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Characterization of Prototype Formulated Particleboards from Agroindustrial Lignocellulose Biomass Bonded with Chemically Modified Cassava Peel Starch.

1. Introduction

Crop residue is an alternative raw material for use in the construction industry [1]. Particleboards are used in the construction industry. Conventional methods of construction involve the use of wood from trees as the main raw material. Because of the decrease in the tree cover, researchers have focused on the use of crop residues as a substitute for wood; however, some crop residues have not been used. Crop residues contain high lignin content [2] and have remain underutilized [3]. Crop residues are disposed off through burning in open fields [4]. In addition, crop residues contain hemicellulose and cellulose which contain hydroxyl and carboxylate groups. The functional groups provide reactive sites for polycondensation polymerization [2]. These inherent reactive sites are underutilized as wood particles are encapsulated with the binder during particleboard formulation. Commonly used binders are phenol and urea formaldehydes [5].

Surface properties of the lignocellulose material are of importance in the compatibility of composite materials. Interfacial interactions between components of the composite material are controlled to an extent by chemical composition and morphology. Surface modification is covalently bonded through esterification. Esterification is enhanced through activation of the agents used in modification before treatment of the lignocellulose material. Inactive modifying agents result in insufficient interfacial adhesion that leads to moisture intrusion. Incompatibility results in decreased mechanical properties of particleboards due to poor stress transition from one material to the other. Interfacial adhesion and chemical approaches are enhanced by addition of coupling agents such as alkali treatment, esterification, and use of coupling materials. Coupling agents specifically create significant bonds between the lignocellulose material and other polymer matrices. Coupling agents include a nucleophile-containing molecule.

Lignocellulose materials such as crop residues are composed of lignin, cellulose, and hemicellulose. These components contain hydroxyl functional groups. Hydroxyl groups determine the physical and chemical dimensions of a material and are chemically modified to carboxylate and aldehyde groups. Aldehydes such as formaldehyde are currently used as a component of resins used as a binder. The carboxylate group is the major functional group utilized during the esterification process. The carboxylate group is formed by oxidation of the hydroxyl group using oxidizing agents [6]. Oxidizing agents include hydrogen peroxide. Hydrogen peroxide decomposes in alkaline media to produce hydroperoxy anion (HOO-) [7] as follows:

[H.sub.2][O.sub.2] [??] [HOO.sup.-] + [H.sup.+] (1)

Hydroperoxy anion reacts with undissociated [H.sub.2][O.sub.2] to form highly reactive hydroxyl radicals (OH) and superoxide ([O.sub.2.sup.-]) as illustrated in the following reaction:

[H.sub.2][O.sub.2] + [HOO.sup.-] [??] [H.sup.+] + [O.sub.2.sup.-] + [H.sub.2]O (2)

Hydrogen peroxide under alkaline media therefore produces peroxide anion that cleaves the side chains of lignin and opens the benzene ring to form oxalic acid, formic acid, and malonic acid [7], as shown in Scheme 1.

Hydroxyl groups in cellulose are converted to carboxylic acid and aldehydes [8], as shown in Scheme 2.

Cleavage of the lignocellulose material with an oxidizing agent leads to synthesis of a mixture of functional groups such as carboxylate and aldehyde. Hydroxyl groups combine through etherification. A hydroxyl group reacts with the carboxylic group through condensation polymerization to form a covalent bond through esterification. Research has shown that chemical treatment of cellulose fibres and lignin enhances the binding efficiency of natural fibres and lignin compounds into the starch composite matrix [9]. Lignin functional groups are activated by bases [10]. Activated lignin leads to increased reactive sites with other polymers [11]. This results in production of natural fibre-reinforced polymer matrix composites [12]. Lignin has other inherent characteristics in that it plasticizes starch [13].

Bio-based adhesives are an alternative to formaldehyde-based adhesives to use as binders in particleboard formulation [14-16]. Various starch modifications on their crystalline nature include chemical treatments such as oxidation [17] and air [18], esterification [19], and cationization [20,21]. Physical modifications of starch include mechanical activation [22], microwave [23, 24], ultrasonic degradation [25, 26], heatmoisture treatment [27], and enzymatic treatment [28-30]. Modified starch has been utilized in particleboard formulation [31-34]. Bio-based binders such as cassava peel starch are an alternative source of functional groups. Chemical compatibility results in formation of a strong chemical bond [35].

Starch abundance has diverted its use from food to nonfood applications [36]. Some of the nonfood applications include synthesis of bioplastic materials [37]. Alkali treatment of starch molecules involves breaking of intramolecular and intermolecular hydrogen bonding that holds the structure together. Starch molecules are hydrolyzed with an alkali to form a nucleophile [38], as shown in Scheme 3.

