Printer Friendly
The Free Library
22,719,120 articles and books

Use of preimpregnated sisal yarn in woven reinforced polypropylene sheets: thermoformability and mechanical properties.


Cellulosic natural fibers are being incorporated into polymeric matrices to reduce cost and to improve mechanical properties. This trend is being driven mainly by government regulations on waste dumping that promote the use of renewable and recyclable materials. Natural sisal, jute, flax, hemp hemp, common name for a tall annual herb (Cannabis sativa) of the family Cannabinaceae, native to Asia but now widespread because of its formerly large-scale cultivation for the bast fiber (also called hemp) and for the drugs it yields. , aspen, coconut, or banana fibers cannot match the mechanical properties of synthetic glass, carbon, or Kevlar in high performance applications. However, there are applications for which the mechanical requirements exceed the properties of the unfilled plastics and in which the use of synthetic fiber Noun 1. synthetic fiber - fiber created from natural materials or by chemical processes
man-made fiber

fiber, fibre - a slender and greatly elongated substance capable of being spun into yarn

acrylic, acrylic fiber - polymerized from acrylonitrile
 is not a cost-efficient alternative; then thermoplastics reinforced with natural fibers become a cost-efficient option.

In previous work, we have studied the injection molding injection molding
A manufacturing process for forming objects, as of plastic or metal, by heating the molding material to a fluid state and injecting it into a mold.
 process for manufacturing composites made out of polypropylene (PP) and sisal fiber (SF), compatibilized with maleic anhydride Maleic anhydride (cis-butenedioic anhydride, toxilic anhydride, dihydro-2,5-dioxofuran) is an organic compound with the formula C4H2O3 (C=OCH=CHC=O2). In its pure state it is a colourless or white solid with an acrid odour.  grafted polypropylene (MA-g-PP), by using a thermoplastic A polymer material that turns to liquid when heated and becomes solid when cooled. There are more than 40 types of thermoplastics, including acrylic, polypropylene, polycarbonate and polyethylene.  impregnation impregnation /im·preg·na·tion/ (im?preg-na´shun)
1. fertilization.

2. saturation (1).


1. the act of fertilizing or rendering pregnant.

2. saturation.
 process to obtain a continuous SF/PP rod. Pellets containing long fibers (~13 mm), obtained by cutting the impregnated pultruded rods, were dry-blended with regular PP pellets at the injection machine hopper, and SF/PP composites with excellent mechanical properties were directly obtained by injection molding [1].

The automotive industry's interest in woven, natural fabric-reinforced thermoplastics (WNFRT) is increasing due to their excellent mechanical-specific properties and competitive raw materials cost. However, production costs may become high because of technological requirements; to obtain acceptable composites properties, good fibers impregnation and matrix-fiber adhesion are needed. Currently available processing technologies that render good fiber impregnation and matrix-fiber adhesion are still expensive. The high viscosity of molten polyolefins and the lack of interfacial adhesion between the nonpolar nonpolar

not having poles; not exhibiting dipole characteristics.
 polyolefins and the hydrophilic hydrophilic /hy·dro·phil·ic/ (-fil´ik) readily absorbing moisture; hygroscopic; having strongly polar groups that readily interact with water.

 sisal fiber surfaces cause poor fiber impregnation and weak interfacial adhesion. The high viscosity of PP is assumed to be responsible for poor penetration of the liquid PP into the fibers bundles, thus diminishing the SF/PP contact area. Much better fiber surface wetting is observed when MA-g-PP is added to the composite matrix [2]. This coupling agent supplies polar functional groups that increase the fiber-matrix adhesion by an esterification es·ter·i·fi·ca·tion
A chemical reaction resulting in the formation of at least one ester product.

es·teri·fied adj.
 reaction between cellulosic fiber hydroxyl hydroxyl /hy·drox·yl/ (hi-drok´sil) the univalent radical OH.

The univalent radical or group OH, a characteristic component of bases, certain acids, phenols, alcohols, carboxylic
 groups and the anhydride anhydride (ănhī`drīd, –drĭd) [Gr.,=without water], chemical compound formed by removing water, H2O, from another compound; the anhydride can also react with water to form the original compound.  functionality of MA-g-PP [2-9]. Besides, the MA-g-PP displays a much lower viscosity that improves the liquid matrix penetration into the fibers bundles. A major drawback for the use of MA-g-PP is its high cost, which may reach about four times the price of polyolefin matrix; therefore, every effort made to reduce the amount of MA-g-PP used in composites will significantly reduce the final cost.

