A comparative study on properties of black soils derived from different parent materials.
In the present study, Hira black soil represents schists of Dharwarian formation, Bidar black soil represents basalts of Deccan trap formation and Shahabad soil represents the limestones of Bhima formation. All these soils have been selected from a broad summit of their respective landscapes. The black soils of Raichur district are said to have formed from granite-gneiss (Dasog and Hadimani, 1980), but there are no studies confirming this. On the other hand, they appear to have developed from schists of Dharwarian formation, which also occur in the district extensively, further, they also opined that the black soils of Northeastern Karnataka have also developed from basalts of Deccan trap and Limestones of Bhima formation, and, they studied on the different properties of these three black soils. Tamhane and Namjoshi (1959) compared the black soils formed from different parent rocks, but under similar climatic conditions. They opined that not much variation was observed in physical, chemical and mineralogical properties of the soil, but the content of silica, iron and alumina varied in the soil clays. The soils formed from granite gneiss and limestone parent rock revealed high percentage of silica compared to other parental-rock soils. Further, they observed that basic rocks favour the development of black soils compared to other rocks.
With the above background the present study was conducted with the objectives: to bring out differences in some properties of these black soils derived from different parent materials, and, to differentiate these black soils in respect of its clay properties.
MATERIALS AND METHODS
The soil pH determined potentiometric determination, EC, organic carbon (OC) determined by Walky and Black method (1934), free lime content were determined by C. S. Piper (1966) method
The Cation Exchange Capacity (CEC) of the soil was determined as per NBSS and LUP Staff (1984) and exchangeable cations were extracted and determined as prescribed by Jackson (1967).
The Coefficient of linear extensibility ([COLE.sub.rod]) was determined on fine earth (<2 mm) samples using the method of Schafer and Singer (1976) and calculated from the equation
[COLE.sub.rod] = (Lm - Ld)/ Ld
Lm is moist length
Ld is dry length of the rod.
Citrate-bicarbonate-dithionate (CBD) dissolutionfree iron, aluminium and silicon oxides and boiling [Na.sub.2]C[O.sub.3] soluble silicon and aluminium oxides were determined according to Jackson, M.L.(1979).
The soil clays were separated from the soil by following the procedure detailed by Jackson, M. L. (1979). The calcium exchange capacity (CaEC) and potassium exchange capacity (K/EC) after K-fixation of the clay fractions were determined as per Jackson, M.L. (1979). The coagulation threshold for soil clays (van Olphen, 1977) and specific surface area of soil clays (Santamarina et al., 2002) were also determined.
RESULTS AND DISCUSSION
Morphologicall characteristics of soil profiles in the study area is depicted in table 1. All selected soils are deep, basalt derived Bidar soil is moderately deep and the schist derived Hira and the limestone derived Shahabad soils are deep. The black soils, in general have very little horizon differentiation as reported by Roy and Barde (1962).The soil structure is sub-angular blocky in the surface horizons and angular blocky in the subsurface horizons of these black soils. The coarse rock fragments were not observed in any of these black soils. A few to common ferro-manganous nodules were found in very fine to medium size in the basalt derived Bidar soil and the schist derived Hira soil, but the nodules were absent in the limestone derived Shahabad soil, calcium carbonate nodules were also observed in these black soils (Dasog and Hadimani, 1980), and further the calcium carbonate nodules in the Bss horizon of basalt derived Bidar soil had fero-manganous coatings.The pressure faces were found in the A2 horizons of the basalt derived Bidar soil and the schist derived Hira soil profiles but they were absent in the limestone derived Shahabad soil. The prominent intersecting slickensides were observed in Bss horizon of the basalt derived Bidar soil, but only non-intersecting slickensides were found in both schist derived Hira soil and limestone derived Shahabad soil. The schist derived Hira soil was calcareous in nature, whereas, Bidar and Shahabad soils were non-calcareous in nature. Even though the Shahabad soil is derived from thelimestone, the soil is not calcareous but many limestone derived soils reported in the literature are calcareous in nature (Dasog and Hadimani, 1980; Khresat and Taimeh, 1998).
