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Development of frozen-fried yam slices: optimization of the processing conditions.

INTRODUCTION

The market of potato French fries has increased over recent years in tropical and northern hemisphere countries [1]. Frying process of these western starchy food materials has been extensively studied. However, few investigations on frying behavior of tropical starchy foods like yam tuber have been performed and, worse, no study on deep-frozen yam slices fries has been operated [2]. The researches performed on yam processing mainly concerns the production of crisps and flour. Yams (Dioscorea species) are popular in Africa, West Indies and parts of Asia, South and Central America [3]. The annual production of yam is about 37.5 million tons and Nigeria contributes for about 70% of the total world production [4]. Yams are an excellent source of dietary energy for most people in the tropics, but methods of processing, storage and marketing of the crop are poorly developed [5].

Deep-fat frying is an established process of food preparation worldwide. It is a simultaneous heat and mass transfer process where moisture leaves the food in the form of vapor bubbles, while oil is absorbed [6]. It is often selected as a method of choice for creating unique flavors and texture in foods processed and results in modification of the physical, chemical and sensory characteristics of the food [7]. Quantitative information describing oil penetrations into the food, crust and texture development, interactions between water and oil, color parameters among others are required for process optimization. Frying in hot oil at temperatures between 160 and 180[degrees]C is critical for ensuring favorable structural and textural properties of the final product [8]; at the same time, there are nutritional concerns related to oil migration into the final product.

The industrial process of production of frozen French fries traditionally includes a pre-frying step. The aim of this step is to develop the color and crispness, and the oil partially absorbed inhibits dehydration during the freezing step [9, 10]. According to Sanz et al. [11], the increase in final frying time improved crispness, but it cannot counterbalance a lack of pre-frying, and pre-frying may allow an easier loss of water from the crust during final frying, which will enhance its crispness. Krokida et al. [12] have examined the effect of pre-fry drying on frying kinetics and quality of French fries. They indicated that pre-fry drying decreased fat content of French fries and, significantly affected color and structural properties of French fries.

The purpose of this study was to optimize pre-frying and frying conditions of deep-frozen yam slices, by comparing the qualities of fried yam slices with the standard quality (oil content, dry matter, color and texture) of potato French fries.

MATERIALS AND METHODS

Potatoes tubers (Solanum tuberosum L.), variety Bintje was purchased from Brussels local supermarket in Belgium, and kept at 10[degrees]C prior to processing. These potatoes were used to control the fryer parameters and to standardize frying conditions in the fryer by applying the process of potato deep-frozen French fries before its application on yam. The choice of this potato variety is due to the fact that it is one of the varieties showing techno-functional properties for processing into French fries [13]. Fresh yam tubers from variety Kponan (Dioscorea cayenensis-rotundata), a stable yam product, originating from Africa, was bought in Bruxelles (Belgium) market.

Preparation of potato and yam slices

Potato tubers were cut into cylindrical sticks having a diameter of 1cm and a length of 6cm with a punch. Seventeen French fries sticks were taken for each frying session. As for yam tubers, they were divided in the longitudinal direction into three equal parts (Fig. 1a). The central part was used and the samples (Fig. 1b) were cut in a similar way as the potato French fries sticks. After cutting, each stick was kept in water at room temperature in order to reduce the drying up and oxygen-activated physiological deterioration. The sticks were then washed, drained for 1min and blanched at 80[degrees]C for 5min in a double boiler to inactivate enzymes (polyphenol oxidase and peroxidase). This leads to uniform colour after frying and permits to form a layer of gelatinized starch that limits oil absorption and improves texture. The blanched sticks were drained for 1min and dried at 60[degrees]C for 5min in a drying oven before pre-frying.

[FIGURE 1 OMITTED]

Frying conditions

A deep-fat fryer (Haake N2, Germany, Berlin, Karlsruhe) equipped with an agitator and temperature control about [+ or -]2[degrees]C, was used. The fryer was filled with 8 liters of oil (Frying oil, 100% vegetable, Buttella, Belgium) and heated with an electrical resistance (effective power 2120W) sub-merged at the bottom of the tank. An agitator shaft fixed to a central and driven by a 100W motor was added to the device. The stirring unit produced a radial flow with aeration-free turbulence. The stirring speed used (150rpm) reduced field temperature heterogeneity in the bath between frying sessions. Dried French fries sticks were introduced under continuous stirring in the fryer. They were pre-fried at 150, 160 and 170[degrees]C for 5, 10, and 15s, drained for 30s and transferred to an absorbent paper to remove the excess oil on the surface. Pre-frying and frying times and temperatures were chosen on the basis of preliminary experiments. Then, the samples were deep-frozen at -50[degrees]C for 20min before frying for 2, 3 and 4min at 170, 180 and 190[degrees]C respectively. After frying, French fries were drained (30s) and transferred to an absorbent paper to remove the excess oil on the surface before analysis. In order to minimize variation in the bulk bath temperature during frying, the samples-to-oil weight ratio was kept as low as possible, only 30g of French fries sticks per 8 liters were fried at a time. During pre-frying, frying and blanching time, French fries samples were fixed on stainless steel rods to ensure defined and constant position of sticks in the oil to prevent floatation. Frying oil was changed after every two frying cycles.

