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Ability of transparent coatings to retard leaching of borates in a Weather-Ometer[R] test.

INTRODUCTION

Engineered wood composites such as glulam and LVL are increasingly used in conditions with moderate decay hazard such as indoor swimming pools and ice arenas, supporting building overhangs and sometimes projecting beyond the roof-line. Under these conditions, pressure treatment with heavy-duty wood preservatives either prior to or post lamination may be overkill, but untreated wood may fail prematurely. Glulam and LVL made from Canadian wood species do not respond well to treatment with water-borne preservatives, gaining limited penetration and dimensional instability. Both of these materials are typically used for aesthetic as well as structural reasons and a natural wood color may be desired. Borates are the only class of preservatives that are colorless and capable of deep penetration in most Canadian species. However, they are susceptible to leaching when continuously exposed to rainfall unless protected by a well-maintained three-coat paint finish. (1) Since glulam and, to a lesser extent, LVL, are used in part for their visual appeal, a transparent coating would be preferred.

[ILLUSTRATION OMITTED]

Orsler and Holland (2) showed substantial redistribution of boron away from unsealed butt joints in painted hyphen units over two years and recommended the long-term significance be investigated. They did not find any difference in boron redistribution between an oil-alkyd and a waterborne acrylic but the similar moisture contents in the test units suggest these coatings did not differ much in permeability. Morris (3) found similar redistribution in L-joints treated to 0.2% BAE after five years but this did not result in premature decay after 10 years. Hedley and Page (4) demonstrated good performance from painted boron-treated L-joints after 35 years exposure with no maintenance. Peylo and Willeitner (5) found 16% loss from test units with a thin coat of transparent varnish exposed outdoors for three years. All these test units were fully exposed to rain and, in the case of the L-joints, canted to ensure moisture accumulation at the joint. Wood components on the exterior of buildings normally have some protection by design and are free-draining. Under real service conditions, Dickinson and Murphy (6) found sufficient borate loading in windows after 23 years exposure to prevent decay, despite considerable paint deterioration.

The general purpose of this project is to develop decay-resistant glulam and LVL using combined borate treatment and effective transparent coating systems. In order to choose the coating with potentially the best performance on borate-treated composites and potentially the highest capability of preventing borate leaching during outdoor weathering, 15 types of commercial transparent coatings were selected and tested on borate-treated solid wood samples. An accelerated artificial weathering test with a Weather-Ometer[R] was used to determine the type of coating to be used for the bigger-scale composites test, based on the coating performance and the borate remaining after this weathering test. Although the treatment and coating combination is ultimately intended for use on composites made from primarily heartwood of a variety of species, ponderosa pine sapwood was selected for this experiment for its uniform and predictable behavior in terms of coating performance and borate leaching.

MATERIALS AND METHODS

Kiln-dried ponderosa pine sapwood samples were processed to the dimensions of 335 mm x 65 mm x 10 mm. These were double-length coupons plus a 10 mm central section for analysis prior to exposure. They were pressure-treated with disodium octaborate tetrahydrate (DOT) solution to a borate uptake around 2% boric acid equivalent (BAE) in wood. Based on the water exclusion and vapor permeability tested by UBC, (7) 15 types of commercial transparent coatings (Table 1) were selected as the candidates for the test, as well as a water-based paint as a reference. The coatings were applied on the air-dry borate-treated samples according to manufacturers' recommendations, with replicates of six for each coating. Before the Weather-Ometer test, a 10 mm sample was cut from the center of each sample, generating two groups of coupons: Group A and Group B (each coupon with the length of 16 cm). The cut ends of these coupons were then sealed with three coats of a two-part epoxy resin.

The accelerated weathering was done using an Atlas Weather-Ometer (model Ci65A) equipped with a 6500-watt, Xenon arc UV lamp and borosilicate inner and outer filters. This light source irradiated samples with near equal sunlight exposure with lower UV wavelength cut-off at about 290 nanometers. Two exposure conditions were used for evaluating the coating performance and borate remaining, one with UV and intensive water spray, the other with intensive water spray only, both for 1000 hr. Since the weathering test with the latter condition is not finished yet and the results are to be reported next quarter, this report only covers results tested under UV and intensive water spray. This weathering program consists of four phases (Figure 1): in each two-hour cycle, there is light with water spray in the first 30 min, no light and no water spray in the second 30 min, no light with water spray in the third 30 min, and light and no water spray in the last 30 min. The coating to be used on LVL and glulam samples is to be based on the results from this more severe weathering test. Five coupons from each coating group were used, with one coupon kept as the reference sample for visual assessment of weathering.

