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Automatic arc welding and overlaying welding of steel using waste materials powder/Lankinis automatinis plieno suvirinimas ir apvirinimas naudojant antriniu medziagu miltelius.

1. Introduction

Mechanical characteristics of a weld depend on the flux composition and welding process parameters used in the arc automatic welding [1]. Investigation [2] shows that resistance of welded joint to tension stresses and dynamic loads is higher when microstructure of the weld contains acicular ferrite. Acicular ferrite can be formed when flux contains boron, titanium, vanadium and other material's oxides [3].

When the flux containing TiO2 is used in welding the weld is alloyed by titanium and acicular ferrite which improves mechanical characteristics of the joint [4].

Paper [5] deals with the effect of molybdenum, boron and titanium on microstructure and mechanical characteristics of the weld metal. The flux containing 21.24% Si[O.sub.2] + Ti[O.sub.2]; 27.29% CaO + MgO; 33.86% [Al.sub.2][O.sub.3] + MnO; 17.55% Ca[F.sub.2] was used. There were 0.2% Mo; 0.072% C; 1.3 - 1.5% Mn, up to 0.4% Si, 0.012% Ti and up to 0.018% B in the overlay. Small and evenly distributed inserted particles stimulated formation of the acicular ferrite. Boron distributed around austenite grains retarded formation of polygonal ferrite.

Addition of Ti[O.sub.2] into a flux influences microstructure and properties of arc welded joint [6]. Four fluxes containing 9, 12, 15 and 18 % of titanium were used for welding with low carbon wire. The same welding regimes but increasing titanium amount in the flux resulted the increase of acicular ferrite and improvement of mechanical characteristics.

Automatic submerged arc welding of pipe steel APJ H5 LA--70 resulted welded joint containing 0.7 0.99% Mo and 2.03 - 2.91% Ni which showed higher resistance to dynamic loads at low temperatures [7]. Microstructure of the weld consisted of acicular ferrite and bainite.

The effect of titanium on the APJ 5L - X70 steel subjected to submerged arc welding weld microstructure is investigated in [8]. The best proportion between microstructure and toughness was obtained at 0.02 - 0.05% of titanium in the weld. Depending on titanium amount the microstructure can contain acicular ferrite, grained ferrite, widmanstatten ferrite, bainite and others.

Various composition fluxes are used in automatic submerged arc welding of steels. Change in flux composition results the change of the weld composition and microstructure and it improves mechanical characteristics of the welded joint. No investigation related to the use of waste materials for welding is found. The objective of this investigation is to analyze microstructure and properties of the steel metal obtained in welding and overlaying welding by the use of waste material, i.e. to determine the effect of waste materials elements on the weld and overlay metal microstructure and properties.

2. Materials and test procedures

Steel Ct3 widely used in machine production and low carbon not alloyed welding wire Cb08 were selected for welding and overlaying welding tests. Specimens were prepared from 8 mm Ct3 steel bar which has been grinded and cut into 8 x 14 x 40 mm pieces. Quality of the welded joint was assesed by tension test of the 8 mm thick 40 mm width and 70 mm length plates obtained by welding of the specimens after the edges were removed. Specimens by size 6.5 x 15 x 80 mm were produced for tension tests.

Structural steel Ct3 (Russian grade) (0.14 - 0.2% C; 0.12 - 0.3% Si; 0.4 - 0.65% Mn) was subjected to automatic submerged arc welding [9] when powder mixtures were sprayed over the specimens surface and melted by welding wire Cb08 (Russian grade) (C < 0.1%; Si < 0.03%; Mn = 0.35 - 0.6%, Cr < 0.15%, Ni < 0.3) arc.

