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Performance And Emission Studies On Cashewnut Shell Liquid Bio-Oil Fuelled Diesel Engine With Acetone As Additive.

INTRODUCTION

Diesel engines are widely used for their low fuel consumption and better thermal efficiency. Also, fast depletion of petroleum fuels and its costs uncertainties have led to more rapid search for alternative fuels. Different vegetable oils such as soybean oil, castor oil, rapeseed oil, Jatropha curcas oil have been considered as alternative fuels for diesel engines [1]. Vegetable oils are not suitable direct replacements for diesel fuel in IC engines, due to their undesirable physical properties such as free fatty acid, lower pour points, lower calorific value, higher viscosities and higher flash points. These undesirable properties cause poor atomization, poor vapor-air mixing, low pressure, and incomplete burning and engine deposits. However, it is possible to reduce the viscosity of vegetable oil and remove the fatty acid content through dilution, pyrolysis, micro emulsion and esterification. Esterification is a kind of chemical reaction in vegetable oil is reacted with alcohol to form esters (biodiesel). Yongsheng Guo et al. [2] list the merits of biodiesel like biodegradable, nontoxic, low emission profiles compared to diesel. Essentially, no engine modifications are required to substitute biodiesel for diesel fuel that can maintain the engine performance. Vegetable oils and ACETONE are obtained from farm products and are renewable, degradable and friendly with the environment [3].

The world production yields of cashew crop, published by Food and agricultural organization (FAO), were around 2.7 million tons per annum. The major raw cashew producing countries with their production figures in 2005 (as per the UN's FAO) are Vietnam (960,800 tons), Nigeria (594,000), India (460,000 tons), Brazil (147,629 tons) and Indonesia (122,000 tons). India ranks first in area utilized for cashew production, though its yields are relatively low. Collectively, Vietnam, India and Brazil account for more than 90% of all cashew kernel exports. India is the largest producer and exporter of cashews, Anacardium occidentale Linn.,in the world. In India, Cashew cultivation now covers a total area of 0.70 million hectares of land, producing over 0.40 million metric tons of raw cashew nuts. The cashew nut shell is about 3mm thick, having a soft feathery outer skin and a thin hard inner skin. Between these skins is the honeycomb structure containing the phenolic material known as CNSL. Inside the shell is the kernel wrapped in a thin skin known as the testa. Mallikappa et al. [4] found the constituents of cashew nut shell that consists of kernel, kernel liquid, testa, rest being the shell. The base material for the manufacture of CNSL is the Cashew nut shells

Pyrolysis is one of the thermo chemical conversions in limited supply of oxygen [5]. In the cashew nut shell, cashew nut shell liquid occurs mainly as anacardic acid (~90%) and cardol around slightly lower than 10%. Risfaheri et al. [6] narrate the pyrolysis procedure of CNSL, the pyrolysis is done in a reactor at a negative pressure of 5kPa and at various maximum temperatures between 400-600oC, with an increase of 50[degrees]C for each experiment. The volatiles removed on pyrolysis are slowly condensed in a pre-weighed condensing container, from atmospheric condensation to condensation in cooled bath (5-7[degrees]C) [7]. The decarboxylated cardanol is termed as CNSL biodiesel. The biodiesel obtained from CNSL does not require further processing like transesterification.

The biodiesel fuelled diesel engine performance and combustion characteristics have been examined by many investigators [8]. The biodiesels used in their experiments were produced from different vegetable oils such as sunflower, rapeseed, soybean, karanja, rubber seed to name a few. Altiparmak et al. reported that CO, smoke, HC and PM emissions experienced a reduction trend with biodiesel and blends of biodiesel-diesel fuels compared to mineral diesel fuel operation [9]. The additives kerosene and ethanol were blended with Palm biodiesel-diesel blends to improve cold flow properties [10]. Cao et al. tested the effect of ethylene vinyl acetate copolymer on cold flow properties of waste cooking oil biodiesel [11]. However, there were some experimental outcomes reporting that the break power increases and NOx emissions decrease when using biodiesel as fuel in diesel engine. The change in power and higher NOx emissions can be experienced to the engine modifications, the fuelling method, after treatment method, test procedures and test conditions. The researchers found CNSL was used as CI engine fuel although the performance did not improve, because it was a low cost alternate fuel for CI engine [12, 13].