Copolymerization of natural polymers from crops emerges as a solution to the high cost of biodegradable materials [39]. The biocomposite material from cassava starch, fibres, and silica had poor internal bonding due to the use of a weak base in pretreatment of cellulose fibres [40]. Crop residues are alternative raw materials for copolymerization with other natural polymers such as starch that allow the country production to grow [41]. Particleboards made from commercially formulated particles and starch-based adhesives did not meet Japanese industrial standards for particleboards (JIS A5908) [42]. This was a result of the use of water to hydrolyze starch. Particleboards made from cassava root and cassava starch mix failed to fulfill recommended ANSI/A2 08.1-1999 standards [43]. Starch was hydrolyzed with water at 80[degrees]C, which is a higher gelatinization temperature of starch [44].

Biopolymers derived from renewable resources are an emerging class of advanced materials with a wide range of industrial applications [45]. Researchers have focused on renewable polymer blends such as composite materials [46]. Major natural polymers include starch, lignin, cellulose, and hemicellulose. Chemical modification of these polymers yields materials with tailored properties suitable for use in formulation of composite materials molded to form particleboards. Various particleboards are used in the building industry (Scheme 4).

The starch-lignin matrix showed reduction in enthalpy of combustion [49]. Therefore, the main objective of this work was to evaluate the physical and mechanical properties of particleboards formulated between chemically treated lignin and modified starch blend. Polyblending is one of the most commercially important and inexpensive ways of developing new materials from readily available base polymers [50]. Polyblending aims at production of high-performance materials at a reduced cost. Crop residues involved were rice husks, maize stalk, and sugarcane bagasse. Cassava starch was used as a binder.

2. Materials and Methods

2.1. Preparation of Materials. Maize stalks were collected at random from a farm in Nakuru County (0[degrees]18'S, 36[degrees]4'E), sugarcane bagasse from Kisumu County (0[degrees]5'S, 34[degrees]46'E), and rice husks from Mwea (0[degrees]37'S, 37[degrees]20'E), Kirinyaga County, which are all counties in Kenya. Maize stalk was cut into small sizes less than 20 mm in width using a chuff cutter and ground using a mill crusher to particle size less than 10 mm. Sugarcane bagasse which was obtained from the sugar factory was not ground further. Rice husks were ground using the mill to particle size less than 10 mm. All the three plant residues were dried in an oven at 105[degrees]C, to a constant mass. Cassava was obtained at random from Thika, Kiambu County. It was peeled, chopped into smaller pieces, and sun-dried to a constant mass. The dried cassava was ground using a maize mill to 100 mesh size. The ground cassava starch was then placed in an oven at 105[degrees]C to a constant mass. Dried cassava was pulverized to 150 mesh size.

2.2. Determination ofLignin Content. Lignin mass was determined through the Klason method [51]. One gram of oven-dried plant residues was weighed in triplicates and transferred to 100 ml Pyrex beakers. 15 ml of 72% sulfuric acid was cooled to 15[degrees]C and added gradually while continuously stirring and macerating the material with a glass rod. The mixture was kept in a water bath maintained at 20[degrees]C for two hours while being stirred continuously. The contents of the beaker were transferred to an Erlenmeyer flask containing 400 ml of water. The resultant solution was topped to 575 ml using water. The solution was boiled for four hours using a reflux condenser. The resultant mixture was allowed to settle overnight. The mixture was then filtered. The residue (lignin) was washed with distilled water and dried to constant weight in an oven at 105[degrees]C. The lignin content was calculated from the oven-dried weight of the residue and reported as the average as shown in equation (3). The samples were labeled according to their source: lignin from rice husks (LRH), lignin from maize stalk (LMS), and lignin from sugarcane bagasse (LSCB).

Lignin content (%) = [M.sub.b] - [M.sub.a]/[M.sub.b] x 100, (3)

where [M.sub.b] is the oven-dried mass of the lignocellulose material before digestion and [M.sub.a] is the oven-dried mass after digestion with acid.

