When thermosets were king.* Thermosets thermosets, materials that can not be softened on heating. In thermosetting polymers, the polymer chains are joined (or cross-linked) by intermolecular bonding. Thermosets are usually supplied as partially polymerized or as monomer-polymer mixtures. have been on my mind lately. I have been perusing 1955 issues of Plastics Technology for our 50th anniversary columns (see p. 11). Back then, thermosets were close to half the 2.6 billion lb of plastics resins used in the U.S. The only plastics whose production and sales volumes were large enough for the U.S. government to count individually were urea, melamine melamine (mĕl`əmēn'), common name for 2,4,6-triamino-1,3,5-triazine. Melamine is a trimer (see polymer) of cyanamide, H2NC≡N, and is synthesized from calcium carbide. , phenolic phe·no·lic adj. Of, relating to, containing, or derived from phenol. n. Any of various synthetic thermosetting resins, obtained by the reaction of phenols with simple aldehydes and used as adhesives. , unsaturated polyester, PVC PVC: see polyvinyl chloride. PVC in full polyvinyl chloride Synthetic resin, an organic polymer made by treating vinyl chloride monomers with a peroxide. , polystyrene, and polyethylene. In those days, if you wanted a plastic for really tough jobs, you chose a thermoset A polymer-based liquid or powder that becomes solid when heated, placed under pressure, treated with a chemical or via radiation. The curing process creates a chemical bond that, unlike a thermoplastic, prevents the material from being remelted. See thermoplastic. . Today, thermosets account for less than 11% of the 91 billion lb of plastics processed in North America. They are still among the most heat- and abuse-resistant plastics around, and among the most economical. But longer cycle times, greater difficulty recycling, higher labor costs, and environmental considerations have eroded their appeal relative to thermoplastics. Thermosets' shrinking role has mirrored the contracting roster of thermoset materials suppliers. In the past month, eight of those suppliers suddenly became three (see p. 76). In one gulp, Borden Chemical absorbed Bakelite AG of Germany along with Resolution Performance Products (formerly Shell's epoxy business) and Resolution Specialty Materials (formerly part of Eastman Chemical and before that, McWhorter Technologies). Simultaneously, Sumitomo Bakelite of Japan (which had earlier acquired Durez, the biggest U.S. name in phenolics) gobbled up Vyncolit of Belgium, which not so long ago bought Rogers Corp. Then Bulk Molding Compounds Inc. took over Rodgers Engineering. Don't cry for thermosets. They still account for almost 10 billion lb/yr of U.S. plastics, and they had healthy growth of around 5% last year. Thermosetting thermosetting, adj having the property of becoming irreversibly rigid or hardened with the application of heat. In dentistry the term is used in connection with resins. composites still have new fields to conquer in aerospace, automotive, and infrastructure. They'll probably be going strong when this magazine celebrates 100 years. |
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