Effect of annealing temperature on CuIn[Se.sub.2]/ZnS thin-film solar cells fabricated by using electron beam evaporation.
Among various materials for thin film solar cells, copper indium diselenide (CuIn[Se.sub.2]) has emerged as a promising material due to its use as a solar radiation absorber. In recent years, interest has increased regarding the use of copper indium selenide (CIS) compounds, which are elements of the [I-III-VI.sub.2] group, as materials for thin film photovoltaic solar cells because of their high theoretical efficiency of approximately 24.8% . CuIn[Se.sub.2] is a promising material for thin film solar cells because of its extraordinary radiation stability . CuIn[Se.sub.2] films possess certain exceptional material characteristics including a band-gap, absorption coefficient and minority carrier diffusion length which are particularly suitable for photovoltaic applications. Because these films can be prepared with n- and p-type conductivity, there is potential for both a homo- and heterojunction . CuIn[Se.sub.2] is also favoured because it is more environmentally benign than CIS. These materials have remarkably stable electrical properties over a wide range of stoichiometries . Recently, CIS solar cells have been produced with efficiencies as high as 15.4%, and have demonstrated good long-term stability and stable device performance . To achieve further commercial success for CuIn[Se.sub.2]-based photovoltaics and to reduce the cost of these solar cells, it is necessary to mass-produce quality CuIn[Se.sub.2] films via a low-cost, eco-friendly, and easily scalable process . Evaporation techniques are typically used to produce good film stoichiometry for elements and simple compounds . Among II-VI compounds, zinc sulfide (ZnS) and zinc selenide (ZnSe) are suitable for many applications . ZnS has a large band gap of approximately 3.7 eV, high refractive index, high precision dielectric constant, and broad band of wavelengths . At certain temperatures, ZnS can change phase from cubic to wurtzite . ZnS can be used in the fabrication of optoelectronic devices, photoconductors and window materials for thin film heterojunction solar cells . The aim of this research is to study the dependence of CuIn[Se.sub.2]: ZnS solar cell efficiencies, structures, and morphologies on the annealing temperature of the CuIn[Se.sub.2] films. In this study, CuIn[Se.sub.2] films with an annealing temperature of room temperature (27[degrees]C), 250[degrees]C, 300[degrees]C, or 350[degrees]C were examined for changes in morphology and structure by
FESEM and XRD analysis. To study the effects of the annealing temperature on the overall CuIn[Se.sub.2]: ZnS solar cell efficiency, I-V measurements were performed for thin films with annealing temperatures of 27[degrees]C and 100[degrees]C.
2. Experimental Details
CuIn[Se.sub.2] layers were produced by annealing CuIn[Se.sub.2] pellets onto FTO glass substrates via electron beam evaporation. ZnS layers were made using the chemical bath deposition (CBD) technique with a 3h deposition time. The CuIn[Se.sub.2] pellets were made from a mixture of Cu, In and Se powders, while ZnS films were fabricated from aZn(C[H.sub.3] COO)2, TEA, N[H.sub.3], [C.sub.6][H.sub.5][Na.sub.3][O.sub.7] and thiourea solution. CuIn[Se.sub.2] films were varied by using annealing temperatures of room temperature, 250[degrees]C, 300[degrees]C, and 350[degrees]C to study the effect of the annealing temperature on the morphology, structure and the efficiency of the solar cells. The flow of the cell fabrication is outlined in Figure 1. The surface morphology was studied with fieldemission scanning electron microscopy (FESEM) while the crystallinity of the CuIn[Se.sub.2] films was determined by Xray diffraction (XRD). I-V data were collected by Gamry Instruments G300 with a light intensity of 110mW/[cm.sup.2]. Figure 2 shows a diagram of the prepared samples with ZnS and CuIn[Se.sub.2] films on top of a glass substrate with an FTO layer.
3. Results and Discussions
Figure 2 shows the cross-section of prepared samples with ZnS and CuIn[Se.sub.2] films on top of glass substrate and FTO layer while Figure 3 shows FE-SEM images of CuIn[Se.sub.2] films deposited with an annealing temperature of 27[degrees]C, 250[degrees]C, 300[degrees]C, or 350[degrees]C. From the results obtained, CuIn[Se.sub.2] films were deposited uniformly over the substrate. These layers covered the entire surface of the substrate even without annealing, but the nonannealed films resulted in grains having less homogeneity. The grains became smaller and more densely arranged when temperature increased from 300[degrees]C to 350[degrees]C than when the temperature was increased from 250[degrees]C to 300[degrees]C. FE-SEM also shows an increase in grain size due to the roughness that developed when the growth rate was increased with an increase in annealing temperature . The average particle size and film thicknesses are shown in Table 1.