Mostly fluxes containing SiO2 and MnO are used for the welding. When the flux is melted a slag is formed in the arc burning zone, Si and Mn from it's content deoxidize welding bath metal and assure necessary metallurgical processes. It was tried instead of standard flux to apply for welding and overlaying welding powder mixtures whose main component is grinded glass. Glass component Si[O.sub.2] deoxidized weld metal and alloyed it by silicon. Powder mixtures contained crushed grinding wheels (containing SiC) and cast-iron and high speed steel P6M5 (Russian grade) crushed chips. Ti[O.sub.2] and TiC powder obtained heating titanium chips at 1050[degrees]C temperature without protective atmosphere or at 950[degrees]C temperature in carbiurizing surrounding (carbiurizer). The use of titanium chips not subjected to heat treatment is complicated because the chips are plastic and it is difficult to crush them into powder. To alloy weld and surfacing metal by manganese and chromium the industrial production Fe -70% Mn and Fe--60% Cr powder was added to the mixtures.

3. Results of the investigation and data analysis

Overlaying welding of the Ct3 steel by various materials powder mixtures resulted the layers alloyed by elements contained in powder. Composition of the powder mixtures and hardness of the surfacing layers are shown in Table 1.

The most mild layers is welded under glass powder, because it contains least carbon amount. This is proved by microstructural investigation (Fig. 1, b): amount of pearlite is smaller than in case of welding under standard AMS1 flux layer (Fig. 1, a). Even harder layers can be obtained using glass powder mixtures with other materials powder. The hardest layers were obtained in submerged arc welding using mixtures containing TiC or P6M5 powder. At high arc burning temperature welded layers were enriched by carbon, influencing layers hardenability. At the same time the layers were alloyed by titanium, tungsten, molybdenum and etc. Depending on materials used for overlaying welding, layers of various microstructures were obtained. Overlaying welding of the Ct3 steel by glass and cast iron powder mixture resulted the layer which microstructure was similar to that obtained in welding under standard flux (Fig. 1, a). More ferrite was obtained in the layer welded with powder containing Ti[O.sub.2] (Fig. 1, d). Even bainite microstructure was formed using for overlaying welding P6M5 steel chips (Fig. 1, e). Insertion of Fe--60% Cr powder into glass powder resulted dendrite microstructure of the surfacing (Fig. 1, f).

[FIGURE 1 OMITTED]

Aiming to assess weld strength structural steel Ct3 was welded using standard AMS1 flux and powder mixtures: 100% glass; 70% glass and 30% cast iron; 60% glass, 30% cast iron and 10% Ti[O.SUB.2]; 70% glass and 30% steel P6M5. In tension test fracture through base metal (not weld) was obtained in the cases, when standard flux, glass powder, and powder mixture of 70% glass and 30% cast iron was used in the welding process. Ultimate tensile strength in these test was 447 - 451 MPa what corresponds to bare metal steel Ct3 used in the welding tensile strength. The specimens welded using powder mixtures containing TiO2 and P6M5 steel chips in tension tests fractured across the weld at stress 379 - 432 MPa. Not satisfying strength of the weld is due to incomplete fusion, what is seen in the fracture. Incomplete fusion can be avoid by the use of different welding regime.

Machine part wear is one of important problems which is solved strengthening contact surfaces. Very often resistance to wear is improved by overlaying welding [10], which forms hard surfacing, or by oiling, which decreases friction between sliding surfaces [11, 12].

Steel parts often are overlaying welded by arc automatic welding using various kinds of wire and flux. In this investigation steel Ct3 was overlaying welded instead of standard flux using waste materials powder spread over the surface and welded by the electric arc between the base metal and continuously supplied welding wire [C.sub.B] 08. Compositions of materials powder mixtures and welded layers are shown in Table 2. Welded layers were alloyed by elements contained in P6M5 steel chips (W, Mo, V, Cr), grinding wheels powder (Si) and manganese in case when in to the powder mixture was inserted Fe--70%Mn powder. Carbon came to the layers from decayed SiC carbide and from P6M5 steel chips.