After the weathering test, the coating performance was visually assessed based on a rating system adopted from the Forest Products Laboratory (FPL) that inspects for discoloration, mold/stain, finish water repellency, flaking, erosion and cracking, and substrate condition (Table 2). Each evaluation was rated on a scale from 1 (complete failure) to 10 (perfect), and the overall general rating was assigned as the average rating of the evaluation group. After the coating evaluation, another 10 mm sample was cut from the center of each coupon. Both of the 10 mm samples, before and after the weathering test, were ground and analyzed for borate retention using the mannitol titration method, (8) and the percentage of borate remaining for each coating was calculated.

RESULTS AND DISCUSSION

There was a considerable range of coating performance (Table 3). After 1000 hr of artificial weathering with the combined UV and water spray, the rating of the uncoated samples dropped to 1. Unsurprisingly, the paint had the highest rating, with almost no visible deterioration after the test. Closely following the paint were coating B and coating F (coating E over pretreatment with a Forintek formula) with general ratings of 9. The relative lower rating of coating E alone suggests there was a positive effect of the pretreatment. Coatings G, H, J, L, and M had general ratings of 8. Some coatings had very low ratings after the test, which suggests they may not perform well in service.

The borate analysis shows a considerable range in ability to retain borate among these coatings with intensive water spray and combined UV (Table 4). The two water-based varnishes seemed most capable of preventing borate from leaching, and the one over pretreatment with a Forintek formula was superior. Closely followed were coatings B, O, and P. Coatings G, H, J, L, and M, which performed reasonably well in terms of UV resistance, were also in the middle of the pack in terms of retarding borate leaching. In terms of product characteristics, these coatings had virtually nothing in common which each other. Surprisingly, the painted samples (coating A) lost more than half the borate during the weathering test, which seemed contradictory with its perfect coating performance. Some coatings, such as D, K, I, N, and C, seem much less capable of retarding the chemical leaching, as little borate remained in wood after the weathering test. With the exception of C, these were typically stain-type products designed not to form a film. The borate remaining in samples is presumably associated with the moisture excluding efficiency of the coating, but it also depends on other factors, particularly UV resistance. The deterioration of coating certainly accelerates the chemical leaching from wood. In parallel field tests (unpublished), the water-based varnish with and without pre-treatment has not shown as good performance as coating B, particularly in terms of resistance to black stain fungi and ability to dry out after wetting. Consequently, it was decided to use Coating B on LVL and glulam samples for a long-term outdoor exposure test.

CONCLUSIONS

Coating B was the best in terms of the weathering resistance and borate retention. This product is being tested on borate-treated LVL and glulam samples for long-term outdoor weathering exposure.

References

(1) Lloyd, J.D., "Leaching of Boron Wood Preservatives--A Reappraisal," Proc. Brit. Wood Presrving and Damproofing Association, 52-58, 1995.

(2) Orsler, R.J. and Holland, G.E., "The Rate and Redistribution and Loss of Leachable Preservatives Under Service Conditions," Int. Res. Group on Wood Preservation, Document No. IRG/WP/93-30026, 1993.

(3) Morris, P.I., "Ten Year Performance of L-Joints Made from Borate Diffusion Treated Wood," Int. Res. Group on Wood Preservation, Paper: 9p, Document No. IRG/WP/00-30225, 2000.

(4) Hedley, M. and Page, D., "Performance of Boron-Treated Radiata Pine in Above Ground Field Tests in New Zealand," Int. Res. Group on Wood Preservation, Document No. IRG/WP/06-30406, 2006.

(5) Peylo, A., and H. Willeitner, five years leaching of Boron. Internat. Res. Group on Wood Preservation Document No. IRG/WP/99-30195, 6 p, 1999.

(6) Dickinson, D.J. and R.J. Murphy, R.J., "The Long-Term Performance of Boron Treated Joinery in Service--A Case Study," Int. Res. Group on Wood Preservation, Document No. IRG/WP/00-20208, 2000.

(7) Evans, P., personal communication, 2006.

(8) Winters, F.T., "Determination of Borates in Wood--A Simplified Analysis for Plant Operations," Unpublished bulletin, United States Borax and Chemical Corp., Los Angeles CA., ca. 1965.

by P.J. Morris, J. Wang, and J.K. Ingram

FPInnovations, Forintek Div.*

Presented at the FSCT Advancement in Coatings Series, "Coatings Wood and Wood Composites: Designing for Durability," July 23-25, Seattle, WA.