As shown in Table 1, the average particle sizes were 156.33 nm, 137.70 nm, 139.53 nm, and 163.77 nm for annealing temperatures of 27[degrees]C, 250[degrees]C, 300[degrees]C, and 350[degrees]C, respectively. After the heat treatment, single grains of CuIn[Se.sub.2] were developed and the morphology of the films became denser. The thicknesses measured 172.67 nm, 109.76 nm, 121.33 nm, and 133.23 nm for the annealing temperatures of 27[degrees]C, 250[degrees]C, 300[degrees]C, and 350[degrees]C, respectively. These show that at room temperature, CuIn[Se.sub.2] films have the greatest thickness, and after annealing, the thickness decreases from 172.67 nm to 109.76 nm. This thickness change occurs because the smaller grains deposited on the film upon thermal treatment have less energy and have lost some of the weak binding between the grains and the substrate. These grains leave the substrate after annealing, but with increased annealing temperatures up to 300[degrees]C and 350[degrees]C, the denser grains become larger serve to increase the thickness of the film. The average size of the grains measured was approximately 100 nm. The similar phenomenon has also been studied by Zhang et al. 2010 . We can conclude from these results that annealing temperature, particle size and film morphology are all proportionally related.
The diffraction patterns for CuIn[Se.sub.2] samples annealed at temperatures of 27[degrees]C, 250[degrees]C, 300[degrees]C, and 350[degrees]C are shown in Figure 4. From analysis of the XRD patterns, it was observed that the CuIn[Se.sub.2] crystallinity increased from amorphous structure to a polycrystalline structure as the annealing temperature increased. As shown in Figure 4, the CuIn[Se.sub.2] films are amorphous at room temperature. There are three dominant peaks corresponding to (1 1 2), (2 2 0)/(2 0 4), and (3 1 2)/(1 1 6) orientations at a 2[theta] of 27[degrees],45[degrees], and 53[degrees], respectively. These peaks have also been studied by Bindu et al. , Soon et al. , Yang and Chen , and Jeong et al. . At an annealing temperature of 250[degrees]C, three peaks, which contained both CuIn[Se.sub.2] and FTO, could be observed with (1 1 2) and (2 2 0)/(2 0 4) orientations, as reported by Bernede and Assmann . At a temperature of 300[degrees]C, CuIn[Se.sub.2] peaks were dominant and the FTO peaks slowly disappeared. When the temperature was increased to 350[degrees]C, CuIn[Se.sub.2] peaks appeared at three locations (2[theta]) of 27[degrees], 45[degrees], and 53[degrees]. The peaks became sharper after the annealing temperature was increased, showing that the crystal sizes were larger than 1nm . The intensity of the peaks decreased with increasing annealing temperature, showing that the amount of the binary compound CuSe decreases during the annealing process. Higher and sharper peaks also appeared, showing that the primary crystal structure was successfully increased after the annealing process.
Figure 4 also shows that the main phase of the deposited CuIn[Se.sub.2] film has a chalcopyrite structure .
A qualitative estimation of the crystal size was obtained from Scherrer's formula:
D = k[lambda]/Bcos[theta] (1)
where k is the shape factor, A is the wavelength (0.154 nm), B is the full-width at half-maximum of the main peak, and 0 is the main peak position . The crystal size was calculated and is shown in Table 2. The average crystal size of CuIn[Se.sub.2] was 2.63 nm, 2.55 nm, and 3.05 nm for CuIn[Se.sub.2] (1 1 1), 8.99 nm, 7.49 nm, and 7.05 nm for the (2 2 0)/(2 0 4) plane, and 3.70 nm for the (3 1 2)/(1 1 6) plane. The grain size increased in the (1 1 1) plane and decreased in the (2 2 0)/(2 0 4) plane proportionally with the increasing annealing temperature. At the higher temperatures of 300[degrees]C and 350[degrees]C, the FTO peak disappeared and a peak corresponding to the (3 1 2)/(1 1 6) plane is observed, showing that the growth of the ternary compound CuIn[Se.sub.2]. This analysis shows that the crystalline structure of CuIn[Se.sub.2] films can be changed from an amorphous to a polycrystalline phase with heat treatment.