2.3. Formulation of Particleboards. Formulation of particleboards was adopted from a method used for starch-lignin polymer preparation [52], but with improvements. 250 [cm.sup.3] of 0.4 M sodium hydroxide was preheated on an electric heater to 40[degrees]C in a 500 [cm.sup.3] Pyrex beaker. 12.5 g of ground cassava starch was then added while continuously stirring the mixture. The temperature of the mixture was gradually raised and maintained between 55 and 60[degrees]C for 15 minutes. 0.2 g of borax was then added to the mixture while continuous stirring for 15 minutes. While being still hot, the hydrolyzed starch was transferred into a 1000 [cm.sup.3] plastic beaker. 50 g ground and dried maize stalk was added into the hot hydrolyzed starch. The mixture was mechanically mixed and allowed to cure for two hours at room temperature. The mixture was then transferred into a metallic mold (internal dimensions: 300 mm by 100 mm by 20 mm) with an internal lining of the polyethylene sheet. The resulting mixture was then compressed at a pressure of 6.5 Nmm"2, at 30[degrees]C for 6 minutes, and then air-dried for 48 hours. The resultant molded composite material was dried to a constant mass using an oven maintained at 60[degrees]C. The above procedure was repeated but using bagasse and rice husks separately in place of maize stalk. The resultant particleboards were labeled according to their lignocellulose materials used and the modified starch used. Those made from rice husks, maize stalk, and sugarcane bagasse were labeled PBR/HS, PBM/HS, and PBS/HS, respectively. Those formulated with rice husks, maize stalk, and sugarcane bagasse and oxidized starch (OS) as a binder were labeled PBR/OS, PBM/OS, and PBS/OS, respectively. Particleboards formulated with rice husks, maize stalk, and sugarcane bagasse and dextrinized starch (DS) as a binder were labeled PBR/DS, PBM/DS, and PBS/ DS. Particleboards formulated with urea-oxidized mix as a binder were labeled PBR/U/OS, PBM/U/OS, and PBS/U/OS, respectively.

2.4. Particleboard Property Evaluation. Physical (density, moisture content (MC), water absorption (WA), and thickness swelling (TS)) and mechanical (internal bonding (IB), modulus of rupture (MOR), and modulus of elasticity (MOE)) tests are important specifications for particleboards. They were measured for each formulated particleboard. Data were analyzed using Excel through data analysis (ANOVA: single factor) at the 95% confidence level (P [less than or equal to] 0.05). Tukey's honestly significant difference (HSD) test was performed to further determine the significance level of the test properties.

2.5. Determination of Starch Content. Ten millilitres of 0.0304 M potassium ferricyanide reagent were pipetted into clean 100 ml Erlenmeyer flasks. 5.0 ml of 2.5 M sodium hydroxide was then added and mixed thoroughly while heating. Five drops of the dilute methylene blue indicator were added, and the resulting mixture was titrated with 2.0 ml starch till the indicator changed to colourless solution. The titre readings were noted. Titration was repeated three times for each sample till concurrent titre values were obtained [53]. The starch content was calculated using the following equation:

starch (g) /100 g fresh weight [10.sup.a] x [100.sup.b] x [0.9.sup.c] x 100/T x [2.0.sup.d] x 1000, (4)

where a is the titre obtained for the ferricyanide reagent, b is the total volume of the hydrolyzed starch, c is the factor used for converting sugar to starch (0.9), T is the titre obtained for the hydrolyzed starch (ml), and d is the weight of the cassava sample (g).

2.6. Testing. Physical tests for density, moisture content, water absorption, and thickness swelling were done. Mechanical tests for internal bonding, modulus of rupture, and modulus of elasticity were done. All tests were done using the standard test methods for evaluating properties of woodbased fibres and particle panel materials (ASTM D 1037-99). Raw materials and formulated boards were subjected to chemical analysis [54].

2.6.1. Density. Density of the particleboards was determined as a quotient of the difference between air-dried weight and air-dried volume:

Density (g/[cm.sup.-3]) = [W.sub.a] - [W.sub.o]/[V.sub.o], (5)

where [W.sub.a] is the air-dried weight and [V.sub.a] is the air-dried volume.

Dimensions were taken with a micrometer screw, and weight was measured using a Mettler AJ150 analytical balance.

2.6.2. Moisture Content. The moisture content was obtained by determining the mass of the boards before oven-drying and after oven-drying:

moisture content (%) = [W.sub.a] - [W.sub.o]/[W.sub.o], (6)

where [W.sub.a] is the air-dried weight and [W.sub.o] is the oven-dried weight.

2.6.3. Water Absorption and Thickness Swelling. Water absorption and thickness swelling tests were done according to the ASTM standard method (ASTMD1037). Test pieces, 300 mm x 50 mm x 2 mm, were cut and immersed in distilled water in a glass vessel and maintained at a temperature of 23[degrees]C for every 2 hours and 24-hour interval. The weight and thickness of the samples were measured before and immediately after soaking within the 10-minute interval and used to calculate water absorption and thickness swelling.

2.6.4. Internal Bond Strength. Internal bond strength (IB) measurements were performed on 5 cm x 5 cm square probes at a crosshead speed of 1.33 mm/min. IB was calculated using the following equation:

[sigma]t = Wtb x t, (7)

where [sigma]t = tensile stress (N/[mm.sup.2]), Wt = failure tensile load (N), b = breadth of the specimen (mm), and t = thickness of the specimen.

