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Nanoparticles Decorated on Resin Particles and Their Flame Retardancy Behavior for Polymer Composites.

1. Introduction

The interesting properties of thermoplastic polymers made them demanded in various applications. However, their poor thermal and bad flammability properties restrict some of their applications. One of these thermoplastic polymers is polystyrene (PS) which is inexpensive polymer and has characteristic features which are required in various industrial applications such as packaging, appliances, electronic, automobile, and electrical applications [1]. So, the study to enhance its thermal stability and flame retardancy properties is required and highly demanded. Usually to improve the thermal stability and flame resistance of thermoplastic polymers flame retardant materials have to be used as additives [2, 3]. Halogen-based flame retardants were used and these materials were found to be effective for flame retardation; however these materials were inhibited due to their associated environmental pollution [4-6]. There are tremendous efforts to find alternative effective flame retardant materials to replace halogenated ones. Phosphorus containing flame retardants has been used which was based on condensed phase action through char forming effect [7, 8]. Also, metal hydroxides have been used as flame retardants additives but their high effective loading was attributed to poor dispersion and drawbacks in mechanical properties of polymer composites [9,10]. Furthermore, the use of combination of charring agent, blowing agent, and acid source termed as intumescent flame retardant achieved good flame retardancy of polymer composites and low toxic gas emission [11-13]. On the other hand, various aluminosilicates have been used as flame retardants fillers such as montmorillonites [14], halloysite nanotubes [15], and zeolites [16]. These materials were used alone and in conjunction with other conventional flame retardant materials as synergistic fillers [17,18]. Interestingly, there are research trend to find alternative potential synergistic additive with intumescent flame retardant systems [17,19]. This is in addition to the use of other various nanomaterials as flame retardant fillers such as organoclay [20], metal oxide nanoparticles [21], carbon nanotubes [22], and graphene sheets [23]. These materials improved the mechanical and flame resistance properties of polymer nanocomposites. In our recent investigations, graphene sheets, organic nanoparticles, metal hydroxide nanoparticles, and polymer nanofibers have been used as flame retardant for polymer nanocomposites [24-27]. This is in conjunction with flammability study of various textile fabrics [28,29]. This is in conjunction with our experience in synthesis and characterization of various nanomaterials [30]. In this study, we report for the first time novel one pot method for the synthesis of Amberlite IR120 resin- (AR-) phosphorus based flame retardant system. This involved the decoration of AR with Ti[O.sub.2] nanoparticles (Ti[O.sub.2]NPs) of an average particle size of 21 nm in presence of maleate diphosphate as flame retardant (FR). The effect of functionalization AR with Ti[O.sub.2]NPs on the flammability and thermal stability of polystyrene nanocomposites was studied. Furthermore, the flame retardancy properties of polymer composites of AR and maleate diphosphate separately and together have investigated.

2. Experimental

2.1. Materials. Polystyrene with a grade 15NF for injection molding was purchased from LG Chem, Korea. Diethyl maleate was supplied by Merck, Schuchardt OHG 85662 hohenbrun, Germany. Amberlite IR120 resin was obtained from Sigma Aldrich Chemie GMBH, Germany. Ti[O.sub.2] nanoparticles with an average diameter of 21 nm and chloroform were purchased from Sigma Aldrich Chemie GMBH, Germany.

2.2. Synthesis of Flame Retardant (FR) Material. The maleate diphosphate was prepared according to previous report [31]. In this synthesis, in a round bottom flask 1 and 2 moles of diethyl maleate and phosphoric acid, respectively, were mixed and refluxed for 4 h at 120[degrees]C and, then, filtered and cooled at room temperature and coded as FR.

2.3. Synthesis of Resin-FR Composites and Resin-Ti[O.sub.2]NP-FR Nanocomposites. In a ceramic capsule of ball milling machine containing various zirconium oxide balls equal mass of AR and FR was added. Then, suitable volume of chloroform was added to the previous mixture. Afterwards, the ball milling machine rotated at 300 rpm for 12 h resulting in AR-FR composite. The previous mixture was repeated with replacing 5 and 10 wt% of ARwith Ti[O.sub.2] nanoparticles, separately. Then, the ball milling machine was rotated at the same rpm for the same time period producing nanocomposites AR-Ti[O.sub.2]NPFR-5 and AR-Ti[O.sub.2]NP-FR-10 based on AR mass.