In this work, a low-cost scheme is shown to produce a continuous sisal fiber fabric-polypropylene composite with excellent mechanical properties that may be thermoformed to an acceptable level. A single-screw extruder and a specially designed die were used to impregnate im·preg·nate
1. To make pregnant; to cause to conceive; inseminate.

2. To fertilize an ovum.

3. To fill throughout; saturate.
 a continuous SF yarn with a blend of a low-viscosity PP and MA-g-PP. The expectation is to achieve good SF yarn impregnation quality, improve the fiber bonding, and reduce the total mass fraction of expensive MA-g-PP in the final composite [1,10]. The yarn thus obtained was knitted to make impregnated SF fabrics, and compression-molded between two PP sheets to obtain a sheet of SF/PP-reinforced compound. Deep cups were thermoformed from the WNFRT sheets. Excellent quality cups were obtained for adequate thermoforming processing conditions. The fiber content of the composites was measured after polyolefin extraction in a high-temperature Soxhlet. The composite's mechanical properties were determined. Formability of the sheet-molded compound was studied by using a punch-and-ring system and a universal testing machine A Universal Testing Machine is used to test the tensile and compressive properties of materials. Such machines generally have two columns but single column types are also available. .



SF (Agave Sisalana Noun 1. Agave sisalana - Mexican or West Indian plant with large fleshy leaves yielding a stiff fiber used in e.g. rope

agave, American aloe, century plant - tropical American plants with basal rosettes of fibrous sword-shaped leaves and flowers in
) yarn with a fiber diameter of about 100-200 [micro]m was obtained from Brascorda Co. (Brazil). The fibers were used for this work as received, without any surface modification or chemical treatment. Under this condition, a single fiber has a tensile strength tensile strength

Ratio of the maximum load a material can support without fracture when being stretched to the original area of a cross section of the material. When stresses less than the tensile strength are removed, a material completely or partially returns to its
 of 628 MPa, and a tensile modulus of 16.142 GPa (ASTM ASTM
American Society for Testing and Materials

MA-g-PP (1.0 wt% MA) (Polybond 3200, produced by Crompton Europe) was used as a coupling agent.

Commercial PP (Cuyolen-1102KX) was supplied by Petroquimica Cuyo.

The organic peroxide used to lower the PP average molecular weight and melt viscosity was 2,5-di (tert-butylperoxy)-hexane, with [T.sub.1/2] = 4 minutes at 170[degrees]C, supplied by Akzo Nobel Quimica S.A.

Low Viscosity PP and Blended Pellet Preparation

The PP pellets (Cuyolen-1102KX) were impregnated with 9000 ppm of 2,5-di(tert-butylperoxy)-hexane. The peroxide was previously dissolved in enough hexane hexane /hex·ane/ (hek´san) a saturated hydrogen obtained by distillation from petroleum.

, which was later removed by evaporation.

The peroxide-impregnated PP was melted, mixed, extruded, cooled, and pelletized using a single-screw extruder at 180 & C and with a residence time of 1.5 minutes.

Melt modified PP (mPP) and MA-g-PP were mixed and pelletized to obtain a MA-g-PP/mPP blend containing 20 wt% of MA-g-PP.

Samples Preparation

Continuous sisal yarns were pulled through a melt impregnation die especially designed for this work. The extrusion die consists of a single rotating disk, powered by an external electric motor, rotating into a polymer melt pool. The action of the single powered disk impregnates the sisal yarn with molten polymer supplied by a single-screw extruder (21 mm diameter, L/D L/D Labor and Delivery
L/D Lethal Dose
L/D Lift/Drag (ratio)
L/D Low Dynamic
L/D Limiter/Discriminator
L/D Loading / Discharging Rate (shipping) 
 = 24) at low pressure (about 0.2-0.4 MPa). The low-pressure operation significantly reduces fiber breakage, and allows a fast yarn impregnation speed (between 10 and 20 m/min). A simple schematic of the process is shown in Fig. 1. The thermoplastic pultrusion Pultrusion is a continuous process of manufacturing of composite materials with constant cross-section whereby reinforcing fibers are pulled through a resin, possibly followed by a separate preforming system, and into a heated die, where the resin undergoes polymerization.  line was operated with an extruder mass flow of 0.55 Kg/h, the line speed of the sisal yarn was between 10 and 20 m/min, and the rotating speed of the disk was 250 rpm.

