Sulfur hazard in the deep.While boring into the seafloor off the coast of Oregon, marine scientists pulled up a nasty surprise late last year. Several cores of rock collected during the drilling held extremely high concentrations of dangerous hydrogen sulfide hydrogen sulfide, chemical compound, H2S, a colorless, extremely poisonous gas that has a very disagreeable odor, much like that of rotten eggs. It is slightly soluble in water and is soluble in carbon disulfide. gas. "Ever since the beginning of scientific ocean drilling, which goes back to the 1960s, I don't think anybody's recovered a core that's so rich in hydrogen sulfide as this stuff was," says Timothy J. G. Francis, deputy director of the Ocean Drilling Program The Ocean Drilling Program (ODP) was an "international" "cooperative" "effort" to explore and study the composition and structure of the earth's ocean basins. ODP, which began in 1985, was the direct successor to the "highly successful" Deep Sea Drilling Project initiated in (ODP ODP - Open Distributed Processing ) in College Station, Texas College Station is a city in Brazos County, Texas, situated in Central Texas. It is located in the heart of the Brazos Valley. The city is located within the most populated region of Texas, near to three of the 10 largest cities in the United States - Houston, Dallas, and San . When the crew brought the cores up to the ship, the rock gave off potentially lethal doses lethal dose n. Abbr. LD The dose of a chemical or biological preparation that is likely to cause death. of gas, forcing the workers to don special breathing equipment, Francis and Robert E. Olivas note in the July 13 Eos. The ODP team encountered the hazardous rocks while drilling into a thick accumulation of sediments in 674 meters of water. The researchers believe the sediments contained hydrogen sulfide in the form of a gas hydrate hydrate (hī`drāt), chemical compound that contains water. A common hydrate is the familiar blue vitriol, a crystalline form of cupric sulfate. Chemically, it is cupric sulfate pentahydrate, CuSO4·5H2O. , an icelike structure kept solid by the tremendous pressures and cold temperatures of the deep ocean. Although they could not make direct measurements, the ODP scientists believe the water near the seafloor also contained dangerous concentrations of hydrogen sulfide. Francis says the drilling operation itself probably melted some of the gas hydrates, releasing hydrogen sulfide into the water. But if the deep ocean in this region normally holds significant concentrations of this gas, it could damage submersibles or other equipment visiting the site, he says. Because the area has geologic importance, submersibles have explored near there in the past. |
|
||||||||||||||||||

Printer friendly
Cite/link
Email
Feedback
Reader Opinion