The engine performance with the biodiesel and the vegetable oil blends of various origins was similar to that of the neat diesel fuel with nearly the same brake thermal efficiency, showing higher specific fuel consumption. The experimental results especially on emissions of various studies are not uniform and show different results as can be seen in the literature. The main objective of this study is to improve the performance and reducing the emissions in the diesel engine by using oxygenated compounds in the diesel fuel. CNSL is the by-product of cashew industries; it is generally used for medical purposes and in rubber industries. As the calorific value of CNSL is high, we try to use it as an engine fuel and add additives to get the results nearer to that of mineral diesel fuel.

In the present research work, we interest to produce CNSL bio oil from the waste cashew nut shell and enhance the fuel's properties with Acetone additive. Diesel fuel and a blend of CNSL biodiesel 20% by volume mixed with Acetone additive in the volume ratio of 4, 8, and 12 percentages were tested in a direct injection, water cooled diesel engine at maximum load operations.

Experimental Details:

A. Experimental apparatus and procedure:

The engine used is Kirloskar make single cylinder, naturally aspirated, four stroke, water cool, 16.5:1 compression ratio, direct injection diesel engine, and the maximum engine power is 3.7 kW at 1500 rpm. A Kirloskar A.C generator with resistance bank loading arrangement was also incorporated. The main components of the experimental set up are combustion pressure and volume measurement (piezo electric sensor and shaft encoder) fuel flow sensor unit, electrical loading arrangement, voltmeter, ammeter, cooling water sensor unit and air flow sensor unit.

The outlet temperatures of cooling water and exhaust gas were measured directly from the thermocouples (Cr-Al) attached to the corresponding passages. All the data were interfaced with computer using software. The engine exhausts Nitrogen oxide, Carbon monoxide, Hydrocarbon, Carbon dioxide were measured with AVL-444 Di gas analyzer. The exhaust emissions were measured at 250 mm from the exhaust valve. The smoke opacity was measured by AVL-437C smoke meter after reducing the pressure and temperature in the expansion chamber. The engine speed was kept fixed at 1500 rpm. The engine was loaded step by step to keep the speed within the allowable range. After the engine reaches equilibrium condition, the various performances, combustion and emission characteristic parameters were observed and recorded. The accuracies of the measurements and the uncertainties determined by uncertainty analysis based on the Gaussian distribution method with a confidence limit of [+ or -] 2[sigma], and the calculated results are shown in Table I.

B. Test fuel and preparation of blends:

Mallikappa et al. [4] concluded that using 20% blend of CNSL biodiesel with diesel would give the anticipated results, so 20% blend is taken for analysis. Some authors narrate that addition of additives will improve on the drawback of biodiesel [14] and therefore in this study Acetone is taken as additive and observed the performance and emissions in C.I engine. The properties of fuel and additives are given in Table II. The CNSL bio oil is utilized to prepare the blends, the volume ratio of CNSL bio oil and diesel, 20/80 is called B20, and the volume ratio of B20 blend and 4%, 8%, 12% of Acetone is called B20+A4, B20+A8, and B20+A12 respectively.

RESULTS AND DISCUSSION

C. Combustion pressure and Crank angle:

In Fig. 1 the variation in the cylinder pressure with crank angle for B20 A12 blends at maximum engine load was shown.

The maximum pressure was observed at 66.6 bar, 64 bar and 47.8 bar for diesel, B20 and B20A12 respectively, at full loads. However the peak cylinder pressure obtained nearly the same crank angle positions that were 6 to 9 degree after top death centre for all fuels. It was clear that the peak cylinder pressure was lower for B20A12 bio oil blend operation, when compared to diesel fuel at the full load condition. The ignition delay is the vital parameter in the diesel engine combustion.

The combustion for biodiesel begins earlier than for diesel fuel combustion. This is because of short ignition delay and pre injection timing for biodiesel [15]. In spite of the slightly higher viscosity and lower volatility of biodiesel, the ignition delay seems to be lower for biodiesel than for diesel [16]. Due to the longer ignition delay, the peak cylinder pressure was reduced [17]. In this experiment, the ignition delay was calculated in terms of the crank angle degree. The ignition delay was measured by crank angle between the start of fuel injection and the start of burning.

