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Steps up the ladder to superconductivity.


Ladder compounds--chains of atoms connected by atomic rungs--have a simplicity and symmetry that make them useful structures for studying how the spins of atoms in a material interact to produce an electric conductor or even a superconductor A material that has little resistance to the flow of electricity. Traditional superconductors operate at absolute zero (-459.67 degrees Fahrenheit or -273.15 degrees Celsius). Experiments in the 1980s raised the temperature to -321 degrees Fahrenheit. .

More often than not, however, such handy arrangements of atoms are just hypothetical structures created by theorists to clarify their ideas and make predictions. Now, researchers have synthesized a particular ladder structure made of copper, oxygen, and lanthanum lanthanum (lăn`thənəm) [Gr.,=to lie hidden], metallic chemical element; symbol La; at. no. 57; at. wt. 138.9055; m.p. about 920°C;; b.p. about 3,460°C;; sp. gr. 6.19 at 25°C;; valence +3.  atoms--key components of high-temperature superconductors--to check their theories.

Z. Hiroi and M. Takano of the Institute for Chemical Research at Kyoto University Kyoto University (京都大学 Kyōto daigaku  in Japan describe their findings in the Sept. 7 Nature.

The researchers produced a material consisting of two-leg ladders made of oxygen and copper atoms (see diagram). Lanthanum atoms occupy sites between adjacent ladders.

This lanthanum copper oxide compound is an electric insulator. Replacing some of the lanthanum atoms with strontium strontium (strŏn`shēəm) [from Strontian, a Scottish town], a metallic chemical element; symbol Sr; at. no. 38; at. wt. 87.62; m.p. 769°C;; b.p. 1,384°C;; sp. gr. 2.6 at 20°C;; valence +2.  atoms modifies the spin interactions between copper atoms to turn the material into an electric conductor. But contrary to predictions by some theorists, the researchers observed no transition to superconductivity superconductivity, abnormally high electrical conductivity of certain substances. The phenomenon was discovered in 1911 by Kamerlingh Onnes, who found that the resistance of mercury dropped suddenly to zero at a temperature of about 4.2°K;. .

"In addition to the intrinsic interest in ladder compounds, there is also the more general hope that studies of such systems can provide new insights into the nature of the mechanism responsible for [superconductivity in high-temperature superconductors]," comments Douglas J. Scalapino of the University of California, Santa Barbara History
The predecessor to UCSB, Santa Barbara State College, focused on teacher training, industrial arts, home economics, and foreign languages. Intense lobbying by an interest group in the City of Santa Barbara led by Thomas Storke and Pearl Chase persuaded the State
, in the same issue of Nature.
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Title Annotation:ladder made from copper, lanthanum and copper atoms produces some signs of being able to conduct electricity
Author:Peterson, Ivars
Publication:Science News
Article Type:Brief Article
Date:Sep 16, 1995
Words:232
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