2.4. Synthesis of Polystyrene Composites. In PS solution dissolved in chloroform, we disperse 30 wt% of FR and AR-based on final mass of the composites separately forming 30% composite of PS-FR and PS-AR, respectively. Then, mechanically stirred for 3 hours, afterwards the solvent was evaporated. In PS solution the composites FR-AR, AR-Ti[O.sub.2]NP-FR-5, and AR-Ti[O.sub.2]NP-FR-10 were mixed separately. Then, the mixtures were stirred for the same time afterwards; the solvent was evaporated and the samples were compressed and molded at 180[degrees]C for 10 min at 100 tones. Also virgin PS sample was molded as blank.

2.5. Characterization. FT-IR spectroscopic analysis was performed using a Nicolet 380 spectrophotometer (Thermo Scientific) in the wave number range 400-4000 [cm.sup.-1]. Thermogravimetric analysis was carried out using TGA 50 (TA Shimudzu, Inc.) under nitrogen atmosphere. The SEM images were then taken using a scanning electron microscope (Quanta FEG-250, operating at a voltage of 10 kV). TEM images were obtained using a JEOL (JEM-1400 TEM) with an accelerating voltage of 100 kV. The flammability properties of various composites and blank samples were conducted using flame chamber (UL94) by horizontal test according to IEC 60695-11-10 [32]. Furthermore, the flammability properties were investigated using cone calorimeter (Fire Testing Technology) according to ISO 5660-1 [33]. The properties obtained were peak heat release rate (PHRR), total heat release rate (THR), and average effective heat of combustion (AEHC). This is in addition to average mass loss rate(AMLR), time to ignition (iign), average heat release rate (AHRR), and emission of CO and C[O.sub.2] gases.

3. Results and Discussion

3.1. Structural Characterization of Resin-Flame Retardant Composites and Resin-Ti[O.sub.2]NP-FR Nanocomposites. Firstly the FR material (maleate diphosphate) used in the synthesis process was synthesized based on previous report [31]. The structure of the FR was confirmed using FT-IR spectroscopy. Figure 1 reflects the characteristic absorption bands of FR. The absorption band positioned at 1024 [cm.sup.-1] can be attributed to C-O-P stretching vibrations. The absorption band suited at 1718 [cm.sup.-1] corresponds to C=O stretching vibrations of ester [31]. The absorption band detected at 1638 [cm.sup.-1] is related to the C=C stretching vibrations. Moreover, the absorption band located at 1305 [cm.sup.-1] is specified to P=O stretching [31]. Interestingly, the absorption bands appear at 2984 and 2794 [cm.sup.-1] are assigned to symmetrical and asymmetrical absorption of the C-H group. The band observed at 3426 [cm.sup.-1] can be related to the O-H stretching vibrations [31].

Facile and effective method has been developed for the synthesis of AR-FR composites and AR particles were decorated with Ti[O.sub.2]NPs producing new flame retardant system. The AR-FR composite was prepared by mixing of AR and FR together in ball mill capsule filled with zirconium oxide balls. During the milling process the FR molecule wrapped AR surface. This was derived by the mechanochemical energy created from the collision between zirconium oxide balls and walls of capsule and with AR particles during milling process. Using the same process AR was doped with Ti[O.sub.2]NPs of an average particle size of 21 nm. The Ti[O.sub.2]NPs were dispersed on the surface of AR and then wrapped by FR which aid the doping process. The synthesis process was represented by the schematic diagram in Figure 2.

On the other hand, the morphology of the AR and Ti[O.sub.2]NPs individually and their decorated form was investigated using microscopic techniques. Figure 3(a) shows the TEM image of AR which has spherical shape and in micrometer range. However, Ti[O.sub.2]NPs were found in aggregated form of a spherical shape with an average particle diameter of 21 nm as seen in SEM image (Figure 3(b)). The Ti[O.sub.2]NPs have doped AR particles in well dispersed form as shown in Figures 3(c) and 3(d); then, the doped Ti[O.sub.2]NPs were wrapped by FR (Figure 3(d)). It is important to note that the ball milling process dispersed the aggregated form of Ti[O.sub.2]NPs which produced dispersed form of nanoparticles on the AR surface as seen in Figure 3(d).

