Effects of Nanoimprinted Structures on the Performance of Organic Solar Cells.
A few light trapping management techniques have been investigated for enhancing photon absorption and PCEs in OSCs [15-24]. Patterning active layers with gratings or wrinkle-like topography by soft lithography led to light trapping into the active films [17-19]. Other light trapping schemes based on the patterned electrodes were also reported using buried nanoelectrodes ,microprism substrates , and azopolymer based submicrometer relief substrates [22-24]. Although the enhancements in light absorption have been demonstrated in those devices, the practical adoption of these light manipulation methods is hindered due to the difficulty of precisely engineering the multiple periodic nanostructures, the incompatibility with the thin organic films, the limited spectral response, and complicated fabrication procedures over large areas.
Nanoimprinting has recently emerged as a promising candidate for fabricating nanostructures [25, 26]. It offers high throughput and high precision. Surface relief pattern of a stamp can be readily replicated over the active film by thermal-contact printing. Recently, this imprinting method has been applied to the OSCs to improve the PCEs [27, 28]. More than 11% enhancements were reported for the nanostructured OSCs as compared to those of the nonstructured ones. Nanospikes created on silicon wafers by near-infrared femtosecond laser pulses have been used for antireflection and light trapping in silicon based photodiodes [28, 29]. In this letter, we report on incorporation of the nanospike structures photofabricated on silicon wafer into the organic photovoltaic cells by nanoimprint technique. The OSCs with the nanostructures exhibited significantly improved photocurrent and PCSs due to enhanced light harvesting and better charge collection.
A femtosecond Ti:sapphire laser (operating at 800 nm with 100-femtosecond pulse width and 1 kHz repetition rate) was used to produce the silicon nanospike structures. Silicon wafer was first cleaned with acetone and then rinsed in methanol. The cleaned silicon wafer was immersed in methanol in a Petri dish. The Petri dish was then positioned on a computer controlled X-Y stage. The frequency-doubled laser pulses from a beta barium borate crystal at 400 nm were normally incident on the surface of the silicon wafer after passing through a lens. The nanospike structure over an area of 1 [cm.sup.2] was fabricated. The nanostructures were treated with 10% hydrofluoric acid to remove the very thin oxidized silicon layer and to smooth the nanospikes. Figure 1 shows the SEM image of typical silicon nanospikes viewed at a tilted angle of 45[degrees]. The nanospikes are typically a few hundred nanometers in height and several hundred nanometers in width. Because the dimensions of nanospikes are in the visible spectral range, the fabricated silicon nanospikes are able to trap most of the incident light and appear black.
Thermal-contact printing method was utilized to transfer the nanostructures over the active thin films. Indium doped tin oxide (ITO) coated glasses (10 O/d) were cleaned with detergent and were then sonicated in water, acetone, and isopropanol. All the chemicals used in this study were acquired from Sigma Aldrich and were used without further purification. Poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) from aqueous solution was first spin-coated on the cleaned ITO substrate at 1200 rpm for 10 seconds and at 3000 rpm for 60 seconds. The PEDOT:PSS coated substrates were then baked at 130[degrees]C for 15 min in a vacuum oven. The PEDOT:PSS film was about 40 nm thick. Solutions of poly 3-hexyl thiophene (P3HT) : phenyl-C61-butyric acid methyl ester (PCBM) (30 mg/mL : 24 mg/mL) and P3HT:indene-C60 bis-adduct (ICBA) (30mg/mL: 24 mg/mL) were prepared by codissolving the corresponding materials in 1,2-dichlorobenzene, respectively. After filtering the solutions through 0.2 [micro]m pore size membrane filters, P3HT:PCBM and P3HT:ICBA thin films were prepared by spin-coating at 800 rpm for 180 seconds on top of the PEDOT:PSS layers, respectively. The resulting blend films were about 260 nm thick. It is known that P3HT absorbs broadly in visible region from 400 nm to 650 nm, with a peak around 550 nm. After spin-coating, the nanostructured silicon stamp was brought into conformal contact with the thin active film and annealed at 130[degrees]C for 30 min under a pressure around 5 kPa. After removal of the silicon stamp, the replica patterns were attained. Aluminum electrodes were deposited on the nanostructured active layers by thermal evaporation. The thickness of aluminum layer was about 100 nm. For comparison, control devices without the nano-spike structures were also fabricated.
Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to study the nanoimprinted structures on the active layer of P3HT:PCBM. Figures 2(a) and 2(b) show the SEM images of the nanostructured active layer at two different magnifications. These images elucidate that nanostructures from the silicon stamp were transferred to the active layer. Figures 3(a) and 3(b) illustrate the topographic and 3D AFM images of the nanostructured active layers. The imprinted active layers exhibited nanotextured structures similar to those of the stamp of a few hundred nanometers high and several hundred nanometers wide. Similar nanopatterns were obtained on the P3HT:ICBA layer.
Figure 4 depicts the absorption spectra of the control and nanostructured P3HT:PCBM and P3HT:ICBA films. Films with the nanostructures scatter more light in comparison against the control samples without the structures. The incident photon-to-current efficiency (IPCE) measurements on the fabricated solar cells were also performed. Figures 5(a) and 5(b) exhibit the IPCE spectra of the nanostructured P3HT:PCBM and P3HT:ICBA OSCs and their corresponding control devices, respectively. The solar cells with the nanostructures yielded about 30% improvement in the quantum efficiency against the control cells without the structures. The increase in the IPCE of the nanostructured solar cells over the wavelength range of 350-700 nm contributes to the short-circuit current density (Jsc) improvement. This enhancement of the nanotextured OSCs indicated that the nanoimprinted structures can increase optical path length and provide efficient light trapping by multireflection from the textured surface and total internal reflection.
Photovoltaic performance of the solar cells was characterized under 1 sun (100mW/[cm.sup.2]) AM 1.5 G solar irradiation. A black shadow mask with an area of 0.08 [cm.sup.2] was used for the characterization. Figures 6(a) and 6(b) show the JV characteristics of the P3HT:PCBM and P3HT:ICBA solar cells with and without the nanostructures, respectively.
The photovoltaic characteristics of the solar cells are summarized in Table 1. The control cells made of P3HT:PCBM and P3HT:ICBA only yielded PCEs of 1.97% and 3.87% with Jsc of 8.10 mA [cm.sup.-2] and 9.70 mA [cm.sup.-2], the open-circuit-voltage (Voc) of 0.56 V and 0.70 V, and the fill-factor (FF) of 0.43 and 0.56, respectively. The nanostructured P3HT:PCBM and P3HT:ICBA solar cells exhibited significantly improved PCEs as compared to those of the control ones. The nanostructured P3HT:PCBM and P3HT:ICBA devices yielded PCEs of 3.50% and 5.38%, respectively. Significant performance enhancements have been achieved for the nanostructured OSCs as compared to those of the nonpatterned ones. The increases in PCEs are mainly ascribed to the increase in Jsc plus improvement in FF.
As shown in Figures 2 and 3, the nanoimprinting induces the textured surface over the active layer with dimensions in the visible wavelength region, leading to scattering of incident light within the layer. Hence, the optical path inside the active layer is increased, resulting in higher absorption and higher charge generation. This leads to enhancement of Jsc and PCE. Moreover, the nanoimprinted surface will also make the aluminum electrode to be textured and buried inside the active film. Since FF is limited by the carrier drift length,  defined as a product of the carrier mobility, the carrier recombination lifetime, and the electric field, the increase in FF upon nanoimprinting can be attributed to the better charge extraction/collection. The nanotextured electrode provides larger surface area in contact with the active materials and helps shortening the travelling distance of the charge carriers to the corresponding electrodes, hence improving the charge collection and significant improvement of photovoltaic performance.