2.6.5. Static Bending Test. Particleboards formulated were cut into various specimens according to the ASTM standard method (ASTM D1037-99). The rectangular 50 mm wide, 275 mm long, and 20 mm thick pieces were cut from each full particleboard. The pieces were used for thickness swelling and three-point-flex measurement of MOR and MOE, respectively. The 5.1 cm x 5.1 cm square pieces were used for IB measurement. The mechanical properties were determined using an Instron testing machine (model 1122; Instron Corporation, Canton, MA) with the speed of the movable crosshead of 4 mm/min for the TS test and 5 mm/ min for three-point-flex and IB tests. The reported value is the average of triplicate measurements.

2.6.6. Fourier Transform Infrared (FTIR) Spectroscopy. Fourier transform infrared (FTIR) spectroscopy was used to characterize the type of functional groups existing in the raw materials and formulated particleboards. Pellets were prepared by mixing 5 mg of powder of each sample type with 95 mg of finely ground potassium bromide (KBr) and pressing the mixture into pellets that are approximately 1 mm in thickness. Particleboards were maintained at 102[degrees]C for 24 hours in an oven. Materials were characterized by the attenuated total reflectance (ATR) mode using the potassium bromide (KBr) disk (model Alpha 1005 4238 from Bruker instrument). Each spectrum was recorded from 4000 to 400 [cm.sup.-1].

2.7. Results and Discussion

2.7.1. Lignin Content in Various Crop Residues. Results of the lignin content in the three lignocellulose materials are shown in Figure 1. Lignin from rice husks, maize stalk, and sugarcane bagasse is denoted as LRH, LMS, and LSCB, respectively.

The lignin content in sugarcane bagasse was more than that in rice husks and maize stalk. Maize stalk had the lowest percentage of lignin content among the three lignocellulose materials. This is within the range of 10 to 25 percent of the lignin content found in wood, a conventional lignocellulose material used in formulation of particleboards [55]. The lignin content determines the physical properties of the particleboard. These properties include water absorption and thickness swelling. Lignin added into a composite material during particleboard formulation reduces water absorption and thickness swelling [56]. Lignin contains a small number of hydroxyl groups that form hydrogen bonding with water [57]. The three lignocellulose materials are suitable for making particleboards. Sugarcane bagasse waste had been deposited for more than six months and thus had been concentrated naturally. Absence of cellulose and hemicellulose was due to decomposition. Maize stalk was collected immediately after harvest and thus had not been decomposed. Rice husks contain high percentage of silica and lignin content. Lignin obtained through the Klason method involves hydrolysis and solubilization of cellulose and hemicellulose from crop residues. Cellulose and hemicellulose compose the highest percentage in maize stalk with more than 88.6% on average. Rice husks contain an average of 15.9% of lignin compared to the total mass of the matrix. Rice husks contain high levels of silica in addition to lignin. This lowers their nutritional value to be used as animal fodder. Sugarcane bagasse contains high levels of lignin at an average of 21.5%, making it less nutritive to be used as fodder.

2.7.2. Tukey's Statistical Analysis Results. One-dimensional ANOVA using the Tukey method for density, moisture content (MC), thickness swelling (TS), water absorption (WA), internal bonding (IB), modulus of rupture (MOR), and modulus of elasticity (MOE) is presented in Table 1.

2.7.3. Particleboard Densities. The average densities of particleboards are shown in Figure 2.

Statistically, no significant difference was observed between the particleboards formulated using rice husks (Table 1). Density of the boards ranged from 0.612 to 0.63 g/ [cm.sup.3]. The densities of the particleboards made from the rice husks, maize stalk, and sugarcane bagasse ranged from 0.604 g/[cm.sup.3] to 0.627 g/[cm.sup.3]. Densities formulated from rice husks and hydrolyzed starch were significantly different from those from dextrinized starch, oxidized starch, and urea-oxidized starch at P = 0.05. The one-dimensional Tukey method showed P > 0.05 between PBR/DS, PBR/OS, and PBR/U/OS. Comparing the P value of the three with PBR/HS showed P < 0.05. There is a significant difference between the particleboards formulated from maize stalk and various chemically modified starch, P > 0.05. Similar trends were also observed in particleboards formulated from sugarcane bagasse and cassava-based binders, P> 0.05. Results showed the synthesized particleboards fell in the category of low density which is d < 0.640 [58]. Research investigated by formulation of composite boards from oil palm trunk stems showed densities that ranged from 0.441 to 0.597g/[cm.sup.3] [59].