3.2. Resin-Ti[O.sub.2]NP-FR Based Polystyrene Nanocomposites. Polystyrene nanocomposites of AR-Ti[O.sub.2]NP-FR and its composites with AR-FR, AR, and FR have been prepared individually through solvent blending method. The morphology of the nanocomposites was characterized using SEM. The dispersion of AR doped with nanoparticles in polymer matrix was elucidated by SEM images. Figure 4(a) shows the SEM image of blank PS. Figure 4(b) represents the morphology of PS-AR-Ti[O.sub.2]NP-FR-5 which clearly shows the well dispersion of AR-Ti[O.sub.2]NP-FR in polymer matrix. Furthermore, the uniform dispersion of high doping level (10% of Ti[O.sub.2]NPs) of AR with Ti[O.sub.2]NPs was also clarified as seen in Figure 4(c).

On the other hand, thermal stability of the new composites was studied using TGA as shown in the thermographs shown in Figure 5. Figure 5(a) represents the TGA graph of blank PS which decomposed in one step starting at 350[degrees]C leaving no char residue at 750[degrees]C. However, the thermogram of AR shows three steps of mass loss, the first one below 100[degrees]C due to the trapped moisture (Figure 5(b)). The second was started at 173[degrees]C and the main decomposition one started at 273[degrees]C leaving char residue of 25% at 750[degrees]C. The TGA graph of PS-FR starts with initial mass loss at 100[degrees]C which attributed to trapped moisture. The main mass loss starts at 288[degrees]C giving rise to char residue of 5% (Figure 5(c)). This low decomposition temperature of PS-FR corresponds to decomposition of FR material in the composite. Figure 5(d) depicted the TGA graph of PS-AR composite which reflects more thermal stability compared to PS-FR. The initial mass loss related to moisture content is detected at around 100[degrees]C and the onset of main decomposition step shifted to 351[degrees]C. However, the char residue was detected as 4.7% compared to PS-FR composite. The PS-AR-FR composite (Figure 5(e)) showed similar trend as PS-AR but main decomposition temperature is lowered to 305[degrees]C leaving enhanced char yield (9.4%). Interestingly, the thermal stability of PS-AR-Ti[O.sub.2]NP-FR-10 nanocomposite is enhanced compared to previous blank and composites. The onset main decomposition step is shifted to 370[degrees]C compared to 350[degrees]C in PS and char residue improved to 16.6% (Figure 5(f)). This enhanced thermal properties of PS-ARTi[O.sub.2]NP-FR-10 nanocomposite stemmed from the good char barrier forming isolating decomposition polymer zone from further decomposition.

3.3. Flame Retardancy of Polystyrene Composites and Nano-composites. The flammability properties of different PS composites were evaluated using two different tests. The first one was UL94 flame chamber according to horizontal test based on international standard IEC 60695-11-10 [32]. The flammability results of UL94 test were tabulated in Table 1. The blank PS was burned quickly giving burning rate of 46.5 mm/min. However, when FR additive was included in PS-FR composite the rate of burning was reduced to 23 mm/min (Table 1) and flame front stopped before reaching the end of the sample. This might be due to the liberation of phosphoric acid after combustion of polymer composite leading to char layer formation, which isolates the decomposition zone of polymer from flaming one. However, when FR was replaced with AR in the composite PS-AR the rate of burning was also reduced to 19.7 mm/min. This fire retardancy property of PS-AR was due to the decomposition of AR before polymer matrix leading to formation of char layer as seen in Table 1. The rate of burning of PS-AR-FR achieved higher degree of flame retardation (62% reduction), which might be stemmed from synergistic effect occurring in the polymer composite (Table 1). When the AR was doped with Ti[O.sub.2]NPs in the previous composite (PS-AR-FR). The new nanocomposite PS-AR-Ti[O.sub.2]NPFR-5 showed improved flame retardancy behavior, where the rate of burning was found to be 13.8 mm/min achieving 70% reduction compared to PS.

Interestingly, when the doping percent of Ti[O.sub.2]NPs increased to 10 wt.% in PS-AR-Ti[O.sub.2]NP-FR-10 the flammability has further reduced and flame stopped after 25 mm only from the first mark. This achieved significant reduction in rate of burning reaching to 10.7 mm/min (77%) as seen in Table 1. This enhanced flame resistance properties of the nanocomposites were attributed to the synergistic effect between FR and AR-Ti[O.sub.2]NP. The proposed action could be as follows. The phosphoric acid released earlier based on combustion of the nanocomposite reacted with the AR degradation products. This reaction was catalyzed by Ti[O.sub.2]NPs which formed strengthened char layer on the nanocomposites surface composed of new compound and effectively resists mass and heat transfer.