Different soil properties of the profiles are depicted in the table 2. Texture of all the three black soils are clay with high clay content followed by silt and sand. The sand content is very less. Generally black soils have less sand (Asio et al., 2006).The basalt derived Bidar soil showed higher magnitude of swelling and shrinkage as indicated by high COLE value (0.33) than the limestone derived Shahabad soil and schist derived Hira soil. The pH of the schist derived Hira soil and the basalt derived Bidar soil are neutral whereas the limestone derived Shahabad soil is alkaline, which is related to a relatively higher exchangeable sodium in this soil (Khresat and Taimeh, 1998, Asio et al, 2006). The salt content of all three black soils is less, indicated by very low EC values. The organic carbon content was low in all the three soils. The calcium carbonate content as determined by rapid reaction with HCl is high in schist derived Hirasoil where as that of limestone derived Shahabad soil and basalt derived Bidar soil is insignificant.
Free iron oxide, silica and alumina content in the soil of the profiles in the study is depicted in table 3, the CBD dissolved free iron and alumina and the boiling sodium-carbonate-soluble silica and alumina content are more in the limestone derived Shahabad soil (1.28 % [Fe.sub.2][O.sub.3], 0.43% [Al.sub.2][O.sub.3]; 1.9 % Si[O.sub.2], 0.57 % [Al.sub.2][O.sub.3] respectively) than the schist derived Hira and the basalt derived Bidar soils, similar results were obtained by other researchers. But when their molar ratios are calculated, the CBD dissolved iron to alumina ratio is high in the schist derived Hira soil (2.4) whereas boiling sodium-carbonate-soluble silica to alumina molar ratiois high in the basalt derived Bidar soil. Considering the total silica and total alumina from both the dissolutions, their molar ratio is high in the basalt derived Bidar soil (5.5) than the schist derived Hira soil (4.8) and the limestone derived Shahabad soil (3.4). Exchange properties of soil and clays in the whole and selected horizons of the profile is given in table 4. All three soils had higher CEC the exchangeable calcium and magnesium are the dominant exchangeable cations in these black soils. The exchangeable calcium is high in the basalt derived Bidar soil (55.8cmol ([p.sup.+]) [kg.sup.-1]) than the schist derived Hira (48.3cmol ([p.sup.+]) [kg.sup.-1]) and the limestone derived Shahabad soils (29.7cmol ([p.sup.+]) [kg.sup.-1]). Whereas the exchangeable magnesium is high in the limestone derived Shahabad soil than (45.5cmol ([p.sup.+]) [kg.sup.-1]) the schist derived Hira (34.2cmol ([p.sup.+])[kg.sup.-1]) and the basalt derived Bidar (26.7cmol ([p.sup.+])[kg.sup.-1]) soils. The exchangeable sodium and potassium are very low in these soils. However the limestone derived Shahabad soil had higher exchangeable sodium (7.2cmol ([p.sup.+])[kg.sup.-1]) than the schist derived Hira soil (0.5cmol ([p.sup.+])[kg.sup.-1]) and the basalt derived Bidar soil (0.5cmol ([p.sup.+])[kg.sup.-1]). And further the content of exchangeable sodium increased with depth as also found by Dasog and Hadimani (1980), Khresat and Taimeh (1998).
When the ratios of exchangeable cations were calculated, the ratio of divalent cations to monowalent cations is higher in the schist derived Hira soil than the basalt derived Bidar soil and is lowest in the limestone derived Shahabad soil (Table 4). Indicating that relatively higher proportion of mono'valent cation are present in the limestone derived Shahabad soil than the Bidar and the Hira soils. And when the ratio of calcium to magnesium is calculated, the ratio is comparatively higher in the basalt derived Bidar soil than the schist derived Hira soil. Both these soils have calcium dominant exchange complex. Contrastingly, the limestone derived Shahabad soil has magnesium dominant exchange complex.