Temperature control

Temperature data were recorded every 2 seconds during the experiment using a digital multimeter (Ellab TM9608, US) fitted with thermocouples T-type (Omega, TT-T-30-SLE, US) and a personal computer. During all frying tests, a thermocouple was inserted longitudinally (about 3cm) into the core of French fry, with the help of a needle tip. This permitted us to monitoring the core temperature of the French fries during instrumental texture measurements. These thermocouples were positioned in the center of the oil bath, hung at about half way the level of the oil; this was the point in which the oil temperature represented the average value of those registered in nine different points of the oil bath according to results of preliminary experiments. During pre-frying and frying, a thermocouple was also fixed on the basket edge. Location of the thermocouple inserted in the oil and in the French fries sticks was checked and verified during and after each experiment by visual examination. After removal from the fryer, French fries with incorporated thermocouples were put in a thermal insulator composed of sea sand in a cylindrical metallic plate and put in the drying oven at 75[degrees]C for 20h ([+ or -]1h). At the exit of the drying oven, absorbing paper was spread out over the sand in the plate as well as in the upper case of the insulator. This absorbing paper helps to absorb water produced by condensation in the insulator during the cooling and thus avoiding moisture uptake by the French fries. Monitoring of the oil bath and the core temperature of French fries in the thermal insulator were followed. Two initial French fries core temperatures, 80 and 90[degrees]C corresponding to 30-70s after removal from the oil bath were used for the experimentation. Three initial oil temperatures (20, 50 and 100[degrees]C) were used to study the stability of oil bath temperature during heating before pre-frying and frying operations. The temperature of 180[degrees]C was fixed as the temperature to be reached before experimentations.

Fries yam slices characterization

All analyses were carried out in triplicate. Fat content was determined using the Soxhlet method [14, 15]. Dry matter content was determined by gravimetric method using the modified AOAC standard methods. The samples were dried at 105[+ or -]4[degrees]C for 24h in a convective oven [16]. Texture measurements for the fried yam slices were performed at room temperature (25[degrees]C). Cutting test was carried out by measuring the maximum shear force (Fmax expressed in Newton) necessary to cut fried French fries sticks. This test imitates a human front teeth bite [17]. This force was determined as the hardness expressing French fries texture. A Texture Analyzer TA-XT2 (Stable Micro Systems, Surrey, UK), equipped with a 50kg load cell, a light knife blade probe guillotine (HDP/BSG) and a test speed of 0.5mm/s were used. Fried yam slices core temperature at the measurement time was 55[degrees]C. For each frying batch, six fried yam slices were analyzed. Eight fried yam slices were used for each frying test for colour measurements. After frying, the slices were placed on a white plate and the slices surface color was measured using a spectrocolorimeter Hunterlab Miniscan XE (version 3.5, Escolab Nv, Belgium), operating in the CIE [L.sup.*][a.sup.*][b.sup.*] colour space [18]. The readings were carried out in duplicate placing the instrument measuring port at both sides of the sticks. In this way, the reflectance of a representative part of the surface was measured. The following measurement conditions were applied: UV 100%; standard illuminant D65 and observer angle 10[degrees]. The instrument was calibrated with a white and a black ceramic plate. The color is defined by three orthogonal co-ordinates. [L.sup.*] refers to lightness and ranges from black ([L.sup.*] = 0) to white ([L.sup.*] = 100) while [a.sup.*] (+[a.sup.*] = red; -[a.sup.*] = green) and [b.sup.*] (+[b.sup.*] = yellow; -b = blue) represent coordinates for hue. From these values, chroma ([C.sup.*]) and hue angle ([h.sup.*]) were calculated based on [C.sup.*] = [([a.sup.*2] + [b.sup.*2]).sup.0.5] and [h.sup.*] = arctangent [b.sup.*]/[a.sup.*]. While [h.sup.*] (where 0[degrees] = red-violet; 90[degrees] = yellow; 180[degrees] = blue-green; 270[degrees]= blue) is useful to quantify the hue expressed by an object, [C.sup.*] is somewhat analogous to colour saturation [19].

Experimental design and statistical analysis

To determine the effect of pre-frying temperature and time, and final frying temperature and time on fried yam slices quality, response surface methodology was applied with a Box-Behnken experimental design [20]. Yam type was taken as a fixed parameter. This design led to studying the effects of four factors (pre-frying temperature ([x.sub.1]), pre-frying time ([x.sub.2]), final frying temperature ([x.sub.3]) and final frying time ([x.sub.4])) in a single block of 27 sets of test conditions and 3 central points. The order of the experiments was fully randomized. Three levels were attributed to each factor, coded as -1, 0, +1 (Table 1). Fried yam slices quality such as fat content, texture, dry matter and colour parameter ([L.sup.*], [a.sup.*], [c.sup.*], [h.sup.*]) with target value (Table 2) [21], were considered as responses to evaluate the effect of pre-frying temperature, pre-frying time, frying temperature and frying time. Statistical analysis was performed with the software package R version 2.9.0 [22]. A quadratic polynomial model was defined to fit the response:

[MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (1)

where Y is the response expressed as fried yam slices quality (fat content, texture, dry matter and colour parameter) and [[beta].sub.0] is a constant coefficient of the model. The regression coefficients ([[beta].sub.1], [[beta].sub.2], [[beta].sub.3] and [[beta].sub.4]), ([[beta].sub.11], [[beta].sub.22], [[beta].sub.33] and [[beta].sub.44]) and ([[beta].sub.12], [[beta].sub.13], [[beta].sub.14], [[beta].sub.23], [[beta].sub.24] and [[beta].sub.34]) respectively represent linear, quadratic, and interaction effects of the model, estimated by multiple regression analysis. [x.sub.1] (Pre-frying temperature), [x.sub.2] (pre-frying time), [x.sub.3] (frying temperature) and [x.sub.4] (frying time) are coded variables ranging from -1 to +1 (table 1). Interpretation of the data was based on the signs (positive or negative effect on the response) and statistical significance of coefficients (P < 0.05). Interactions between two factors could appear as an antagonistic effect (negative coefficient) or a synergistic effect (positive coefficient). Internal validation of prediction accuracy of the Box-Behnken models was based on statistical evaluation of the following tests: bias index and accuracy factor, and the lack-of-fit test [23].

[MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (2)

[MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (3)

where [[mu].sub.observed] and [[mu].sub.predicted] are respectively the observed and predicted values and, n is the number of observations used in the calculation.

RESULTS

Temperature profiles

The temperature profiles of fried yam slices core and oil bath were monitored during the whole frying test (results not shown). It has been observed that the temperature of oil bath remained constant once 180[degrees]C was reached. This indicated that the frying bath used during the study was therefore reliable. At the beginning of frying, the initial oil temperature in the fried yam slices basket rapidly increased during both pre-frying and frying time as a consequence of the fried yam slices immersion, and reached the oil bath temperature in the first five seconds and the first 30 seconds, respectively; surface temperature profile rapidly exceeded the boiling point of water. Only for the longest frying times, at which overcooked products were obtained, was there a high similarity between the temperature behavior of the oil bath and the fried yam slices surface. No decrease of the temperature profile of oil bath occurred during pre-frying or frying. It supposes that the quantity of fried yam slices (17 slices of 90g) introduced in the oil (8 liters) was adequate to maintain a constant temperature during pre-frying and frying, which was necessary for the control of experimental conditions. Fig. 2 shows the temperature profile of fried yam slices core during cooling in the thermal insulator versus time. There were no differences between these initial core temperature curves. At the beginning of cooling, both the initial core temperature of fried yam slices rapidly decreased and reached 60[degrees]C after 10min. The core temperature of fried yam slices remained relatively constant at 55[+ or -]3[degrees]C during at least 25min after 15min of cooling. The thermal insulator thus made it possible to stabilize the fried yam slices core temperature at about 55[degrees]C after 15min of cooling for texture measurement.

[FIGURE 2 OMITTED]

Effects of pre-frying and final frying conditions on fried yam slices quality

The experimental values obtained for the fried yam slices quality parameters under the various conditions tested are shown columns 6 (MG), 8 (Fmax), 10 (MS), 12 ([h.sup.*]), 14 ([a.sup.*]), 16 ([C.sup.*]) and 18 ([L.sup.*]) in Table 2. It was possible to achieve the desirable quality target values of fried yam slices when the frying temperature 180[degrees]C was applied for 2 or 4min and high pre-frying temperature with short time or low temperature with long time. At higher frying temperature and short time or lower frying temperature and long time, these target values were sometimes reached (see observed value in E2, E14, E21, and E27).

Modeling the effects

The results of the multiple regression analysis from which the model coefficients were derived are listed in (Table 3). The higher the absolute value of a linear coefficient ([[beta].sub.1], [[beta].sub.2], [[beta].sub.3] or [[beta].sub.4]), the greater the influence of the corresponding factor on the predicted quality values [24], considering the chosen range of the parameter. With oil content, the applied pre-frying temperature had the greatest effect, followed by the final frying time, then final frying temperature and finally the pre-frying time. For this model, the coefficients [[beta].sub.1] (pre-frying temperature), [[beta].sub.14] (effect of the interaction between pre-frying temperature and final frying time), and [[beta].sub.23] (effect of the interaction between pre-frying time and final frying temperature) appeared significant (P < 0.05). In texture model, fried yam slices texture was more significantly affected by the effect of interaction between pre-frying temperature and frying time (coefficient [[beta].sub.14]) and the effect of interaction between pre-frying time and frying temperature ([[beta].sub.23]) (P < 0.01). With dry matter, only the final frying time had the greatest effect and appeared highly significant (coefficients [[beta].sub.4]) (P < 0.01). In all colour parameters models, the applied final frying temperature had the greatest effect, followed by the final frying time (except for [C.sup.*]), then pre-frying temperature and finally the pre-frying time. For these models, the highly significant (P < 0.01) coefficients were [[beta].sub.3] (final frying temperature), [[beta].sub.4] (final frying) and the other significant (P < 0.05) were [[beta].sub.11] (quadratic effect of pre-frying temperature), [[beta].sub.22] (quadratic effect of pre-frying time for [L.sup.*] and [C.sup.*]), [[beta].sub.33] (quadratic effect of final frying temperature only for [C.sup.*]), [[beta].sub.14] (effect of the interaction between pre-frying temperature and final frying time) (effect of the interaction between pre-frying temperature and final frying time), [[beta].sub.24] (effect of the interaction between pre-frying time and final frying time for [L.sup.*]) and, [[beta].sub.34] (effect of the interaction between final frying temperature and final frying time for [L.sup.*]). In redness and chroma models, all significant coefficients have positive effects except the linear [[beta].sub.2] has negative effect, while they have negative effect hue angle and lightness models except the linear [[beta].sub.2] and quadratic [[beta].sub.4] have positive effects for lightness.