CuIn[Se.sub.2]: ZnS solar cells were fabricated by depositing ZnS thin films on top of CuIn[Se.sub.2] films via the chemical bath deposition (CBD) method with a deposition time of 3h. Figure 5 shows the I-V curves for CuIn[Se.sub.2]: ZnS solar cells for the CuIn[Se.sub.2] films annealed at temperatures of 27[degrees]C and 100[degrees]C. These temperatures have been chosen for the I-V measurements and are merely included to study the effect of annealing treatments on the overall solar cell efficiency. As shown in Figure 5, the effect of the changes in annealing temperature on the solar cell efficiencies was analysed and the results indicate that there was a difference in current density (/sc) and open-circuit voltage (Voc) of the samples before and after annealing. After annealing, /sc, decreased from 8.65mA/[cm.sup.2] to 1.92mA/[cm.sup.2] while Voc, increased from 0.20 V to 1.96 V. This could be due to the surface morphology of the samples prior to annealing as was shown by FESEM. This condition enhanced the electron-hole pair recombination rate in the film which affected the overall cell performance. The cell with the thicker layer had a lower efficiency, despite having greater photon absorption due to a simultaneous decrease in internal quantum efficiency . As shown in Table 3, which presents the calculated efficiency along with /sc, the fill factor, FF and Voc, annealing increases the efficiency of CuIn[Se.sub.2]: ZnS solar cells from 0.99% to 1.12%.
This study used electron beam evaporation, with annealing temperatures of 27[degrees]C, 250[degrees]C, 300[degrees]C, and 350[degrees]C, and the chemical bath deposition (CBD) method, with a 3h deposition time, to produce CuIn[Se.sub.2]: ZnS solar cells. XRD analysis suggested that the diffraction of CuIn[Se.sub.2] films changed from an amorphous to a polycrystalline phase after annealing at 27[degrees], 45[degrees] and 53[degrees] at (1 1 2), (2 2 0)/(2 0 4), and (3 1 2)/(1 1 6) orientations, respectively. FESEM results showed that the CuIn[Se.sub.2] particles were in better arrays after annealing and had sizes of 156.33 nm, 137.70 nm, 139.53 nm, and 163.77 nm. The thicknesses measured were 172.67 nm, 109.76 nm, 121.33 nm, and 133.23 nm for annealing temperatures of 27[degrees]C, 250[degrees]C, 300[degrees]C, and 350[degrees]C, respectively. From these data, we conclude that as the annealing temperature increases, the particle size and thickness also increase. IV measurements indicated that annealing increases the efficiency of solar cells from 0.99% to 1.12%. These results show the dependence of both the efficiency and the structural and morphological characteristics of CuIn[Se.sub.2] layers on annealing temperature.
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H. Abdullah and S. Habibi
Department of Electrical, Electronics, and Systems Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia
Correspondence should be addressed to H. Abdullah; email@example.com
Received 17 October 2012; Accepted 10 December 2012
Academic Editor: Sudhakar Shet
TABLE 1: Particle size of CuIn[S.sub.2] for each annealing temperature. Annealing temperature ([degrees]C) Particle size (nm) 27 113.90 250 2790 300 21.66 350 24.03 TABLE 2: Crystal size and diffraction angle for each of annealing temperature. Annealing temperature 2[theta] Samples ([degrees]C) (degrees) CuIn[Se.sub.2]_27 25 Amorphous CuIn[Se.sub.2]_250 250 26.9 45.0 CuIn[Se.sub.2]_300 300 26.9 44.9 26.8 CuIn[Se.sub.2]_350 350 44.8 52.7 Crystal size, Samples d (nm) (h k l) CuIn[Se.sub.2]_27 Amorphous Amorphous CuIn[Se.sub.2]_250 2.63 111 8.99 2 2 0/2 0 4 CuIn[Se.sub.2]_300 2.55 111 7.49 2 2 0/2 0 4 3.05 112 CuIn[Se.sub.2]_350 7.05 2 2 0/2 0 4 3.70 3 1 2/1 1 6 TABLE 3: Efficiency of CuIn[Se.sub.2]: ZnS solar cell at produced room temperature and annealing temperature of 100[degrees]C. Annealing temperature Current density, J Open-circuit Sample ([degrees]C) (mA/[cm.sup.2]) voltage (V) 4000_room 27 8.65 0.20 temperature 4000_100 100 1.92 1.96 Sample Fill factor FF Efficiency (%) 4000_room 0.36 0.99 temperature 4000_100 0.33 1.12
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|Title Annotation:||Research Article|
|Author:||Abdullah, H.; Habibi, S.|
|Publication:||International Journal of Photoenergy|
|Date:||Jan 1, 2013|
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