D. Engine performances:

The Brake Specific Fuel Consumption (BSFC) was found to increase with the increasing proportion of biodiesel blends with diesel, whereas it decreased sharply with increase in load for all blends. For bio oil and various percentages of Acetone blends, the BSFC are higher than that of diesel. Lei Zhu et al. [18] attributed the increase of BSFC due to lower calorific value. It is observed that with increases in Acetone percentage in the blends the calorific value of the blend decreases. The brake thermal efficiency (BTE) obtained for different volumetric blends were recorded in Fig. 2. In general, the BTE increases gradually with the increasing the percentage of Acetone in the blends. This could be noted that the rich amount of oxygen in the blends, which might have resulted in its better combustion as compared to mineral diesel [19].

E. Pollutant Emissions:

The emission of Carbon monoxide (CO) with engine loading for tested fuels was compared in Fig. 3. The CO emitted by 4%, 8% and 12% addition of Acetone with B20 bio oil blends increase by 87, 83 and 82 percentages respectively at full load while comparing B20. The higher amount of oxygen content in the biodiesel and Acetone will lead to further oxidation of CO during combustion [19]. At the medium loads of engine, test fuels gave the lower CO emissions. It can be explained that the enriched oxygen in the combustion chamber produce the better turbulence caused increased piston mean speed. The sharp increase in CO emission at full load was because of the supply of rich mixture to the engine at higher load ranges [20].

HC emission is an important parameter for finding the exhaust emission behavior of the engines. It is observed from Fig. 4, the 4% Acetone blend with B20 gives relatively higher HC emissions at full load as compared with other blends. At low engine loads, the HC emissions increased because of the cooling skin of unburned Acetone present in the combustion chamber. In addition to that, the higher latent heat of vaporization of Acetone results in low combustion chamber temperature, which is the main factor to produce HC emissions. HC emission was reduced by 34% while the engine was operated by 12% Acetone with B20 when comparing neat diesel operation. The lowest percentage of HC emission was observed with 12% Acetone blend with B20 at full load, this is because of better combustion inside the combustion chamber.

The Nitrogen Oxide (NO) content in exhaust emissions of engine for various percentages of Acetone addition in B20, are plotted as a function of load in Fig. 5. From this figure, it can be seen that the NO emission decreases remarkably by 49.4% for 12% Acetone blends with B20, respectively at full load conditions. The NO level was depending directly to the exhaust gas temperature. This may be explained due to Acetone blended with B20 produces a cooling effect in the combustion chamber leading to reduction of NO emission. On the other hand, the higher oxygen content of B20 blend and premixed burning phase might result in high temperatures and hence higher NO formation [21].

The smoke content from the engine using biodiesel and its blends with diesel is shown in Fig. 6, as a function of engine load versus smoke opacity percentage. From this figure, it can be seen that B20 blend produced less smoke than diesel fuel operation. This is due to more amounts of oxygen molecules in the biodiesel which produce more burning efficiency as compared to mineral diesel. The B20+A4 blend produce more smoke emission at full load. The higher smoke emission influenced by the cooling effect of Acetone. In general higher smoke emission at full load for all fuel blend were observed. This is because, when the engine load is increased, more fuel is burned with inadequate air [22]. The smoke density reduced by 16% while the engine was operated by 12% Acetone with B20 when comparing neat diesel operation. The B20+A12 blend produce relatively less smoke emission for entire load operation then that of tested fuel blends.

Conclusions:

The CNSL bio oil was obtained from byproduct of cashew Industries. Some fuel properties of B20 such as cetane number, Calorific value, sulphur content, and flash point are very close to diesel fuel. In addition, Acetone as additive improves the lubricity. Exhaust gas emission for 12% Acetone blend reduces NO emission by 49.4 % and smoke opacity decreases by 17% at full load while comparing with diesel. In general, low NO and smoke emissions were measured with the 12% Acetone as additive in B20 blend. Therefore CNSL bio oil would be used as fuel in diesel engines in rural areas in India for their energy requirements. Hence CNSL can be alternately used as fuel for diesel engine. Consequently 20% CNSL bio oil and 12% Acetone as additive was the better alternate fuel blend for diesel engines without any engine modification.