Particleboards formulated using maize stalk and sugarcane bagasse showed a significant difference, as shown in Table 1. Particleboards made from dextrinized starch had the highest densities across the three lignocellulose materials. Densities of the composite material are affected by the interaction between the lignocellulose materials and the binder. An increase in the interaction reduces the voids in the resulting blend, resulting in higher density. Dextrinized starch contains a high number of hydroxyl groups. During particleboard formulation, the hydroxyl groups are involved in esterification, leading to the formation of covalent bonding and others through hydrogen bonding. This reduces the spaces between the blended materials, thus increasing the density. Hydrolyzed starch contains hydroxyl groups that are partially converted into sodium salt [60] as follows:

St - OH + NaOH [left and right arrow] St - ONa + [H.sub.2]O (8)

This minimizes the interaction between lignocellulose materials and the modified starch. These result in formation of voids that increase the volume of the composite material, thus reducing the density of the particleboards.

2.7.4. Moisture Content. Figure 3 shows the moisture content of the particleboards.

Moisture influences the density of particleboard as it serves as a means of heat transfer. Heat transfer from composite mat faces to the composite mat core helps in the curing of the binder [61]. Particleboards with high moisture content showed highest densities. High moisture content affects the mechanical properties such as the modulus of rupture. All those boards with high moisture content showed lowest MOR. Particleboards from maize stalk bonded with dextrinized starch had the highest amount of moisture content. Dextrinization involves cleavage of molecular chains in starch granules to afford smaller structural units [62]. This results in the increase of surface area of the lignocellulose material which exposes the hydroxyl group that interacts with water vapour in the atmosphere. The moisture content in lignocellulose materials is controlled by the available hydroxyl group content and their accessibility [63]. During oxidation of starch, hydroxyl groups are converted to aldehydes and carboxylic groups [64].

Aldehydes and carboxylic groups are used during esterification. The hydroxyl groups are therefore reduced in the process of particleboard formulation. Hydroxyl groups transformed into aldehydes and carboxylic groups are used in formation of bondage between the modified starch and the lignocellulose material. Rice husks bonded with oxidized starch and urea showed the lowest moisture content. Sodium hydroxide used reacts with silica to form silicic acid. Silicic acid is an inorganic adhesive that undergoes condensation by cross-linking and dehydration to yield less hydrated silicon dioxide phases. Porosity of the particleboard made from maize stalk is higher than that of the particleboard made from sugarcane bagasse and rice husks [65].

2.7.5. Water Absorption. Water absorption of the particleboards is shown in Figure 4.

Particleboards formulated with maize stalk and dextrinized starch as a binder had the highest water absorption of 83.87%. Maize stalk contains high content of cellulose and hemicellulose materials. Cellulose and hemicellulose contain high hydroxyl groups. Hydroxyl groups influence the physical properties of the composite materials formulated. Hydroxyl groups form hydrogen bonding with water, thus absorbing a lot of water. Particleboard with a high lignin content of 21.5% showed reduction in water absorption. Lignin is a hydrophobic material and reduces the WA of particleboards [56]. The initial high water absorption rate was due to diffusion through capillaries, vessels, and cellular walls of crop residues.

Moisture movement was restricted within the matrix. Water moves easily into large cavities of maize stalk than into small cavities of sugarcane bagasse [66]. Here, water already had enough time to permeate through the entire panel structure, and lignocellulose materials being low-density residues, a larger number of particles are needed to compose the medium-density particleboards. This allows more hygroscopic sites for water to bind. Maize stalk contains holocellulose that contains polyoses which have hygroscopic sites that promote higher WA [67]. It has been suggested that the furniture particleboard requires less than 60% long-term water absorption (ASTM D 1037-99). All particleboards made in this study showed higher water absorption than the maximum allowed by the ASTM D 1037-99 standard. This challenge was managed by addition of water repellants such as paraffin and phenolic resins during particleboard formulation [35]. All particleboards showed P < 0.05, showing there was a significant difference between different cassava-based binders.

2.7.6. Thickness Swelling. Particleboards formulated showed thickness swelling as in Figure 5.

Thickness swelling showed a direct relationship to the results obtained on water absorption. Particleboards made from maize stalks bound with dextrinized starch showed the highest TS of 23.43%. This is attributed to the presence of the cellulose material in maize stalk. PBM/DS showed the highest thickness swelling of 27.08%, and PBS/OS showed the least at 18.23 and PBR/HS at 19.32% and 25.59%, respectively.

Particleboards based on the ASTM D 1037-99(1999) standard should have a maximum thickness swelling value of 25% for general uses [68], and according to the US Standard ANSI/A208.1, the average maximum thickness swelling value is 8% (for 2 h immersion) [69]. The average TS values of all the specimens analyzed meet this minimum requirement for general uses. Pores accommodate absorbed water, resulting in swelling of the added lignocellulose materials. This phenomenon leads to more moisture buildup in the maize stalk cell wall (fibre swelling) and also in the fibre-adhesive interface. This is responsible for the changes in the dimension of particleboards, particularly in the thickness and the linear expansion due to reversible and irreversible swelling of the boards [70]. This is attributed to the presence of the hydroxyl group content formed during hydrolysis by sodium hydroxide. The amount of the hydroxyl group depends on the concentration of the lignin content. Particleboards formulated with rice husks and maize stalk did not show any significant difference, P < 0.05, while those made from sugarcane bagasse showed P > 0.05.