Welded layers are used to alloy in course of cooling. The highest primary hardening (up to 62 HRC), was obtained for the layer welded with powder mixture containing SiC and P6M5 powder (Fig. 2). The layer containing manganese in course of cooling after welding hardened up to 49 HRC, and it's tempering at 550[degrees]C temperature resulted 57 HRC hardness (secondary hardening). Secondary hardening was possible due to great amount of residual austenite in the welded layer containing manganese. Manganese is an element expanding austenite zone. Presence of residual austenite is prooved by white areas seen after etching of the test piece with 3% spirit solution of nitric acid; weak acid solution does not effect on them (Fig. 3).

X-ray examination shows presence of residual austenite. X-ray photograph of overlaying welded specimen shows that the peak of residual austenite is more intensive in comparison with martensite peak (Fig. 4, a). Such ratio of the intensities corresponds to 83% residual austenite amount. Tempering of the specimen at 550[degrees]C temperature, when residual austenite was transformed to martensite, the amount of residual austenite decreased to 13 %, and X-ray photograph (Fig. 4, b) does not show any austenite peak.

[FIGURE 2 OMITTED]

[FIGURE 3 OMITTED]

[FIGURE 4 OMITTED]

[FIGURE 5 OMITTED]

Abrasive wear resistance of welded layers was determined in the test, when rotating abrasive wheel was pushed to the specimen rotating in the opposite direction [12]. A decrease of the specimen weight was measured (Fig. 5). Wear of welded layers depends on materials used for overlaying welding. The smallest wear out was obtained in the layer welded with 60% P6M5, 20% SiC and 20% Fe-70% Mn powder mixture. Microstructure of this layer contained carbide phase and great amount of residual austenite (Fig. 3). After tempering at 550[degrees]C temperature hardness increased, wear decreased. Overlaying welding of the Ct3 steel with suitably selected materials powder mixture can result more wear-resistant layer than that of standard tool steel.

3. Conclusions

1. The use of waste material powders in welding process due to alloying elements in the powder enables to produce welded joints of necessary microstructure and properties. Welds produced using glass powder or glass and cast iron powder mixture have higher than the main metal (Ct3 steel, 447-451 MPa) tension strength.

2. Overlaying welding of Ct3 steel with glass and grinding wheels SiC powder resulted hard (up to 62 HRC) layer; addition of Fe-70% Mn powder into this mixture enabled to produce welded layer, which after tempering at 550[degrees]C temperature hardened from 49 HRC to 57 HRC.

3. The Ct3 steel subjected to overlaying welding with 60% P6M5 chips, 20[degrees]% grinding wheel SiC and 70% Fe-70% Mn powder mixture in comparison with hardened tool steel (0.9% C; 1.5% Cr) was 3-4 times more abrasive wear--resistant.

Received January 06, 2010 Accepted April 07, 2010

References

[1.] Joarder, S.C., Ghose, A.K. Study of submerged arc weld metal and heat--affected zone microstructures of a plain carbon steel. -Weld. J. Suppl. Res., 70, 1991, p.141-146.

[2.] Liu, S., Olson, D.L. The role of inclusions in controlling HSLA steel weld microstructures. -Weld. J. Suppl. Res., 65, 1986, p.139-141.

[3.] Evans, G.M. Microstructure and properties of ferritic steel welds containing Ti and B. -Weld. J. Suppl. Res., 75, 1996, p.251-254.

[4.] Paniagua, Ana Ma, Lopez--Hirata Victor, M. Sancedo Manoz Maribel, L. Influence of the chemical composition of flux on the microstructure and tensile properties of submerged arc welds. -Journal of Materials Processing Technology, 169, 2005, p.346-351.

[5.] Peng Yan, Chen Wuzha, Xu Zuze. Study of high toughness ferrite wire for submerged arc welding of pipeline steel. -Materials Characterizatons, 2001, 47, p.67-73.