From the impregnation process, continuous SF yarns, impregnated either with mPP or with MA-g-PP/mPP blend, were obtained. These impregnated yarns were used to make a woven structure in the form of an orthotropic or·tho·trop·ic
Tending to grow or form along a vertical axis.

or·thotro·pism n.
, bidirectional The ability to move, transfer or transmit in both directions.  fabric. These fabrics were hot compression-molded between thin sheets of unmodified PP. Tensile specimens, flexural flexural

pertaining to the flexure of a joint.

flexural deformity
fixation of joints in flexion. In the newborn called contracted calves or foals.
 specimens, and circular specimens for thermoforming were cut and machined from the woven SF/PP composite sheet (W) and from the woven SF/PP/MA-g-PP composite sheet (W-MA). Tensile and flexural specimens were cut, always with fibers aligned parallel to the main stress direction.

A blend of 60 wt% of long SF and 40 wt% of PP, and a blend of 60 wt% of long SF, 35.75 wt% PP, and 4.25 wt% MA-g-PP were prepared in a Brabender mixer. The fibers were added to a PP melt at 180[degrees]C and blended at a rotor speed of 50 rpm for 10 min. The blends ware taken from the mixer while hot, and then compression molded. Tensile specimens, flexural specimens, and circular specimens were cut and machined from the nonwoven non·wo·ven  
Made by a process not involving weaving. Used of textiles.

Material or a fabric made by a process not involving weaving.
 SF/PP composite sheet (NW) and the nonwoven SF/PP/MA-g-PP composite sheet (NW-MA).

Fiber Content Measurement

The fiber content of the impregnated yarn and for the molded composite sheet were measured. The polyolefins were dissolved in a high-temperature Soxhlet extraction system, with boiling hot xylene xylene (zī`lēn) or dimethylbenzene (dī'mĕthəlbĕn`zēn), C6H4(CH3)2  acting for several hours. The fibers were then recovered by filtration, washed, dried, and weighted.


Characterization of the Interface Adhesion

Mechanical properties, infrared spectroscopy, and optical observation of hot compression-molded specimens were used to study the adhesion between fibers and the matrix.

Tensile and flexural specimens were cut from the hot compression-molded sheets. Stress-strain curves were calculated from the force-displacement graphs measured in an Instron 4467 Universal Mechanical Testing Machine. Tests were conducted under ASTM D 638 and ASTM 790 specifications.

Fourier transform infrared (FT-IR) spectra of SF before and after the three-step (extrusion-knitting-compression molding) process were measured with a Mattson FT-IR unit, Model Genesis II. The sisal fibers were recovered from the compression-molded sheets by dissolving the polymeric matrix in boiling hot toluene toluene (tōl`yēn') or methylbenzene (mĕth'əlbĕn`zēn), C7H8  for several hours. The absorbance absorbance /ab·sor·bance/ (-sor´bans)
1. in analytical chemistry, a measure of the light that a solution does not transmit compared to a pure solution. Symbol .

 IR spectra were recorded in the 2000-1500 [cm.sup.-1] range with a resolution of 2 [cm.sup.-1], with 100 scans for each spectrum. FT-IR has been also used by other authors to study the interfacial adhesion between natural fibers and MA-g-PP [5,9].

Scanning electron microscopy (SEM) was used to study the break surfaces after mechanical testing.

Thermoforming Capability Evaluation

An evaluation of the hot formability of the sheets was performed by stamping a cup on a circular blank. The apparatus consists of a two-half holder ring and a concentric punch mounted on an INSTRON 4467 testing machine (Fig. 2). A similar instrument has been used by Bhattacharyya et al. [11] for the same purpose.

Circular specimens cut from the compression molded sheets were placed between the holder ring halves. This assembly was then heated in an oven. Once the desired temperature was achieved, the assembly was taken from the oven and placed at the testing machine, centering the holder ring with the punch. The sheet material was forced through the die using the punch at a crosshead cross·head  
A beam that connects the piston rod to the connecting rod of a reciprocating engine.

Noun 1. crosshead - a heading of a subsection printed within the body of the text
 speed of 200 mm/min. The punch force and displacement were recorded, and the forming energy was calculated.


Fiber Content Determination

Results from high-temperature Soxhlet extraction indicate that the SF content for the yarn impregnated with molten polymer is 74.35 wt%. The MA-g-PP content corresponding to the extracted 25.65 wt% polymer is 5.13 wt%.

