Teasing apart nanotubes: fast-spun carbon fibers may feed an industry.Nanoscale tubes of carbon could potentially lead to novel technologies, such as electronic circuits that are much faster and more compact than those made today. However, the batches of carbon nanotubes that manufacturers now produce are difficult to use because they contain a hodgepodge of tubes of varying electronic properties and diameters. Now, researchers have devised a way to sort these nanotubes. The technique could clear a major obstacle to industrial-scale application of the tubes in circuits, sensors, computer screens, and other products, say Michael S. Arnold and his colleagues at Northwestern University Northwestern University, mainly at Evanston, Ill.; coeducational; chartered 1851, opened 1855 by Methodists. In 1873 it absorbed Evanston College for Ladies. in Evanston, Ill. The new approach is "a landmark breakthrough," comments nanotechnologist and chemist Ray H. Baughman of the University of Texas at Dallas History The university was originally started as a research arm of Texas Instruments as the Graduate Research Center of the Southwest in 1961. The institute (by then renamed the Southwest Center for Advanced Studies) which at the time was located at Southern Methodist . "This method is surely going to accelerate the process for developing real applications of nanotubes," adds chemist Jie Liu of Duke University in Durham, N.C. The atomic structures of carbon nanotubes enable some of them to serve as semiconductors in nanoscale transistors (SN: 9/10/05, p. 165). Other nanotubes behave like metal wires. Nanotubes' diameters also affect their properties. In previous research, other scientists had devised ways to separate carbon nanotubes. However, those methods required costly additives or had other shortcomings A shortcoming is a character flaw. Shortcomings may also be:
In the new method, he and his colleagues, led by Mark C. Hersam, mix cheap, soaplike molecules called surfactants with a black powder black powder n. An explosive mixture of saltpeter, charcoal, and sulfur, formerly used in firearms. containing a jumble of carbon nanotubes. The surfactants render the nanotubes water soluble. The researchers then add the blend to a test tube that they've filled so that the concentration of an iodine compound--and the density of the solution--increases with depth. Next, they centrifuge centrifuge (sĕn`trəfy j), device using centrifugal force to separate two or more substances of different density, e.g., two liquids or a liquid and a solid. the materials for hours at tens of thousands of revolutions per minute. Buoyancy differences segregate seg·re·gate v. seg·re·gat·ed, seg·re·gat·ing, seg·re·gates v.tr. 1. To separate or isolate from others or from a main body or group. See Synonyms at isolate. 2. the nanotubes into homogeneous, horizontal bands. The nanotubes' structures cause each band to appear as a distinct color. "The first time we did this ... and saw a rainbow, we knew that it worked," Hersam recalls. Exquisitely precise, the new technique separates nanotubes that are only a few hundredths of a nanometer different in diameter, the team reports in the October Nature Nanotechnology Nature Nanotechnology, published by Nature Publishing Group, was launched in October 2006. The journal covers all areas of nanoscience and nanotechnology, including chemistry, physics, materials science, the life sciences and engineering, and also the application of . Metallic and semi-conductor nanotubes segregate because they attract different loads of surfactant Surfactant Definition Surfactant is a complex naturally occurring substance made of six lipids (fats) and four proteins that is produced in the lungs. It can also be manufactured synthetically. molecules, the scientists speculate. Although the team's experiments have produced only micrograms of purified nanotubes per band, a path to much larger yields is straightforward, Hersam says: Use bigger centrifuges, and lots of them. |
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