Other clay properties of selected horizons of the profiles in the study are in depicted in table 4, the specific surface area of soil clays in the three different soils is in the range of 300-400[m.sup.2]/g and there is no significant difference among the three soils. The critical coagulation concentration (c.c.c) of the three black soil clays is in the range of 18 to 22 mmol/dm3and showen no significant difference among the three soils. However, considering the magnitude of c.c.c., the schist derived Hira soil clays have less c.c.c than that of the basalt derived Bidar soil clays and the limestone derived Shahabad soil clays. The charge of soil clays is obtained from calcium exchange capacity (CaEC). From the table 4, it is seen that these soils have the clay charge in the range of 87'92 cmol ([p.sup.+])[kg.sup.-1] of clay. Comparing the charge of soil clays of these three black soils, the CaEC of the schist derived Hira soil clays is relatively less than those of Bidar and Shahabad soil calys, similar results were found by Krale, et al. (1969), but the CEC of clays calculated from soil CEC is higher in Hira and Shahabad soil clays than in the basalt derived Bidar soil clays. Whereas, the clays of these three black soils fix K at high temperatures generally. The magnitude of K-fixed always increased with depth (Table 4). The K/EC after Kfixation was relatively more in the schist derived Hira soil clays than the basalt derived Bidar soil clays and the limestone derived Shahabad soil clays. This indicates that, these soils have smectitic mineralogy with significant amounts of vermiculite. The vermiculite content is estimated in this study by the magnitude of K-fixation as per Jackson (1966). The calculated vermiculite content in these soil clays is in the range of 7'23 per cent of soil clays. The basalt derived Bidar soil clays and the limestone derived Shahabad soil clays had higher vermiculite content than the schist derived Hira soil clays.
All the three soils derived from three different parent materials showed that the soils are rich in clay content which can be confirmed by pressure faces and non' intersecting slickensides in subsurface horizon, which yield in high CEC in all three soils. Apart from soil reaction (pH), all three soils are not significantly differentiated, but, there are variations and differences in respect of exchangeable sodium percent, calcium-magnesium ratio, divalent to monovalent ratio, vermiculite content and charges on clays.
(1.) Asio, V.b., Carlito C. Cabunosjr And Zuengsang Chen, Morphology, physicochemical characteristics and fertility of soils from quaternary limestone in Leyte, Philippines. Soil Sci., 2006; 171: 648-661.
(2.) Dasog, G.s. And Hadimani, Genesis and chemical properties of some vertisols. J. Indian Soc. Soil Sci., 1980; 28(1):49'56.
(3.) Jackson, M.L. 1966, Soil Chemical Analysis, Prentice Hall of India Private Limited, New Delhi.
(4.) Jackson, M.L. 1979, Soil Chemical Analysis-Advanced Course, 2nd Edition, 11th printing, Madison, Wis. 53705
(5.) Karale, R. L., Tamhane, R. V and Das, S. C., Soil genesis as related to parent material and climate. Physical and physic-chemical properties. J. Indian Soc. Soil Sci., 1969; 17: 227-229.
(6.) Khresat, Sa'eb A. and Taimeh, A.Y, Properties and characterization of verisols developed on limestone in a semi-arid environment. J. Arid Environments, 1998; 40: 235-244.
(7.) NBSS and Lup Staff., Soil Resource Mapping of Different States in India (Laboratory methods), NBSS and LUP Publications, Nagpur, India 1987.
(8.) Piper, C.S., Soil and Plant Analysis. Hans Publisher, Bombay 1966.
(9.) Santamarina, J.C., Klein, K.A., Wang, YH. and Prencke, E., Specific surface: determination and relevance. Can. Geotech. J., 2002; 39: 233-241.
(10.) Schafer, W.M., Singer, M.J., A new method of measuring shrink-swell potential using soil pastes. Soil Sci. Soc. Am. J. 1976; 40, 805-806.
(11.) Van Olphen, H., An Introduction to Clay Colloidal Chemistry. J Weley and sons, New York, 1977; pp: 22-23.
(12.) Walkey, A. and Black, C.A., An examination of digestion methods for determining soil organic matter and a proposed modifications of the chromic acid titration method. Soil Sci., 1934; 37: 29-38.
T.M. Shruthi , S.L. Budihal , Sidharam Patil , C.P. Sankalpa  and Eresha 
 Department of Soil Science and Agricultural Chemistry, College of Agriculture, University of Agricultural Sci, Raichur--584 104, India.