Table 1 shows the SF content obtained by Soxhlet extraction technique for all the composites used for this work. For NW-MA and W-MA, the MA-g-PP contents were calculated from the SF contents in the composites and the estimated MA-g-PP content in the impregnated sisal yarn. For NW and NW-MA, the lengths of the extracted fibers were measured and the average value obtained was 35.6 mm.

Tensile and Flexural Properties

Table 1 also shows the tensile and flexural properties for all the composites used for this work, and also for unfilled PP. The incorporation of 61 wt% of SF into the PP matrix increases the composite flexural modulus, tensile modulus, and the tensile strength. Large differences are observed between the woven and the nonwoven composites and between the SF/PP composites compatibilized with MA-g-PP and the SF/PP composites not compatibilized with MA-g-PP.


Figure 3 shows stress-strain data from three-point-bending tests for all the composites and the PP used for this work. At a first glance we can observe that for nonwoven and also for woven composites, the addition of 4.2% of MA-g-PP causes large increases in modulus and strength, and also restricts the maximum attainable strain before failure.

For the case of nonwoven composites without MA-g-PP, the incorporation of SF into the PP matrix increases the tensile modulus by 31%, increases the flexural modulus by 32%, and decreases the tensile strength by 44% compared with unfilled PP. When the coupling agent is not used, the mechanical properties are not improved, and the SF acts only as a filler to reduce raw material cost by about 80%, because the PP is approximately three times more expensive than SF. The addition of 4.20 wt% of MA-g-PP to the nonwoven composites increases the raw materials costs by about 75%, but compared with unfilled PP the tensile modulus increases by 137%, the flexural modulus increases by 160%, the tensile strength increases by 77%, and the raw material cost is still close to unfilled PP.

For the woven SF/PP composites, the incorporation of woven SF into the PP matrix increases the tensile modulus by 157%, increases the flexural modulus by 216%, and increases the tensile strength by 77% when compared with unfilled PP. The addition of 4.20 wt% of MA-g-PP to the woven composites also increases the cost of raw materials by about 75% but the tensile modulus increases by 477%, the flexural modulus increases by 600%, the tensile strength increases by 300%, and the raw material cost is still close to unfilled PP. The woven fabric orthogonal structure provides a much larger fraction of fibers aligned parallel to the testing direction.


For rigid component applications, the best improvement in mechanical properties is obtained for the case in which a woven SF, impregnated with a small quantity of MA-g-PP, is used. The use of SF well-impregnated with PP is also a very attractive, low-cost way to improve the mechanical properties of PP.

Interfacial Adhesion Characterization

Figure 4 shows the FT-IR spectra at the 2000-1500 [cm.sup.-1] region, for the SF before the extrusion impregnation process, and for the SF extracted from W-MA specimens. The characteristic peak at 1742 [cm.sup.-1] found for the SF extracted from W-MA corresponds to ester bonds. The esterification of the maleic anhydride groups of the MA-g-PP with the cellulosic hydroxyl groups is responsible for a better fiber/matrix adhesion, and allows a better stress transfer and distribution inside the composite. This is the reason for the improvements of the tensile and flexural properties for SF/PP composites when MA-g-PP is added.


Figure 5a and b shows SEM micrographs of rupture surfaces corresponding to tensile nonwoven composite specimens. Figure 5a corresponds to NW (without MA-g-PP). Figure 5b corresponds to NW-MA (with MA-g-PP). The SF surface shown in Fig. 5a has no bonded PP, and the fibers have been pulled out from the PP matrix without fiber rupture. The SF surface shown in Fig. 5b shows some PP still bonded after the specimen rupture; this image shows a strong interfacial adhesion that in some cases causes the SF breakage during tensile test.

Thermoforming Evaluation

Figure 6 shows the force-displacement curves for W-MA composites thermoformed at different blank-forming temperatures using the INSTRON machine and the apparatus shown in Fig. 2. For all the testing conditions used, the maximum forming force is achieved just before the punch starts forming the cylindrical zone of the cup -8 mm of crosshead displacement. At blank-forming temperatures above the matrix melting point, the W-MA composites sheets can be easily thermoformed with low stress, the punch shape is copied exactly, and good surface finish is obtained. At temperatures below the matrix melting point, forming requires much more stress and energy, the punch shape is not copied well, and the surface finish obtained is poor.