[6.] Paniagua--Marcado Ana Ma, Lopez--Hirata Victor M. Dorantes--Rosales Hector J. Estrada Diaz Paulino, Valdez Diaz Elvia. Effect of TiO2 containing fluxes on the mechanical properties and microstructure in submerged arc weld steels. -Materials Characteriza tons, 2008, 80, p.36-39.

[7.] Bhole, S.D., Nemade, J.B., Collins, l., Liu Cheng. Effect of nickel and molybdenum addition on weld metal toughness in a submerged arc welded HSLA line --pipe steel. -Journal of Materials Processing Technology, 173, 2006, p.92-100.

[8.] Beidohti, B., Koukabi, A.H., Dalati, A. Effect of titanium addition on the microstructure and inclusion formation in submerged arc welded HSLA pipeline steel. -Journal of Materials Processing Technology, 2009, 209, p.4027-4035.

[9.] Ambroza, P. Submerged arc overlaying welding of structural steel by high speed steel powder. -Mechanika. -Kaunas: Technologija, 2003, Nr.5(43), p.61-64.

[10.] Jankauskas, V., Kreivaitis, R. Study of wear prediction by applying surface microgeometric parameters. -Mechanika. -Kaunas: Technologija, 2007, Nr.5(67), p.65-70.

[11.] Padgurskas, J., Kreivaitis, R., Jankauskas, V., Janulis, P., Zakarevi?iene, V., Sadauskas, S., Miknius, L. Antiwear properties of lard methyl esters and rapeseed oil with commercial ashless additives. -Mechanika. -Kaunas: Technologija, 2008, Nr.2 (70), p.67-72.

[12.] Kreivaitis, R., Padgurskas, J., Jankauskas, V., Kup?inskas, A., Makarevi?iene, V., Gumbyte, M. Tribological behavior of rapeseed oil mixtures with monoand diglycerides. -Mechanika. -Kaunas: Technologija, 2009, Nr.5 (79), p.74-78.

P. Ambroza *, L. Kavaliauskiene **, E. Pupelis ***

* Kaunas University of Technology, Kestucio 27, 44312 Kaunas, Lithuania, E-mail: petras.ambroza@ktu.lt

** Kaunas University of Technology, Kestucio 27, 44312 Kaunas, Lithuania, E-mail: lina.kavaliauskiene@ktu.lt

*** Kaunas University of Technology, Kestucio 27, 44312 Kaunas, Lithuania, E- mail: edmundas.pupelis@ktu.lt
Table 1

Composition of powder mixtures and hardness of the layers
obtained in overlaying welding

           Composition of powder mixture, %

Glass   Cast iron   P6M5     SiC    Ti[O.sub.2]

100.0
70.0      30.0
60.0      30.0                         10.0
60.0      30.0
70.0      20.0              10.0
70.0                30.0
70.0                20.0    10.0
70.0

          Composition of powder
                mixture, %
                                     Hardness,
Glass   TiC    Fe - 60% Cr   AMS1       HRC

                             100.0      14
100.0                                    7
70.0                                    19
60.0                                    23
60.0    10.0                            49
70.0                                    38
70.0                                    24
70.0                                    49
70.0              30.0                  32

Table 2

Chemical composition of the steel overlaying welded by powder
mixtures

Composition of powder
mixture, % 1               Elements amount in layer, mas, %

P6M5    SiC     Fe-70%Mn   C       Si      Mn      Cr

80.0    20.0               0.83    1.92    0.95    0.6
60.0    20.0    20.0       1.06    1.69    4.73    0.76

Composition of powder
mixture, % 1               Elements amount in layer, mas, %

P6M5    SiC     Fe-70%Mn   Mo      V       W       Fe

80.0    20.0               0.71    0.28    0.75    Balance
60.0    20.0    20.0       0.88    0.36    1.10    Balance
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Author:Ambroza, P.; Kavaliauskiene, L.; Pupelis, E.
Publication:Mechanika
Article Type:Report
Geographic Code:4EXLT
Date:Mar 1, 2010
Words:2438
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