DISCUSSION

Modeling

In the oil content model, all coefficients except the linear [[beta].sub.3] had negative effect. Due to positive interactions between pre-frying temperature and frying time, and pre-frying time and frying temperature, pre-frying and frying times were less important at higher temperatures. The process could thus be shortened at higher temperatures, without high oil absorption. Pedreschi and Moyano [25] reported similar results for fried potato slices. In texture model, fried yam slices texture was more significantly affected by the effect of interaction between pre-frying temperature and frying time (coefficient [[beta].sub.14]) and the effect of interaction between pre-frying time and frying temperature ([[beta].sub.23]) (P < 0.01). Other significant effects (P < 0.05) were those of the quadratic effect of pre-frying time (coefficient [[beta].sub.22]) and effect of interaction between final frying temperature an final frying time ([[beta].sub.34]) and, all coefficients except the linear [[beta].sub.4] have negative effects. With dry matter, only the final frying time had the greatest effect and appeared highly significant (coefficients[ [beta].sub.4]) (P < 0.01). For the defined conditions of frying, dry matter variation would be due to the frying time. Besides, it needs to be mentioned that the previous blanching, drying treatments and yam tuber history could also influence the final dry matter content of yam fries as in the case of potatoes French fries [26]. In all colour parameters models, the applied final frying temperature had the greatest effect, followed by the final frying time (except for [C.sup.*]), then pre-frying temperature and finally the pre-frying time. Sobukola [2] observed a similar result for colour parameters. The average predicted values obtained with these fried yam slices quality parameters models under various conditions are summarized in Table 2, columns 7 (MG), 9 (Fmax), 11 (MS), 13 ([h.sup.*]), 15 ([a.sup.*]), 17 ([C.sup.*]) and 19 ([L.sup.*]). With all quality parameters studied, differences were slight between the predicted and observed values. All models predict values close to target values when "high frying temperature/short time" or "low frying temperature/long time" were applied.

Statistical validation of the models

The tests used to validate our predictive models are listed in Table 4. The lack of fit F test is insignificant for all established models (except oil content and [C.sup.*]), suggesting that quadratic models adequately approximate the true surfaces. The significant lack of fit for oil content and [C.sup.*] is mainly due to the high repeatability of the oil content measurement and therefore does not affect the quality of their model predictions. For each model, the [R.sup.2] (coefficient of determination) was calculated. This coefficient, ranging from zero to one, represents the part of the response variation that is attributable to variations of the factors studied in the model and their interactions. The closer the [R.sup.2] value is to one the higher the predictive power of the model. In this case, the values for all fried yam slices quality parameters are higher than 70% except for dry mater and oil content. This means that fewer than 30% (except oil content and oil content) of the total response variation remained unexplained by the model. Thus, the fit between the quadratic model and the experimental data is good. Bias index and accuracy factors were calculated for all fried yam slices quality parameters. Perfect agreement between predictions and observations will lead to the bias factor of one. However, a bias factor less than one indicates a "fail-dangerous" model. For accuracy factors, the larger the value, the less accurate the average estimate, while a value of one indicates that there is perfect agreement between all predicted and observed value [23]. The bias index was close to one for all models. This result implies that, for this experiment, all models are good predictors fried yam slices quality. The accuracy factors are close to one for all and show that the prediction differs from the observation by fewer than 15%.

Optimization process

The optimum processing conditions of fried yam slices were obtained using optimization tool in R. The data and the target value of oil content, dry matter, texture and color parameters were set in the program. For each observed value, the model was used to predict the experimental response areas of the target values of the optimization value concerned. These specific optimization areas were then combined to determine joint optimization areas by crossing, allowing to meet optimization target values of several combined values. To determine the frying parameters range satisfying the various outlined target values, the values grid covering the entire range observed in these four factors has been previously generated:

* Pre-frying temperature of 150 to 170[degrees]C in steps of 1[degrees]C

* Pre-frying time of 5 to 15 sec in steps of 1 sec

* Final frying temperature of 170 to 190[degrees]C in steps of 1[degrees]C

* Final frying time of 2 to 4 min in step of 15 s

For each combination of frying parameters thus produced, the values predicted by the response surface models were generated. These estimated values were then compared to the target values provided for each observed value to accept or reject the frying conditions. The target values of each variable were then combined to determine a subset of frying parameters satisfying all of them. The sub-assembly thus formed being empty, the target values were removed one by one, in ascending order of priority (starting by the lightness [L.sup.*]). The assembly formed by all the target values except the lightness target values was not empty, and thus had been retained.