ACKNOWLEDGEMENT

First of all, I am thankful to Almighty for making me to complete this paper presentation. I wish to convey my sincere thanks to our MANAGEMENT of KINGS COLLEGE OF ENGINEERING for providing me with all the necessary facilities. I place on record my sincere gratitude to our PRINCIPAL of KINGS COLLEGE OF ENGINEERING for his constant encouragement. I also place on record, my sense of gratitude to one and all who, directly or indirectly, have lent their helping hand in this venture.

REFERENCES

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[2.] Yongsheng Guo, Fengjun Yang, Yan Xing, Dan Li, Wenjun Fang and Ruisen Lin, 2009. Study on volatility and flash point of the pseudo binary mixtures of sunflower-based biodiesel+methylcyclohexane, Fluid Phase Equilibria, 276: 127-132.

[3.] Meher, L.C., D.Vidya Sagar and S.N. Naik, 2006. Technical aspect of biodiesel production by transesterification- a review, Renew Sustain Energy Rev.,10: 248-268.

[4.] Mallikappa, D.N., Rana Pratap Reddy and Ch. SN. Murthy, 2011. Performance and emission characteristics of stationary CI engine with cardnol bio fuel blends, Int. J. Scientific and Eng Research, 2: 1-6.

[5.] Maharnawar, A.P., 1994. Characterization and processing of CNSL, Master of Science (Technology) thesis, University of Bombay, India.

[6.] Risfaheri, Tun Tedja Irawadi, M. Anwar Nur, and Illah Sailah, 2010. Isolation of cardanol from cashew nut shell liquid using the vacuum distillation method, Indonesian Journal of Agriculture, 2: 11-20.

[7.] Piyali Das and Anuradda Ganesh, 2003. Bio oil from pyrolysis of cashew nut shell-a near fuel, Biomass Bioenergy, 25: 113-117.

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P.P. Shantharaman and T. Pushparaj, M. Prabhakar

(1) Dept. of Mechanical Engineering, Kings College of Engineering, Punalkulam-613303, Pudukkottai, Tamilnadu, India.

(2) Dept. of Mechanical Engineering, Kings College of Engineering, Punalkulam-613303, Pudukkottai, Tamilnadu, India.

(3) Dept. of Mechanical Engineering, TRP Engineering College, Irungalur- 621105, Thichy, Tamilnadu, India.

Received 14 September 2017; Accepted 15 October 2017; Available online 30 October 2017

Address For Correspondence:

P.P.Shantharaman, Dept. of Mechanical Engineering, Kings College of Engineering, Punalkulam-613303, Pudukkottai, Tamilnadu, India.

E-mail: ppshantharaman@yahoo.co.in

Caption: Fig. 1: Variations of cylinder pressure with respect to crank angle for B20A12 at 0.579MPa load.

Caption: Fig. 2: Comparison of BTE variation with load and fuel blends.

Caption: Fig. 3: Comparison of CO variation with load and fuel blends.

Caption: Fig. 4: Comparison of HC variation with load and fuel blends.

Caption: Fig. 5: Comparison of NO variation with load and fuel blends.

Caption: Fig. 6: Comparison of smoke opacity variation with load and fuel blends.
Table I: The Accuracies of measurements and the
Uncertainties in the calculated results

Measurements   Accuracy

Speed          [+ or -] 2 rpm
Temperature    [+ or -] 1oC
CO             [+ or -] 0.03 %
CO2            [+ or -] 0.5 %
NO             [+ or -] 50 ppm
HC             [+ or -] 10 ppm
Opacity        [+ or -] 0.1 %
Calculated     Uncertainty
  results
Brake power    [+ or -] 2.50 %
BSFC           [+ or -] 2.64 %
Pressure       [+ or -] 1 bar

Table II: Properties of the Fuel and Additive

* Properties                           No-2 Diesel   CNSL    Acetone

Kinematic Viscosity   [cSt]            2.82          29.77   0.46
Density               [kg/[m.sup.3]]   840           884     791
Lower Heating Value   [MJ/kg]          42.3          39.4    28.8
Cetane Number                          46            54      --
Flash Point                            70            157     -20
  [[degrees]C]

Note: * Producers data.
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Author:Shantharaman, P.P.; Pushparaj, T.; Prabhakar, M.
Publication:Advances in Natural and Applied Sciences
Article Type:Report
Date:Oct 1, 2017
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