Figure 7 shows that PP sheets can be successfully thermoformed at temperatures above 140[degrees]C, and NW-MA and W-MA sheets can be successfully thermoformed at temperatures above 170[degrees]C. Below these temperature ranges the sheets break or cannot copy exactly the shape of the punch.

Unfilled PP can be thermoformed at 25[degrees]C below the PP peak melting temperature, because at that temperature the crystals can easily be sheared at low stress. Above the PP melting point, the unfilled PP sheets flow into the heating oven before the action of the forming punch. This way the forming temperature range can be defined as 140-160[degrees]C. From 100[degrees]C and up to 140[degrees]C, unfilled PP can be thermoformed with severe surface damage.


W-MA and NW-MA composites can be thermoformed only above 150[degrees]C, because the real deformation applied to the polymer matrix is much larger for the composites than for the unfilled PP. The SF network restricts the free flow of the hot polymer matrix, and the sheets can be heated and conformed at higher temperatures with much better surface finish.

Thermoformed cups walls are 6.65% thinner than the original unfilled PP flat sheet. The thinning for W-MA is 2%, and for NW-MA it is 2.6%. This is related to the fact that the SF network (woven or nonwoven) restricts the elongation suffered by the unfilled PP sheets during the thermoforming process. The thinning reduction prevents excessively thin and weak areas in the final parts, and this fact is considered a distinctive advantage for the proposed method.

Figure 8 shows the forming mechanical energy (FME FME Formal Methods Europe
FME Faculty of Mechanical Engineering (Brno University of Technology, Czech Republic)
FME Feature Manipulation Engine
FME Facultat de Matemàtiques I Estadística
) for PP, NW-MA, and W-MA sheets at different blank-forming temperatures. The FME is calculated from the force-displacement curves. At temperatures below the PP melting range melting range,
n See range, melting.
 the FME is high because much of this energy is used to deform the polymer matrix sheet. Increasing the blank-forming temperature, the FME diminishes exponentially due to the much lower yield stress of the polymer matrix sheet. Entering the PP melting range the FME falls dramatically, because the PP matrix becomes a liquid and can flow and easily copy the shape of the punch.


In this work a thermoplastic pultrusion system was designed and developed. Continuous SF yarns (75 wt%) were impregnated to obtain continuous thin rods with a melt blend of polypropylene (20 wt%) and MA-g-PP (5 wt%) at high-speed production. These impregnated yarns were knitted to obtain a woven structure in the form of an orthotropic, bidirectional fabric, and compression molded between thin sheets of unmodified PP to obtain woven sisal fabric-reinforced PP sheets. Due to the presence of the coupling agent and the bidirectional array of the fibers, the flexural modulus increases 600%, the tensile modulus increases 475%, and the tensile strength increases 300% compared with unfilled PP. The composite sheets were successfully thermoformed at a temperature between 150-190[degrees]C, by stamping a cup on a circular blank to obtain a 3D shape. Above the matrix melting range, the woven composites were thermoformed with very low forming energy and excellent surface finish.


The use of this nonconventional four-step process (impregnation-knitting-compression-molding-shaping) enables rapid automated production of 3D composite structures with excellent mechanical properties, excellent surface finish, short cycle time, and controlled raw material cost. The use of impregnated yarns followed by knitting and thermoforming (W-MA) results in products that show twice the Young's modulus and twice the tensile strength of similar composites in which the fibers are randomly oriented (NW-MA). The previous impregnation of the SF yarns allows excellent wetting of the fibers with excellent fiber/matrix adhesion, keeping the need for expensive MA-g-PP to a minimum. Knitting the previously impregnated yarns is necessary to obtain cheaper 3D thermoformed products with much better properties. The presence of the knitted reinforcement allows efficient thermoforming with very low wall-thickness reduction, thus improving the quality of the products.
TABLE 1. Measured properties for all composites.

Properties/composite     PP      NW      NW-MA   W       W-MA

Sisal fiber content (%)   0      61.0    60.9    60.4    61.2
MA-g-PP content (%)       0       0       4.20    0       4.22
Flexural modulus (GPa.)   1.140   1.504   2.956   3.611   7.968
  ASTM D 790
Tensile strength (MPa)   24.287  13.578  42.987  50.361  96.57
  ASTM D 638
Tensile modulus (GPa)     1.286   1.686   3.054   3.301   7.423
  ASTM D 638


We thank Dr. Jose Carella for useful discussions. C.J.P. thanks CONICET CONICET Consejo Nacional de Investigaciones Científicas Y Técnicas (National Council for Science and Technology, Argentina)  for a Post-Doctoral Scholarship.