The second stage of optimization was to retain the frying combination parameters which not only meet the target values set, but lead to values closest to the optimum values for the observed values. The weighted distance between the value predicted by the model and the optimal target value of the values was calculated, with a decreasing weight according to priority of this variable (from seven for fat, one for clarity). The average distance from all targets was then calculated for each frying parameters combination. The closest 5% combinations to the global optimum (with the lowest overall distance from this optimum) were retained. The results showed two groups of optimal frying conditions: short pre-frying and frying conditions at high temperatures and long pre-frying and frying conditions at low temperatures. The frying conditions at high temperatures were characterized by pre-frying temperature 157-170[degrees]C for 5-9s and frying temperature 181-188[degrees]C for 2min 15s-2min 30s. For the frying conditions at low temperature, they are characterized by pre-frying temperature 150-158[degrees]C for 10-15s and frying temperature 170-177[degrees]C for 3-3min 15s. These results are in agreement with authors who have reported that an increase in oil temperature decreased the frying times and enhanced properties of deep fried products [2, 27]. Pedreschi et al. [28] reported that the use of low temperature of frying (under 160[degrees]C) reduces the concentration of acrylamide produced, but quality characteristics of the product like texture, color and oil content are negatively affected. For Fiselier et al. [29] and Romani et al. [30], the optimal frying temperature and time are influenced by the product to oil ratio and the fryer equipment. Baumann and Escher [8] found that oil temperatures between 160 and 180[degrees]C are critical for ensuring favorable structural and textural properties of the final product and this temperature is used with a frying time between 4 and 5min [2].

CONCLUSIONS

The best parameters derived by the models in the study were short pre-frying and frying conditions at high temperature characterized by pre-frying temperature at 157-170[degrees]C during 5-9s and frying temperature at 181-188[degrees]C for 2 min 15s-2 min 30s; or long pre-frying and frying conditions at low temperature characterized by pre-frying temperature at 150-158[degrees]C during 10-15s and frying temperature 170-177[degrees]C for 3 min 15s. This study also allowed for the finalization of an adiabatic system by means of an insulator in which the core temperature of fried yam slices can be maintained constant at about 55[degrees]C after 15 min of cooling for texture measurement, facilitating texture measurements.

ACKNOWLEDGEMENTS

This research was financially supported by AUF grant (University Agency from French Speaking countries) and IFAD/IITA (International Fund for the Agricultural Development/International Institute for Tropical Agriculture). Authors are grateful to Mrs. Lynn Doran and Nicolas Mabon for assistance with English.

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Toure Y (1,2,4) *, Nindjin C (1,2), Brostaux Y (3), Amani GN (1) and M Sindic (4)

* Corresponding author email: yetiomantiti@yahoo.fr/yetioman.toure@doct.ulg.ac.be

(1) Food Biochemistry laboratory and Technology of the Tropical Products (FBLTTP), University of Abobo-Adjame, B.P 801 Abidjan 02, Cote d'Ivoire

(2) Swiss centre of Scientific Research, 01 B.P. 1303 Abidjan 01, Cote d'Ivoire

(3) University of Liege-Gembloux Agro-Bio Tech, Department of Applied Statistics, Computer Science and Mathematics, Avenue de la Faculte 8, 5030 Gembloux, Belgium

(4) University of Liege-Gembloux Agro-Bio Tech, Analysis Quality and Risk Unit, Laboratory of Agro-food Quality and Safety, Passage des Deportes 2, 5030 Gembloux, Belgium
Table 1: Coded values of independent variables
attributed to each factor parameters of frying
conditions

                               Codes

Variables                -1    0     +1

[x.sub.1] ([degrees]C)   150   160   170
[x.sub.2] ([degrees]C)   5     10    15
[x.sub.3] ([degrees]C)   170   180   190
[x.sub.4] (min)          2     3     4

[x.sub.1]: Pre-frying temperature; [x.sub.2]:
Pre-frying time; [x.sub.3]: Frying temperature;
[x.sub.4]: Frying time

Table 2: Experimental, predicted and target values of fried yam
slices

Experiments    [x.sub.1]   [x.sub.2]   [x.sub.3]   [x.sub.4]
Standard
order

E1             1           0           -1          0
E2             -1          0           0           -1
E3             1           1           0           0
E4             0           0           0           0
E5             -1          0           -1          0
E6             1           0           0           1
E7             0           1           0           -1
E8             -1          1           0           0
E9             -1          0           0           1
E10            0           1           0           1
E11            0           0           0           0
E12            -1          -1          0           0
E13            0           0           1           -1
E14            0           -1          0           -1
E15            -1          0           1           0
E16            0           -1          0           1
E17            1           0           1           0
E18            0           0           -1          1
E19            0           1           1           0
E20            0           0           -1          -1
E21            0           1           -1          0
E22            0           0           0           0
E23            0           -1          1           0
E24            0           0           1           1
E25            0           -1          -1          0
E26            1           -1          0           0
E27            1           0           0           -1
Target values

