Wet end starch: its importance and measurement.Alkaline papermaking pa·per·mak·ing n. The process or craft of making paper. pa per·mak uses starch as one of several wet end specialty chemical A Specialty chemical is a chemical produced for a specialized use. They are produced in lower volume than bulk chemicals, of which petrochemicals, made from oil feedstocks, are the most common. However, both are produced in a chemical plant. additives. Starch has three critical purposes in the wet end: 1) dry strength enhancement, 2) internal size retention, and 3) first pass retention. Starch's importance to dry strength and size retention is generally accepted, but there is debate about its importance to first pass retention. This author's experience shows starch as a major contributor to first pass retention through charge neutralization neutralization, chemical reaction, according to the Arrhenius theory of acids and bases, in which a water solution of acid is mixed with a water solution of base to form a salt and water; this reaction is complete only if the resulting solution has neither acidic nor , through polymer flocculation flocculation /floc·cu·la·tion/ (flok?u-la´shun) a colloid phenomenon in which the disperse phase separates in discrete, usually visible, particles rather than congealing into a continuous mass, as in coagulation. , and as a component of micro particulate par·tic·u·lateadj. Of or occurring in the form of fine particles. n. A particulate substance. particulate composed of separate particles. retention systems. One problem that many mills face today is that they do not pay adequate attention to this important wet end additive. It is not made down consistently, not fed/metered with state of the art technology, and its effectiveness is rarely measured once added. Starch should not be exposed to high shear pumps, agitators and re-circulation loops in the make down and storage process. Starch should then be fed through low shear pumps with properly sized flow meters and adequate filtration. At a minimum, slurried and cooked starch solids, viscosity, and pH should be measured and controlled. Mills should run a simple in-mill starch residual test to measure its effectiveness. This test will quantitatively measure free (non-adsorbed) wet end starch, including starch from the broke. This free starch should be minimized since it can lead to biological activity, foam, deposits, poor specialty chemical efficiency, etc. This test leads to an understanding of where non-adsorbed starch is coming from and to a reduction in process variability and upsets.--Kasy King, TAPP TAPP Teacher Alternative Preparation Program TAPP Technical Assistance for Public Participation TAPP Thermochemical and Physical Properties TAPP transabdominal pre-peritoneal TAPP The Art of Positive Parenting 1 Editorial Board, email: kasyking@new.rr.com |
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