2.7.7. Chemical Analysis for the Particleboards

(1) Elemental Analysis. The results in Table 2 show chemical analysis for Na, Zn, Ca, and Mg in crop residues and cassava starch.

Sodium ions ([Na.sup.+]) were low in both lignocellulose materials and starch. Sodium enables the curing process of the cassava adhesive. Treatment of the starch with sodium hydroxide increased the concentration of the sodium ions. Zinc is involved in the synthesis and breakdown of carbohydrates. Chemical additives containing zinc and magnesium influence the bonding strength of the particleboards [71]. [Zn.sup.2+] improves starch granule dissolution as it penetrates into the inner structure of the starch granules and weakens the intra- and intermolecular hydrogen bonds. This results in disruption of the crystalline nature of the starch [72]. [Ca.sup.2+] influences the physicochemical properties of the starch granules and changes morphological, vibrational, mechanical, and pasting properties [73]. [Ca.sup.2+] ions influence the elastic and plastic regions of the hydrogel. [Mg.sup.2+] is a plasticizer and increases the swelling and solubility index [72]. Metal oxides and hydroxides such as MgO and Mg[(OH).sub.2] control the acidity of the reaction mixture.

(2) Fourier Transform Infrared (FTIR) Spectroscopy. Figure 6 shows several major absorption bands for native cassava starch, rice husks, sugarcane bagasse, and PBM/OS board.

A major peak was found at 3414.06 [cm.sup.-1] which was attributed to the presence of intramolecular hydrogen-bonded hydroxyl groups in single bridge compounds. Another peak was observed at 1626.98 [cm.sup.-1] which was for -OH bending. The peaks at 2484.36 [cm.sup.-1] and 1362.73 [cm.sup.-1] corresponded to C-H bending. A peak was observed at wavenumber 1229.64 [cm.sup.-1] that corresponds to C=O vibration and at 1102.34 [cm.sup.-1] that corresponds to C-O stretching. There were major functional group transformations from rice husks and gelatinized cassava starch, leading to reduction in the peak size at wavenumber 3414.06 [cm.sup.-1], -OH stretching, and increase in 2484.36 [cm.sup.-1] for C-O. Reduction in the OH peak was attributed to formation of esters and hence the formation of C-O in C-O-C. The -OH spectra that remained can be attributed to the presence of sodium hydroxide used in the pretreatment of the lignocellulose matrix, water formed through condensation polymerization, and also boric acid formed during hydrolysis of borax in sodium hydroxide. The C-H peak increased because of the addition of C-H functional groups from both cassava and lignocellulose matrices. Peaks observed at 1150 [cm.sup.-1] and 950 [cm.sup.-1] were attributed to B-O-H because of hydrolysis of borax.

2.7.8. Mechanical Properties

(1) Internal Bond. Particleboards formulated from rice husks, maize stalk, and sugarcane bagasse with various binders showed internal bond (IB), as illustrated in Figure 7.

Particleboard formulated with maize stalk and dextrinized starch showed the highest internal bonding of 2.367% N/[mm.sup.2]. Maize stalk contains low percentage of lignin and high content of cellulose and hemicellulose. The hemicellulose content increases the fibre joint strength. The bonding of fibres is described by the bonded area and the bonding strength between fibres. The high density of particleboards made from maize stalk and dextrinized starch increases fibre-to-fibre bonding strength. Density results in the improvement of fibre-to-fibre bonding [74]. Maize stalk was treated with sodium hydroxide that increases the flexibility of fibres. Sodium hydroxide increases the flexibility of lignin in maize stalk. This changes the surface morphology of lignin that influences the specific bond strength and cohesiveness in the composite material. Cellulose has been used in reinforcement of internal bondage of the composite material [75]. Cellulose provides more hydroxyl groups that are involved in chemical reactions between crop residues and the starch-based binder [76].

Particleboards formulated from rice husks showed the lowest internal bonding of 1.613 N/[mm.sup.2]. This is attributed to low hemicellulose content in the rice husks that reinforce the bondage in composite materials. The lignin content in rice husks was higher than that in maize stalk. This implies that the cellulose content is lower in rice husks. Reduction in the cellulose and hemicellulose content reduced the amount of hydroxyl groups that influences cohesion between components of the particleboard.