 Department of Soil Science and Agricultural Chemistry, College of Agriculture, University of Agricultural Sci, GKVK, Bangalore--560 065, India.
(Received: 25 December 2015; accepted: 06 February 2016)
* To whom all correspondence should be addressed.
Table 1. Morphological features of the selected pedons. Horizon Depth Colour Texture# Structure * (cm) (Munsel) Hira soil profile (Schist derived) Ap 0-20 10YR3/2 c 2 c sbk A2 20-35 10YR3/1 c 2m sbk A3 35-60 10YR3/2 c 2c abk A4 60-75 10YR3/1 c 3m abk Bidar soil profile (Basalt derived) Ap 0-24 10YR3/1 c 3f gr A2 24-47 10YR2/1 c 3f sbk Bss 47-94 10YR1/1 c 3m abk Cr/B 94-135 Shahabad soil profile (Limestone derived) Ap 0-22 10YR3/2 c 2f sbk A2 22-38 10YR2/1 c 2m sbk A3 38-58 10YR3/1 c 3c abk A4 58-120 10YR2/1 c 3c abk Horizon Reaction Salient features with dil.HCl# Hira soil profile (Schist derived) Ap e A2 e Pressure faces on ped surface A3 e Non-interesting slicken slides A4 e Non-interesting slicken slides Bidar soil profile (Basalt derived) Ap - A2 - Pressure faces on ped surface Bss - Slickensides on ped surface Cr/B Bed rock Shahabad soil profile (Limestone derived) Ap - A2 - A3 - Non-interesting slicken slides A4 - Non-interesting slicken slides # c: clay; e: effervesence * 2: moderate; 3: strong; f: fine; m: medium; c: coarse; gr: granular; sbk: sub-angular blocky; abk: angular blocky. Table 2. Soil properties. Horizon Depth Sand Silt (cm) (2-0.02 mm) (0.02-0.002mm) Hira soil profile (Schist derived) Ap 0-20 18 16 A2 20-35 19 15 A3 35-60 19 15 Bidar soil profile (Basalt derived) Ap 0-24 7 16 A2 24-47 8 16 Bss 47-94 6 16 Shahabad soil profile (Limestone derived) Ap 0-22 8 22 A2 22-38 4 25 A3 38-58 7 22 A4 58-120 4 24 Horizon Clay pH EC (<0.002 mm) (1:2.5) ([dSm.sup.-1]) Hira soil profile (Schist derived) Ap 66 7.5 0.16 A2 66 7.6 0.17 A3 66 7.5 0.18 Bidar soil profile (Basalt derived) Ap 77 7.3 0.16 A2 76 7.4 0.24 Bss 78 7.4 0.21 Shahabad soil profile (Limestone derived) Ap 70 7.5 0.16 A2 71 7.7 0.20 A3 71 8.0 0.28 A4 71 8.1 0.38 Horizon OC CaC[O.sub.3] COLE (%) (%) Hira soil profile (Schist derived) Ap 0.50 13 0.21 A2 0.32 14 0.26 A3 0.25 15 0.23 Bidar soil profile (Basalt derived) Ap 0.32 4 0.25 A2 0.34 6 0.29 Bss 0.18 7 0.33 Shahabad soil profile (Limestone derived) Ap 0.36 8 0.19 A2 0.22 5 0.29 A3 0.20 6 0.28 A4 0.14 3 0.30 Table 3. Free iron, aluminium and silicon oxide of the soils. CBD extract Horizon Depth [Fe.sub.2] [Al.sub.2] [Fe.sub.2] (cm) [O.sub.3] [O.sub.3] [O.sub.3] Hira soil profile (Schist derived) Ap 0-20 0.96 0.26 6.0 A2 20-35 1.08 0.34 6.75 A3 35-60 0.90 0.28 5.63 Bidar soil profile (Basalt derived) Ap 0-24 0.84 0.26 5.25 A2 24-47 0.70 0.28 4.38 Bss 47-94 1.02 0.34 6.38 Shahabad soil profile (Limestone derived) Ap 0-22 0.88 0.34 5.5 A2 22-38 0.88 0.38 5.5 A3 38-58 1.28 0.43 8.0 A4 58-120 1.11 0.42 6.94 CBD extract Boiling sodium carbonate extract Horizon [Al.sub.2] [Fe.sub.2] Si[O.sub.2] [Al.sub.2] [O.sub.3] [O.sub.3] [O.sub.3] /[Al.sub.2] [O.sub.3] Hira soil profile (Schist derived) Ap 2.55 2.4 1.28 0.19 A2 3.33 2.0 1.05 0.34 A3 2.75 2.0 0.90 0.28 Bidar soil profile (Basalt derived) Ap 2.55 2.1 1.28 0.26 A2 2.75 1.6 1.82 0.28 Bss 3.33 1.9 1.72 0.23 Shahabad soil profile (Limestone derived) Ap 3.33 1.7 1.37 0.34 A2 3.33 1.7 0.75 0.34 A3 4.22 1.9 1.00 0.40 A4 4.12 1.7 1.90 0.57 Boiling sodium carbonate extract Horizon Si[O.sub.2] [Al.sub.2] Si[O.sub.2] [O.sub.3] /[Al.sub.2] [O.sub.3] * Hira soil profile (Schist derived) Ap 21.33 1.86 4.8 A2 17.50 3.33 2.6 A3 15.00 2.75 2.7 Bidar soil profile (Basalt derived) Ap 21.33 2.55 4.2 A2 30.33 2.75 5.5 Bss 28.67 2.25 5.1 Shahabad soil profile (Limestone derived) Ap 22.83 3.33 3.4 A2 12.50 3.33 1.9 A3 16.67 3.92 2.0 A4 31.67 5.59 3.3 * Calculated from total silica and alumina, extracted by CBD and boiling carbonate treatments. Table 4. Exchange properties of whole soils and clay properties of selected horizons. Exchangeable bases (pH 7.0) Horizon Depth CEC Ca Mg K Na Sum (cm) (pH 8.2) Hira soil profile (Schist derived) Ap 0-20 85.4 29.2 34.2 0.6 0.4 64.4 A2 20-35 87.7 35.8 21.0 0.6 0.4 57.7 A3 35-60 83.3 48.3 17.8 0.5 0.5 67.2 Bidar soil profile (Basalt derived) Ap 0-24 91.5 55.8 22.2 1.1 0.5 79.6 A2 24-47 86.0 44.8 25.6 0.8 0.4 71.6 Bss 47-94 72.2 34.5 26.7 0.7 0.4 62.3 Shahabad soil profile (Limestone derived) Ap 0-22 90.7 29.7 20.4 0.7 0.9 51.7 A2 22-38 96.7 22.6 29.4 0.6 2.3 54.8 A3 38-58 95.1 21.2 45.5 0.6 4.0 71.3 A4 58-120 96.8 19.8 37.5 0.6 7.2 65.0 (Ca+Mg)/ Ca CaEC K/EC Horizon (K+Na) / Mg (%) (%) cmol ([p.sup.+]) [kg.sup.-1] Hira soil profile (Schist derived) Ap 63 0.9 A2 59 1.7 87.3 76.9 A3 61 2.7 89.4 69.1 Bidar soil profile (Basalt derived) Ap 49 2.5 A2 59 1.8 91.9 61.1 Bss 56 1.3 92.1 58.0 Shahabad soil profile (Limestone derived) Ap 31 1.5 A2 18 0.8 89.4 62.7 A3 14 0.5 91.2 58.3 A4 7 0.5 91.6 56.4 Vermi- c.c.c SSA Horizon culite (mmol ([m.sup.2]/g) (%) /[dm.sup.3]) Hira soil profile (Schist derived) Ap A2 7 19 416 A3 13 18 367 Bidar soil profile (Basalt derived) Ap A2 20 22 367 Bss 22 19 367 Shahabad soil profile (Limestone derived) Ap A2 17 20 367 A3 21 19 305 A4 23 19 367 c.c.c: Critical coagulation concentration SSA: Specific Surface Area
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|Author:||Shruthi, T.M.; Budihal, S.L.; Patil, Sidharam; Sankalpa, C.P.; Eresha|
|Publication:||Journal of Pure and Applied Microbiology|
|Date:||Jun 1, 2016|
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