On the other hand, Figure 6 represents the heat release curve of PS which was ignited after 47 sec giving rise to very sharp heat release curve with PHRR of 1257 kW/[m.sup.2]. The THR, AEHC, and AHRR were recorded as 141MJ/[m.sup.2], 26 MJ/kg and 562 kW/[m.sup.2], respectively (Table 2 and Figure 6).

When organic FR was used the PS-FR composite achieved reduction in in PHRR by 34% (827kW/[m.sup.2]) and the THR was reduced to 70 MJ/[m.sup.2] (Table 2). The time required to ignite the sample is reduced to 37 sec; this is due to the decomposition of FR compound. Also the AEHC is reduced to 23 MJ/kg and AMLR is reduced to 0.031 g/s compared to 0.054 g/s for PS. This flame resistance behavior corresponds to the char layer formed by the liberation of phosphoric acid after combustion of polymer composite. The flammability properties of PS-AR were clearly reduced as the PHRR was found to be 675 kW/[m.sup.2] achieving 46% reduction (Table 2 and Figure 6). Also, the THR and AHRR were lowered to 86 MJ/[m.sup.2] and 253 kW/[m.sup.2], respectively. This is in addition to reduction in AEHC (Table 2). It is important to note that the time to ignition was extended to 60 sec. This was attributed to the action of AR in flame resistance of polymer composites. This could be proposed as, during the polymer composite heating, the AR decomposes earlier than polymer chains. This is attributed to liberation of sulphate group which triggered the formation char layer from AR [34]. This carbonaceous char structure usually contains pores which trapped the volatile combustible radicals, which then delayed the combustion as indicated in time to ignition and slow down the degradation rate of PS-AR (Table 3). This physical char layer eases up the degradation process and restricts the mass and heat transfer. This mechanism was supported by the reduction in AMLR to 0.028 g/s compared to 0.054 g/s for PS (Table 3).

The inclusion of FR and AR with equal mass ratio in PS-AR-FR composite reduced the PHRR to 704 kW/[m.sup.2]. This value, a little higher compared to PS-AR and lower than PSFR achieving synergistic effect as depicted in digital photos, showed dense char residue (Figure 7). However, the THR was found to be 99 MJ/[m.sup.2] and AHRR was 309 kW/[m.sup.2] as shown in Table 2. The time recorded to ignition is reduced to 53 sec compared to PS-AR. This might be due to collapse of carbonaceous structure of AR which traps combustible radicals. This is clearly confirmed by AMLR value recorded as 0.030 g/s. Interestingly, when the AR was doped with Ti[O.sub.2]NPs of an average diameter of 21 nm it resulted in PS-AR-Ti[O.sub.2]NP-FR10. The fire retardant data obtained from cone calorimeter was changed where the nanocomposite ignited faster than PS-AR and PS-AR-FR (44 sec). The PHRR was found to be 804 kW/[m.sup.2] with AHRR 340 kW/[m.sup.2]. However, the THR was significantly reduced compared to PS-AR and PS-AR-FR composites achieving 77 MJ/m (Table 2). This change in flammability behavior of PS-AR-Ti[O.sub.2]NP-FR-10 could be due to the existence of cone heater irradiating 35 kW/[m.sup.2] during all the test time in cone test. This is in conjunction to the existence of AR doped with Ti[O.sub.2]NPs, which take part in catalyzing the decomposition process of nanocomposites. On the other hand the emission of CO in PS-FR composite is almost similar to that in PS; but the C[O.sub.2] emission was reduced (Table 3). It is noteworthy to note that the emission of CO and C[O.sub.2] was reduced in PS-AR by 14 and 44, respectively (Table 3). The emission of CO in PS-AR-FR was higher than PS indicating incomplete combustion reaction, but C[O.sub.2] was reduced (0.92 kg/kg). Interestingly, in the PS-AR-Ti[O.sub.2]NPFR-10 the emission of CO increased to 0.065 kg/kg confirming incomplete combustion reaction; however the C[O.sub.2] reduced (1.22 kg/kg) compared to PS.

4. Conclusion

Smart and new flame retardant system has been developed for polystyrene. The flame retardancy and thermal stability of the polymer nanocomposites were improved significantly. Resin particles alone were found to be effective flame retardant of the polymer composites. Also, their use in conjunction with nanoparticles and flame retardant showed synergism flame retardant effect. Facile method for doping resin with Ti[O.sub.2] NPs was developed. The nanoparticles doped resin was well dispersed in polymer matrix. The rate of burning, PHRR, and AMLR of the new polymer composites were reduced by 77, 46, and 48%, respectively. This is in addition to the reduction in the emission of CO and C[O.sub.2] gases. The proposed action of fire retardancy of resin was studied. The good flame retardancy in nanocomposites was attributed to the formation of excellent protective char layer.

https://doi.org/10.1155/2017/7381787

Conflicts of Interest

There are no conflicts of interest regarding the publication of this paper.

