absorbers or the newer triazines. Data on transparent, compression molded flexible PVC [ILLUSTRATION FOR FIGURE 1 OMITTED] shows PR-25 to outperform Ciba's Tinuvin P benzotriazole, traditionally a workhorse for flexible PVC, after 3000 hr of accelerated weathering.
Similarly, data on injection molded polycarbonate [ILLUSTRATION FOR FIGURE 2 OMITTED] show less color development with PR-25 after 700 hr of accelerated weathering than with either Ciba's Tinuvin 234 benzotriazole (a workhorse for polycarbonate) or Cyasorb HPT 1164 triazine from Cytec.
In molded PET [ILLUSTRATION FOR FIGURE 3 OMITTED], PR-25 also produces less yellowing before weathering than does Tinuvin 234 (commonly used in PET). The unweathered PR-25 sample is virtually indistinguishable from the control sample containing no uv stabilizer.
More interesting is color development in PET after 600 hr of accelerated weathering [ILLUSTRATION FOR FIGURE 4 OMITTED], where PR-25 still outperforms Tinuvin 234 benzotriazole.
Sanduvor PR-25 uv absorber is priced competitively with the benzotriazoles and newer triazines. It lists at $15.50/lb as compared with $14-28/lb for hydroxy-substituted benzotriazoles and $26-50/lb for the phenyltriazines.
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|Title Annotation:||Clariant Corp develops a non-staining, highly absorptive photo-graftable stabilizer|
|Comment:||Photo-graftable UV absorber gets the yellow out.(Clariant Corp develops a non-staining, highly absorptive photo-graftable stabilizer)|
|Author:||Sherman, Lilli Manolis|
|Date:||May 1, 1999|
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