Experiments    Oil content (MG, g x
Standard       [kg.sup.-1] db) values
order

                MG.observed      MG.predicted

E1             178 [+ or -] 15       168
E2             123 [+ or -] 02       152
E3              17 [+ or -] 07       163
E4             168 [+ or -] 05       147
E5             166 [+ or -] 03       138
E6             236 [+ or -] 03       208
E7             126 [+ or -] 06       135
E8             139 [+ or -] 07       133
E9             112 [+ or -] 03       112
E10            182 [+ or -] 06       161
E11            163 [+ or -] 07       147
E12            127 [+ or -] 06       131
E13            141 [+ or -] 02       128
E14            107 [+ or -] 13       133
E15            151 [+ or -] 01       126
E16            128 [+ or -] 03       159
E17            142 [+ or -] 08       156
E18            118 [+ or -] 17       166
E19            135 [+ or -] 02       168
E20            151 [+ or -] 09       140
E21            102 [+ or -] 06       128
E22            166 [+ or -] 18       147
E23            126 [+ or -] 03       114
E24            145 [+ or -] 11       154
E25            196 [+ or -] 02       177
E26            155 [+ or -] 03       161
E27            115 [+ or -] 01       116

Target values    The possible smallest

Experiments         Texture (Fmax N) values
Standard
order

                Fmax.observed       Fmax.predicted

E1               8 [+ or -] 1.1         9.17
E2             5.2 [+ or -] 2.3         6.60
E3             7.2 [+ or -] 1.3         6.60
E4             9.6 [+ or -] 2.1         9.01
E5             9.9 [+ or -] 2.6         9.78
E6                  7.60                7.42
E7             5.7 [+ or -] 1.4         6.19
E8             8.2 [+ or -] 1.4         7.21
E9            12.3 [+ or -] 1.2       12.03
E10           7.03 [+ or -] 2.2         7.62
E11           10.6 [+ or -] 1.5         9.01
E12            8.4 [+ or -] 1.8         8.56
E13            9.8 [+ or -] 1.7         9.45
E14            8.9 [+ or -] 1.0         7.53
E15            6.7 [+ or -] 0.7         8.85
E16            9.5 [+ or -] 1.3         8.97
E17            8.3 [+ or -] 1;7         8.23
E18           13.1 [+ or -] 1.5        11.82
E19            5.4 [+ or -] 2.0         4.34
E20            9.6 [+ or -] 0.4         7.13
E21            7.9 [+ or -] 2.1         9.47
E22            9.1 [+ or -] 3.6         9.01
E23           10.6 [+ or -] 1;6         9.88
E24            6.8 [+ or -] 2.3         7.63
E25            4.7 [+ or -] 1.4         6.62
E26            7.4 [+ or -] 1.8         7.94
E27            8.5 [+ or -] 2.7         9.98

Target values                  08-13N

Experiments         Dry matter ( MS, g.
Standard          values [k.sup.g-1] wb)
order

                MS.observed       MS.predicted

E1             617 [+ or -] 06       598
E2             538 [+ or -] 17       547
E3             553 [+ or -] 17       598
E4             647 [+ or -] 00       598
E5             563 [+ or -] 17       598
E6             558 [+ or -] 34       648
E7             496 [+ or -] 24       547
E8             534 [+ or -] 10       598
E9             593 [+ or -] 26       648
E10             76 [+ or -] 15       648
E11            601 [+ or -] 03       598
E12            624 [+ or -] 31       598
E13            534 [+ or -] 00       547
E14            551 [+ or -] 30       547
E15            579 [+ or -] 11       598
E16            673 [+ or -] 23       648
E17            611 [+ or -] 07       598
E18            632 [+ or -] 16       648
E19            746 [+ or -] 22       598
E20            557 [+ or -] 14       547
E21            641 [+ or -] 14       598
E22             62 [+ or -] 12       598
E23            663 [+ or -] 07       598
E24            621 [+ or -] 02       648
E25            469 [+ or -] 11       598
E26            602 [+ or -] 05       598
E27            554 [+ or -] 07       547

Target values               550-620

Experiments        Colour parameters
Standard
order

                  Hue angle (h*) values

               h*.observed   h*.predicted

E1                88.3           85.3
E2                89.6           85.6
E3                80.1           81.8
E4                85.7           85.5
E5                86.4           88.3
E6                74.7           76.0
E7                89.8           88.7
E8                83.0           84.9
E9                86.2           84.2
E10               82.2           82.3
E11               88.1           85.5
E12               84.0           84.9
E13               86.9           85.3
E14               86.6           88.7
E15               80.0           81.4
E16               84.3           82.3
E17               81.8           78.3
E18               86.9           85.7
E19               82.2           82.0
E20               89.2           92.2
E21               89.0           89.0
E22               87.2           85.5
E23               78.6           82.0
E24               77.3           78.8
E25               88.6           89.0
E26               77.5           81.8
E27               88.3           87.6
Target values            85-90