In summary, the OSCs with the nanospike structures were successfully fabricated using thermal-contact printing technique. Significant enhancement of the photovoltaic performance of the nanoimprinted solar cells was achieved due to effective light trapping and increase in optical path length from the textured active layer and efficient charge carrier collection from the buried nanostructured aluminum electrode. This simple technique can be adapted for roll-to-roll manufacturing. This work can provide an effective way to further enhance the OSC performance by optimization of processing protocols of given materials.
Impact Statement. Significant enhancement of the photovoltaic performance of the nanoimprinted solar cells was achieved due to effective light trapping and increase in optical path length from the textured active layer.
Conflicts of Interest
The authors declare that they have no conflicts of interest.
This work was supported as part of Polymer-Based Materials for Harvesting Solar Energy, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, and Basic Energy Sciences under Award no. DESC0001087. This research was also supported in part by an appointment to the Faculty Research Participation Program at the U.S. Army Natick Soldier Research, Development and Engineering Center (NSRDEC) administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the U.S. Department of Energy and NSRDEC. Hardeep Singh Gill will like to thank the Tripathy Summer Graduate Fellowship from the Center for Advanced Materials at the University of Massachusetts Lowell.
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Hardeep Singh Gill, (1,2) Lian Li, (1,2,3) Haizhou Ren, (1) Ravi Mosurkal [ID], (3) and Jayant Kumar [ID], (1,2)
(1) Department of Physics, University of Massachusetts Lowell, Lowell, MA 01854, USA
(2) Center for Advanced Materials, University of Massachusetts Lowell, Lowell, MA 01854, USA
(3) US Army Natick Soldier Research, Development and Engineering Center, Natick, MA 01760, USA
Correspondence should be addressed to Jayant Kumar; email@example.com
Received 9 August 2017; Revised 23 January 2018; Accepted 26 February 2018; Published 11 April 2018
Academic Editor: Chih-Liang Wang
Caption: Figure 1: SEM image of the silicon nanospikes viewed at a tilted angle of 45[degrees].
Caption: Figure 2: SEM images of the structured active layer of P3HT:PCBM viewed at the tilted angles of 45[degrees] with two different magnifications of (a) 1,500x and (b) 35,000x.
Caption: Figure 3: (a) Topographic and (b) 3D AFM images of the nanostructured active layer of P3HT:PCBM.
Caption: Figure 4: Absorption spectra comparison of control and nanostructured films.
Caption: Figure 5: IPCE spectra of (a) the P3HT:PCBM and (b) the P3HT:ICBA solar cells with and without nanoimprinted structures.
Caption: Figure 6: J-V characteristics of (a) the P3HT:PCBM and (b) the P3HT:ICBA solar cells with and without the nanostructures.
Table 1: Performance characteristics of the P3HT:PCBM and P3HT:ICBA solar cells with and without the nanostructures. Sample [J.sub.sc] [V.sub.oc] (V) (mA/[cm.sub.2]) P3HTPCBM Control 8.10 [+ or -] 0.05 0.56 [+ or -] 0.03 Nanostructured 10.70 [+ or -] 0.03 0.56 [+ or -] 0.02 P3HT:ICBA Control 9.70 [+ or -] 0.05 0.70 [+ or -] 0.02 Nanostructured 12.40 [+ or -] 0.03 0.70 [+ or -] 0.02 Sample FF (%) PCE(%) P3HTPCBM Control 43.30 [+ or -] 0.02 1.97 [+ or -] 0.01 Nanostructured 58.40 [+ or -] 0.02 3.50 [+ or -] 0.01 P3HT:ICBA Control 56.10 [+ or -] 0.03 3.87 [+ or -] 0.02 Nanostructured 61.80 [+ or -] 0.04 5.38 [+ or -] 0.02
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|Title Annotation:||Research Article|
|Author:||Gill, Hardeep Singh; Li, Lian; Ren, Haizhou; Mosurkal, Ravi; Kumar, Jayant|
|Publication:||Journal of Nanomaterials|
|Date:||Jan 1, 2018|
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