Particleboards met minimum requirements of IB between 0.24 and 0.4N/[mm.sup.2] for both general use and furniture manufacturing based on the European standard EN 312:2010 [77]. They also they met the minimum requirements of 0.60 N/[mm.sup.2] based on ANSI A208 for interior applications, as shown in Figure 7. The density of the particleboards is directly related to internal bonding. Particleboards made from maize stalk had the highest IB. This is attributed to the cross-linking of cellulose, hemicellulose, and lignin. At low temperatures of 40[degrees]C, the density greatly improved the IB [78]. The higher the density the more the resin was used. Findings have been reported on the effect of the increase of surface area on strength properties [79], although the increase in surface area decreases the internal bonding.

2.7.9. Static Bending Test

(1) Modulus of Rupture (MOR). Modulus of rupture of particleboards formulated in this study is presented in Figure 8.

Particleboard is a random blend of lignocellulose materials that require no orientation during board formulation. In this study, composite materials were put in a mold with no bias towards the forming direction expected. Tests for the MOR and MOE properties were taken parallel and perpendicular to the forming directions. Analysis of the test data revealed a significant difference between samples from the parallel and perpendicular directions. Particleboards from maize stalk showed the highest MOR of more than 13.96 N/[mm.sup.2]. MOR is influenced by the cross-linking of the lignocellulose materials with the binder and the particle geometry. Maize stalk contains cellulose and hemicellulose that provide hydroxyl groups that underwent esterification with carboxylic groups from oxidized starch. Esterification leads to cross-linking of starch and lignocellulose materials, hence increasing the MOR. A covalent bond is formed during the esterification process which is a strong bond. Reddy and Yang [80] have shown that a hydroxyl group and a carboxyl group react to form cross-linked molecules. In their study, the hydroxyl group from starch was cross-linked with the carboxylic group from citric acid. The findings showed improvement of the performance of bondage in composite materials [80].

Low-density particleboards formulated exceeded the minimum requirements of 2.8 N/[mm.sup.2] for interior applications based on ASNI 208.2-2009. Rice husks contain very high percentages of silica. Silica reacts with sodium hydroxide to form sodium silicate which is an adhesive [81].

(2) Modulus of Elasticity (MOE). Figure 9 shows the average MOE of particleboards made from rice husk, maize stalk, and sugarcane bagasse.

Particleboards made from sugarcane bagasse had the highest MOE of 3175.71 N/[mm.sup.2], those from rice husks had 2647.23 N/[mm.sup.2], and those from maize stalk had 2508.34 N/[mm.sup.2]. All low-density boards attained the MOE of 1241 N/[mm.sup.2] based on ASNI 208.2-2009 for interior applications. Trends in MOE are similar to those of MOR where there is no significant difference between particleboards formulated from rice husks. In addition, there was no significant difference among particleboards formulated with maize stalk and sugarcane bagasse. Low-density particleboards formulated exceeded the minimum MOR of 500 N/[mm.sup.2].

7. Conclusion

Chemical treatment of the lignocellulose material and starch led to the formation of essential functional groups used in esterification. This resulted in compatibility of lignocellulose materials and starch materials used in formulation of composite materials. Composite materials were molded to form the particleboard. The particleboard formulated showed high water absorption and thickness swelling. The results showed that mechanical properties of the formulated low-density particleboards exceeded the requirements of American Society for Testing and Materials (ANSI 208.1 1999). Furthermore, all physical properties, except water absorption and thickness swelling, met the ANSI 208.1 1999 standards. Water absorption and thickness swelling were due to a high number of hydroxyl groups. Hydroxyl groups formed hydrogen bonding with water, making the composite material interact with water. Reduction of hydroxyl groups through chemical modification resulted in introduction of carboxylate groups that formed a covalent bond between the lignocellulose material and the starch binder. Particleboards formulated showed characteristics of low density. From this study, it was apparent that rice husks, sugarcane bagasse, and maize stalk formulate low-density particleboards for interior housing applications. 10.1155/2019/1615629

Data Availability

The data used to support the findings of this study are available from the corresponding author upon request.

Conflicts of Interest

The authors declare that there are no conflicts of interest regarding the publication of this paper.


The authors acknowledge the immense support from the University of Embu for availing their chemistry laboratory for research; the Ministry of Infrastructure and Roads, where most physical and mechanical properties were investigated; the Ministry of Geology and Mines for XRF analysis; and Kenyatta University, where FTIR spectroscopy analysis was performed.


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Stephen Warui Kariuki [ID], Jackson Wachira [ID], Millien Kawira, and Genson Murithi Leonard

Department of Physical Sciences, University of Embu, P.O. Box 6-60100, Embu, Kenya

Correspondence should be addressed to Stephen Warui Kariuki;

Received 7 October 2019; Accepted 24 October 2019; Published 11 November 2019

Academic Editor: Marinos Pitsikalis

Caption: Scheme 1: Cleavage and oxidation of the lignin material in the lignocellulose material using perhydroxyl anion.