Experiments           Colour parameters
Standard
order

                         Redness (a*)

                 a*.observed        a*.predicted

E1             1.0 [+ or -] 0.5        2.9
E2               2 [+ or -] 0.2        2.5
E3             7.4 [+ or -] 1.0        6.8
E4             2.7 [+ or -] 0.5        2.5
E5             2.3 [+ or -] 0.5        0.1
E6            12.3 [+ or -] 0.8       10.6
E7             0.1 [+ or -] 0.1        0.9
E8             4.8 [+ or -] 0.5        4.0
E9             2.4 [+ or -] 0.5        3.4
E10            5.9 [+ or -] 0.8        6.2
E11            1.2 [+ or -] 0.4        2.5
E12              4 [+ or -] 0.4        4.8
E13            1.8 [+ or -] 0.2        0.9
E14              2 [+ or -] 0.3        1.6
E15            7.3 [+ or -] 0.5        5.8
E16            4.1 [+ or -] 0.4        7.0
E17            6.4 [+ or -] 0.9        8.6
E18            1.9 [+ or -] 0.6        0.6
E19           6.20 [+ or -] .9         6.4
E20              2 [+ or -] 0.1        1.3
E21            0.6 [+ or -] 0.2        0.7
E22            1.7 [+ or -] 0.3        2.5
E23            9.1 [+ or -] 1.1        7.1
E24           10.3 [+ or -] 1.6        9.7
E25            0.8 [+ or -] 0.7        1.5
E26            9.6 [+ or -] 1.2        7.6
E27            0.9 [+ or -] 0.1        0.9
Target values             (-2) - (+8)

Experiments        Colour parameters
Standard
order

                   Chroma (C*) values

               c*.observed   c*.predicted

E1                33.5           35.6
E2                32.6           34.0
E3                43.0           41.5
E4                36.3           34.9
E5                35.7           32.8
E6                46.5           46.9
E7                29.4           31.0
E8                39.9           38.6
E9                36.8           37.8
E10               43.3           44.3
E11               36.1           34.9
E12               37.6           39.0
E13               34.2           34.7
E14               33.9           34.6
E15               42.0           42.4
E16               41.3           41.4
E17               44.8           45.3
E18               35.8           35.1
E19               45.7           44.2
E20               30.1           28.4
E21               32.9           34.5
E22               35.5           34.9
E23               45.9           44.6
E24               46.7           48.2
E25               33.4           34.9
E26               44.4           41.9
E27               29.7           30.6
Target values             <91

Experiments           Colour parameters
Standard
order

                     Lighness (L*) values

                 L*.observed       L*.predicted

E1             77.5 [+ or -] 1.2       76.7
E2             79.9 [+ or -] 0.9       77.2
E3             71.2 [+ or -] 0.5       71.0
E4             76.2 [+ or -] 1.5       76.8
E5             80.5 [+ or -] 0.6       80.8
E6             64.6 [+ or -] 1.6       66.2
E7             80.6 [+ or -] 0.3       80.9
E8             73.3 [+ or -] 1.2       75.1
E9             77.2 [+ or -] 0.8       76.4
E10            69.9 [+ or -] 2.2       69.3
E11            80.7 [+ or -] 0.7       76.8
E12            75.7 [+ or -] 1.6       74.5
E13            76.1 [+ or -] 0.8       78.7
E14            76.6 [+ or -] 0.9       75.6
E15            70.2 [+ or -] 1.1       72.8
E16            75.3 [+ or -] 0.9       73.4
E17            71.4 [+ or -] 1.1       68.7
E18            78.2 [+ or -] 1.5       79.8
E19              72 [+ or -] 1.4       71.1
E20            79.3 [+ or -] 0.7       81.9
E21            79.5 [+ or -] 1.0       79.1
E22              79 [+ or -] 0.7       76.8
E23            69.6 [+ or -] 1.6       70.5
E24            65.4 [+ or -] 2.4       67.0
E25            77.9 [+ or -] 1.1       78.5
E26            67.8 [+ or -] 2.1       70.4
E27            79.5 [+ or -] 0.4       79.2
Target values                  60-70

A Box-Behnken experimental design was applied with four controlled
factors: [x.sub.1]: Pre-frying temperature; [x.sub.2]: Pre-frying
time; [x.sub.3]: Frying temperature; [x.sub.4]: Frying time; Ei:
experiment standard order.

Table 3: Significance of the coefficients used in the Box and
Behnken (1960) experimental design adopted for estimating fried
yam slices quality, obtained after multiple regression analysis
([x.sub.1]: Pre-frying temperature; [x.sub.2]: Pre-frying time;
[x.sub.3]: Frying temperature; [x.sub.4]: Frying time)

                                    Oil content    Texture
                                     (MG, g x     (Fmax, N)
                                    [kg.sup.-1]
                                        db)

Response mean     [[beta].sub.0]      147 **       9.01 **
[x.sub.1]         [[beta].sub.1]      1.48 *      -0.31 (NS)
[x.sub.2]         [[beta].sub.2]     0.13 (NS)    -0.67 (NS)
[x.sub.3]         [[beta].sub.3]    -0.59 (NS)    -0.47 (NS)
[x.sub.4]         [[beta].sub.4]     1.32 (NS)    0.72 (NS)
[x.sub.1.sup.2]   [[beta].sub.11]                     ~
[x.sub.2.sup.2]   [[beta].sub.22]                  -1.43 *
[x.sub.3.sup.2]   [[beta].sub.33]                     ~
[x.sub.1]         [[beta].sub.14]      3.3 *       -2.00 **
  [x.sub.4]
[x.sub.2]         [[beta].sub.23]     2.56 *       -2.1 **
  [x.sub.3]
[x.sub.2]         [[beta].sub.24]                     ~
  [x.sub.4]
[x.sub.3]         [[beta].sub.34]                  -1.63 *
  [x.sub.4]