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Nour F. Attia (1) and Mohamed Zayed (2)

(1) Fire Protection Laboratory, National Institute for Standards, P.O. Box 136, Giza 12211, Egypt

(2) Chemistry Department, Faculty of Science, Cairo University, Nahdet Misr Street, Giza 12613, Egypt

Correspondence should be addressed to Nour F. Attia; drnour2005@yahoo.com

Received 14 March 2017; Accepted 19 June 2017; Published 19 July 2017

Academic Editor: Jim Low

Caption: FIGURE 1: FTIR spectra of maleate diphosphate (FR).

Caption: FIGURE 2: Schematic diagram showing the synthesis of resin doped Ti[O.sub.2]NP-FR nanocomposites.

Caption: FIGURE 3: TEM images of resin (a), SEM image of Ti[O.sub.2] NPs (b), and TEM images of AR-Ti[O.sub.2]NP-FR nanocomposite (c) and AR-Ti[O.sub.2] NP-FR nanocomposite at high magnification (d).

Caption: FIGURE 4: SEM images of blank PS (a), PS-AR-Ti[O.sub.2]NP-FR-5 (b), and PS-AR-Ti[O.sub.2]NP-FR-10 (c) nanocomposites.

Caption: FIGURE 5: TGA curves of PS (a), AR (b), PS-FR (c), PS-AR (d), PSAR-FR (e), and PS-AR-Ti[O.sub.2]NP-FR-10 (f).

Caption: FIGURE 6: Heat release curves of PS (a), PS-FR (b), PS-AR (c), PSAR-FR (d), and PS-AR-Ti[O.sub.2]NP-10-FR (e).

Caption: FIGURE 7: Digital photos of the char residues after cone test for the PS, PS-FR, PS-AR, and PS-AR-FR composites.
TABLE 1: Rate of burning results of PS blank and their composites.

Sample code                  (a) Distance   (b) Time    (c) Rate of
                                 (mm)         (sec)        burning
                                                           (mm/min)

PS                                75           96.5          46.5
PS-FR                             65          170.5           23
PS-AR                             70          213.5          19.7
PS-AR-FR                         67.5          265           17.6
PS-AR-Ti[O.sub.2]NP-5-FR          60           267           13.8
PS-AR-Ti[O.sub.2]NP-10-FR         25           140           10.7

(a) Average distance burned, (b) average time used for burning, and
(c) average rate of burning.

TABLE 2: Cone calorimetric data of the PS, PS-FR, PS-AR, PS-AR-FR, and
PS-AR-Ti[O.sub.2]NP-FR composites.

Term [a]               PS    PS-FR   PS-AR   PS-AR   PS-AR-Ti[O.sub.2]
                                              -FR        NP-10-FR

V[s]                   47     37      60      53            44
PHRR [kW/[m.sup.2]]   1257    827     675     704           804
AHRR [kW/[m.sup.2]]   562     289     253     309           340
THR [MJ/[m.sup.2]]    141     70      86      99            77
AEHC [MJ/kg]           26     23      22      25            25

[a] [t.sub.ign]: time to ignition; PHRR: peak heat release rate; AHR:
average heat release; THR: total heat release; AEHC: average effective
heat of combustion.

TABLE 3: Smoke parameters of the PS, PS-FR, PS-AR, PS-AR-FR, and
PS-AR-Ti[O.sub.2]NP-FR composites.

Term [a]       PS     PS-FR   PS-AR   PS-AR   PS-AR-Ti[O.sub.2]
                                       -FR        NP-10-FR

AMLR [g/s]    0.054   0.031   0.028   0.030         0.033
CO [kg/kg]    0.051   0.053   0.044   0.056         0.065
C[O.sub.2]    1.64      1     0.92    0.92          1.22
  [kg/Kg]

[a] AMLR: average mass loss rate; CO: average emission of carbon
monoxide; C[O.sub.2]: average emission of carbon dioxide.
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Title Annotation:Research Article
Author:Attia, Nour F.; Zayed, Mohamed
Publication:Journal of Nanomaterials
Date:Jan 1, 2017
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