Caption: Scheme 2: Oxidation of cellulose using hydrogen peroxide in alkaline media.

Caption: Scheme 3: Effects of sodium hydroxide on changing the starch morphology by breaking intra- and intermolecular hydrogen bonding.

Caption: Scheme 4: Possible interaction mechanism between hydrolyzed starch and oxidized lignocellulose materials [47, 48].

Caption: Figure 1: Lignin content in crop residues.

Caption: Figure 2: Average densities of particleboards and their standard deviation as error bars.

Caption: Figure 3: Moisture content of particleboards.

Caption: Figure 4: Water absorption (WA) of synthesized particleboards.

Caption: Figure 5: Thickness swelling (TS) of the particleboards.

Caption: Figure 6: FTIR spectra for cassava starch, rice husks, sugarcane bagasse, and PBM/OS board.

Caption: Figure 7: IB of the particleboards formulated using rice husks, maize stalk, and sugarcane bagasse.

Caption: Figure 8: MOR of the three particleboards formulated in this study.

Caption: Figure 9: MOE of the three formulated particleboards.
Table 1: Average values of physical and mechanical properties of
particleboards formulated.

Boards                                    Physical properties

              Density (g/      MC (%)       WA (%)         TS

PBR/HS         0.612(a)       9.587(a)     76.33(a)     19.32(a)
PBR/DS         0.623(a)       9.700(b)     74.67(a)     20.63(b)
PBR/OS         0.622(a)       9.593(c)     64.67(b)     18.59(c)
PBR/U/OS       0.621(a)       9.487(d)     68.61(c)     19.12(d)

PBM/HS         0.604(a)       9.577(a)     81.33(a)     22.77(a)
PBM/DS         0.622(b)       9.843(b)     83.87(a)     23.43(b)
PBM/OS         0.621(c)       9.763(c)     72.67(b)     19.31(c)
PBM/U/OS       0.615(a)       9.593(d)     78.68(c)     19.44(d)

PBS/HS         0.608(a)       9.543(a)     66.67(a)     18.94(a)
PBS/DS         0.627(b)       9.770(b)     69.27(b)     19.88(a)
PBS/OS         0.619(ab)      9.567(a)     61.33(c)     18.23(b)
PBS/U/OS       0.611(ab)      9.553(c)     71.04(d)     18.46(c)

Boards                    Mechanical properties

                 IB          MOR           MOE

PBR/HS        1.613(a)    13.630(a)     2651.61(a)
PBR/DS        1.623(a)    13.553(a)     2875.67(b)
PBR/OS        1.657(b)    13.770(b)     2806.67(c)
PBR/U/OS      1.710(c)    14.323(c)     2891.67(d)

PBM/HS        2.220(a)    14.380(a)     2508.34(a)
PBM/DS        2.367(b)    13.960(b)     2364.20(b)
PBM/OS        2.343(c)    14.720(c)     2672.27(c)
PBM/U/OS     2.370(bd)    14.830(d)     2716.57(d)

PBS/HS        1.720(a)    13.880(a)     3175.71(a)
PBS/DS        1.677(a)    13.630(b)     2907.68(b)
PBS/OS        1.820(b)    14.134(c)     3229.08(c)
PBS/U/OS      1.950(c)    14.320(d)     3329.93(d)

Same letters show no significant difference, while different
letters show significant difference from each other in the Tukey
test at the 5% significance level.

Table 2: Chemical analysis for lignocellulose materials and
cassava starch.

                            Na                       Zn

Rice husk          0.001 [+ or -] 0.001     0.005 [+ or -] 0.001
Maize stalk        0.002 [+ or -] 0.001     0.055 [+ or -] 0.001
Bagasse            0.002 [+ or -] 0.003     0.012 [+ or -] 0.001
Cassava starch     0.003 [+ or -] 0.002     0.038 [+ or -] 0.021

                            Ca                       Mg

Rice husk          1.029 [+ or -] 0.012     0.001 [+ or -] 1.841
Maize stalk        8.021 [+ or -] 0.540    17.085 [+ or -] 2.842
Bagasse            3.893 [+ or -] 0.350    12.862 [+ or -] 2.877
Cassava starch    10.087 [+ or -] 0.321     0.001 [+ or -] 0.217
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Title Annotation:Research Article
Author:Kariuki, Stephen Warui; Wachira, Jackson; Kawira, Millien; Leonard, Genson Murithi
Publication:Advances in Materials Science and Engineering
Date:Nov 1, 2019
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