*2665 East Mall, Vancouver, BC V6T 1W5, Canada.
Table 1 -- Coatings Used on Borate-Treated Wood Coupons

Product Description Coats

A Water-based paint 1 acrylic primer; 2
 acrylic topcoat (a)
B Water-based two-part two-step film 2 coats step one; 1 coat
 step two
C Water-based polyurethane/acrylic film 3 coats
D Oil-based log home stain 2 coats
E Water-based polyurethane varnish 3 coats
F Water-based polyurethane varnish + 3 coats
 pretreatment
G Liquid plastic 1 coat
H Oil-based well known two-step 1 coat step 1; 2 coats
 transparent film step 2
I Oil based deck stain 1 coat
J Water-based film designed to seal in 2 coats
 borates
K Water-based two-step siding stain 2 coats step 1; 1 coat
 step 2
L Water-based acrylic siding stain 2 coats
M Water-based clear acrylic film 3 coats
N Oil-based siding stain 1 coat
O Water-based polyurethane film 2 coats
P Water-based clear two-step 2 coats step 1; 1 coat
 polyurethane film step 2
 None (Reference)

(a) As used in previous coating test over borate-treated wood

Figure 1 -- Weather-Ometer cycle.

30 minutes light with water spray -- 38[degrees]C, 65% RH
30 minutes no light and no water spray -- 38 to 30[degrees]C, 60% RH
30 minutes no light with water spray -- 30 to 28[degrees]C, 80+% RH
30 minutes light and no water spray -- 28 to 43[degrees]C, 80 to 25% RH

Table 2 -- Coating Evaluation Methods

Evaluation Method and Standard

Substrate condition Subjective visual assessment
Water repellency Subjective visual assessment
Discoloration Subjective visual assessment similar to ASTM D
 3274-82
UV surface breakdown Subjective visual assessment
Flaking ASTM D 772-86
Erosion ASTM D 662-93
Cracking ASTM D 661-93
General rating Overall appearance

Table 3 -- General Coating Performance after the Weather-Ometer Test

 Observation
 Surface
 Water UV Surface
Coatings Substrate Repellency Discoloration

 A 10 9 10
 B 10 10 9
 F 10 10 9
 G 10 9 8
 H 10 10 8
 J 10 10 8
 L 9 10 8
 M 10 10 8
 E 10 9 7
 D 9 7 7
 K 10 10 7
 C 9 8 7
 O 10 9 5
 I 8 10 5
 P 10 10 5
 N 9 2 3
Control 8 1 1

 Observation
 General
 Finish Coating
Coatings Breakdown Flaking Erosion Cracking Performance

 A 9 9 10
 B 9 10 9
 F 8 10 10 9
 G 8 10 10 8
 H 8 10 10 8
 J 8 10 10 8
 L 8 10 8
 M 8 10 10 8
 E 8 10 10 7
 D 7 7 7
 K 8 8 7
 C 7 7 7
 O 5 10 8 5
 I 5 5 5
 P 8 10 10 5
 N 3 2 3
Control 1 1

Table 4 -- Borate Remaining after the Weather-Ometer Test

 Borate Remaining (BAE, %)
 Standard
Coating Description Mean Deviation

F Water-based polyurethane 95 2.9
 varnish + pretreatment
E Water-based polyurethane 89 7.3
 varnish
B Water-based two-part 86 5.8
 two-step film
P Water-based clear two- 85 6.7
 step polyurethane film
O Water-based polyurethane 85 7.5
 film
J Water-based film 81 6.6
 designed to seal in
 borates
H Oil-based well known 78 4.0
 two-step transparent
 film
G Liquid plastic 78 11.2
M Water-based clear 75 14.1
 acrylic film
L Water-based acrylic 50 7.2
 siding stain
A Water-based paint 42 8.8
D Oil-based log home stain 33 11.5
K Water-based two-step 33 16.6
 siding stain
I Oil-based deck stain 26 11.7
N Oil-based siding stain 10 6.1
C Water-based 8 11.2
 polyurethane/acrylic
 film
Control [less than or equal to] 5%
COPYRIGHT 2008 Federation of Societies for Coatings Technology
No portion of this article can be reproduced without the express written permission from the copyright holder.
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Title Annotation:Technology Today
Author:Morris, P.J.; Wang, J.; Ingram, J.K.
Publication:JCT CoatingsTech
Date:Mar 1, 2008
Words:2251
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