Contract grant sponsor: Agencia Nacional de Promocion Cientifica y Tecnologia (ANPCYT); contract grant number: PICT 99-14-07247.


1. L.M. Arzondo, A. Vazquez, J.M. Carella, and J.M. Pastor, Polym. Eng. Sci., 44, 1766 (2004).

2. K.L. Fung, R.K.Y. Li, and S.C. Tjong, J. Appl. Polym. Sci., 85, 169 (2002).

3. R. Gauthier, C. Joly, A.C. Coupas, H. Gauthier, and M. Escoubes, Polym. Compos., 19, 287 (1998).

4. R. Karnani, M. Krishnan, and R. Narayan, Polym. Eng. Sci., 37, 476 (1997).

5. M. Kazayawoko, J.J. Balatinecz, and L.M. Matuana, J. Mater. Sci., 34, 6189 (1999).

6. X.L. Xie, R.K.Y. Li, S.C. Tjong, and Y.W. Mai, Polym. Compos., 23, 319 (2002).

7. K.L. Fung, R.K.Y. Li, and S.C. Tjong, J. Appl. Polym. Sci., 85, 169 (2002).

8. S. Mohanty, S.K. Verma, S.K. Nayak, and S.S. Tripathy, J. Appl. Polym. Sci., 94, 1336 (2004).

9. J.M. Felix and P. Gatenholm, J. Appl. Polym. Sci., 42, 609 (1991).

10. K.L. Fung, X.S. Xing, R.K.Y. Li, S.C. Tjong, and Y.-W. Mai, Compos. Sci. Technol., 63, 1255 (2003).

11. D. Bhattacharyya, M. Bowis, and K. Jayaraman, Compos. Sci. Technol., 63, 353 (2003).

L.M. Arzondo

Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA) (UNMdP-CONICET); Departamento de Ingenieria en Materiales, Facultad de Ingenieria, Universidad Nacional de Mar del Plata Mar del Plata (mär thĕl plä`tä), city (1991 pop. 519,707), E central Argentina, on the Atlantic Ocean. It is one of the most popular seaside resorts in South America. Fishing and fish processing are also important industries. , Juan B. Justo Juan Bautista Justo (born June 28 1865 in Buenos Aires - died on January 8, 1928 in Buenos Aires) was an Argentine physician, journalist, politician, and writer. After finishing medical school he joined the Unión Cívica Radical, later participating in the foundation of the  4302, 7600 Mar del Plata, Republica Argentina

C.J. Perez

Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA) (UNMdP-CONICET), Facultad de Ingenieria, Universidad Nacional de Mar del Plata, Juan B. Justo 4302, 7600 Mar del Plata, Republica Argentina

Correspondence to: C.J. Perez; e-mail:
COPYRIGHT 2005 Society of Plastics Engineers, Inc.
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2005 Gale, Cengage Learning. All rights reserved.

 Reader Opinion




Article Details
Printer friendly Cite/link Email Feedback
Author:Arzondo, L.M.; Perez, C.J.
Publication:Polymer Engineering and Science
Geographic Code:3ARGE
Date:Jul 1, 2005
Previous Article:Comparison of the performance of vulcanized rubbers and elastomer/TPE/iron composites for less lethal ammunition applications.
Next Article:Influence of long-chain branching on the rheological behavior of polyethylene in shear and extensional flow.

Related Articles
Synthetic industries adds capacity, products.
Oxygen plasma treatment of sisal fibers and polypropylene: effects on mechanical properties of composites.
A low-cost, low-fiber-breakage, injection molding process for long sisal fiber reinforced polypropylene.
German autos use more natural fibers.
Injection molding of long sisal fiber-reinforced polypropylene: effects of compatibilizer concentration and viscosity on fiber adhesion and thermal...
Lava-based fibers reinforce composites.
All-polymer composites from recycled woven polypropylene fabrics and polyethylene film.
Composite thermoplastic sheets including natural fibers: no. 7,431,980; Daniel Woodman, Venkat Raghavendran and John McHugh, assignors to Azdel,...

Terms of use | Copyright © 2014 Farlex, Inc. | Feedback | For webmasters