                                    Dry matter     Colour
                                     (MS, g x     parameter
                                    [kg.sup.-1]
                                        wb)

                                                  Hue angle
                                                    (h *)

Response mean     [[beta].sub.0]     59.77 **     85.51 **
[x.sub.1]         [[beta].sub.1]         ~         -1.54 *
[x.sub.2]         [[beta].sub.2]         ~            ~
[x.sub.3]         [[beta].sub.3]         ~        -3.47 **
[x.sub.4]         [[beta].sub.4]      5.06 **     -3.23 **
[x.sub.1.sup.2]   [[beta].sub.11]        ~         -2.18 *
[x.sub.2.sup.2]   [[beta].sub.22]        ~            ~
[x.sub.3.sup.2]   [[beta].sub.33]        ~            ~
[x.sub.1]         [[beta].sub.14]        ~         -2.55 *
  [x.sub.4]
[x.sub.2]         [[beta].sub.23]        ~            ~
  [x.sub.3]
[x.sub.2]         [[beta].sub.24]        ~            ~
  [x.sub.4]
[x.sub.3]         [[beta].sub.34]        ~            ~
  [x.sub.4]

                                           Colour
                                          parameter

                                     Redness       Chroma
                                      (a *)        (C *)

Response mean     [[beta].sub.0]     2.49 **      34.86 **
[x.sub.1]         [[beta].sub.1]      1.42 *       1.44 *
[x.sub.2]         [[beta].sub.2]    -0.38 (NS)   -0.19 (NS)
[x.sub.3]         [[beta].sub.3]     2.84 **      4.83 **
[x.sub.4]         [[beta].sub.4]     2.66 **      5.04 **
[x.sub.1.sup.2]   [[beta].sub.11]     1.88 *       2.45 *
[x.sub.2.sup.2]   [[beta].sub.22]   1.43 (NS)      2.97 *
[x.sub.3.sup.2]   [[beta].sub.33]       ~          1.72 *
[x.sub.1]         [[beta].sub.14]     2.2 *        3.15 *
  [x.sub.4]
[x.sub.2]         [[beta].sub.23]       ~            ~
  [x.sub.3]
[x.sub.2]         [[beta].sub.24]       ~        1.63 (NS)
  [x.sub.4]
[x.sub.3]         [[beta].sub.34]   1.75 (NS)     1.7 (NS)
  [x.sub.4]

                                     Colour
                                    parameter

                                    Lighness
                                     (L *)

Response mean     [[beta].sub.0]    76.83 **
[x.sub.1]         [[beta].sub.1]    -2.07 *
[x.sub.2]         [[beta].sub.2]    0.3 (NS)
[x.sub.3]         [[beta].sub.3]    -4.02 **
[x.sub.4]         [[beta].sub.4]    -3.45 **
[x.sub.1.sup.2]   [[beta].sub.11]   -2.09 *
[x.sub.2.sup.2]   [[beta].sub.22]    2.01 *
[x.sub.3.sup.2]   [[beta].sub.33]      ~
[x.sub.1]         [[beta].sub.14]   -3.05 *
  [x.sub.4]
[x.sub.2]         [[beta].sub.23]      ~
  [x.sub.3]
[x.sub.2]         [[beta].sub.24]   -2.35 *
  [x.sub.4]
[x.sub.3]         [[beta].sub.34]    -2.4 *
  [x.sub.4]

~ Coefficient = 0

* Significant to the predictive regression model (P < 0.05).

** Highly significant to the predictive regression model (P < 0.01).

wb is weight in wet basis and db is weight in dry basis.

Table 4: ANOVA of quadratic response surface models for fried yam
slices parameters

                  Oil content    Texture    Dry matter     Colour
                   (MG, g x     (Fmax, N)   (MS, g x      parameter
                  [kg.sup.-1]               [kg.sup.-1]
                      db)                       wb)
                                                          Hue angle
                                                            (h *)

[R.sup.2]            0.51         0.68         0.27          0.75
F Ratio            101.56         3.51         0.48          3.01
p value              0.00         0.24         0.50          0.06
Bias indice         1.009        1.009        1.004         1.000
Accuracy            1.127        1.125        1.070         1.021
  indice

                             Colour
                            parameter

                  Redness   Chroma   Lighness
                   (a *)     (C *)    (L *)

[R.sup.2]           0.83      0.94     0.86
F Ratio             5.62     21.32     0.93
p value             0.16      0.05     0.63
Bias indice        1.010     1.001    1.000
Accuracy           1.678     1.034    1.020
  indice
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Article Details
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Author:Yetioman, Toure; Nindjin, C.; Brostaux, Y.; Amani, G.N.; Sindic, M.
Publication:African Journal of Food, Agriculture, Nutrition and Development
Article Type:Report
Geographic Code:6COTE
Date:Dec 1, 2012
Words:7514
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