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Shedding some light on UV curable coatings.


European finishing methods are gaining popularity in the U.S.

A quiet revolution is taking place in the U.S. wood finishing Wood finishing refers to the process of embellishing and/or protecting the surface. The process starts with surface preparation, either by sanding by hand (typically using a sanding block) or power sander, scraping, or planing.  industry. Stricter federal regulation of volatile organic compound volatile organic compound Environment Any toxic cabon-based (organic) substance that easily become vapors or gases–eg, solvents–paint thinners, lacquer thinner, degreasers, dry cleaning fluids  emissions is leading to an increase in the use of ultraviolet light-curable coatings and automated finishing lines similar to the European style of wood finishing.

While not explosive, the overall growth rate in the U.S. for sales of UV coatings and equipment is more than twice that for the general coatings industry. UV coating sales are predicted to maintain a healthy 10 to 15 percent growth rate. Growth is expected to increase as wood finishers become familiar with the advantages and application characteristics of non-thermal curing technologies.

Light-Induced Curing

UV-curable coatings are high-solids, cross-linked coatings cured by brief exposure to intense ultraviolet light Ultraviolet light
A portion of the light spectrum not visible to the eye. Two bands of the UV spectrum, UVA and UVB, are used to treat psoriasis and other skin diseases.
. The cure schedules for these types of coatings are incredibly fast - usually less than five seconds - allowing finishing lines to be shortened, line speeds increased, and products immediately handled and packaged. Also, since these products are high solids with little or no VOCs, compliance to stricter VOC (Vertical Online Community) See vertical portal.  regulations is made easier. Other advantages of UV coatings include increased superior hardness and durability compared to conventional coatings.

The chemical reaction, or polymerization polymerization

Any process in which monomers combine chemically to produce a polymer. The monomer molecules—which in the polymer usually number from at least 100 to many thousands—may or may not all be the same.
, that occurs in UV coatings involves two major constituents: monomers and oligomers. While reaction time is dependent on radiant intensity In radiometry, radiant intensity is a measure of the intensity of electromagnetic radiation. It is defined as power per unit solid angle. The SI unit of radiant intensity is watts per steradian (W·sr-1).  levels of the energy source, these two components are capable of reacting at extremely high rates. Oligomers are polymers that vary in chemical composition and define a coating's physical properties. There are four types of oligomers currently used in the majority of UV-wood coatings. They include urethane urethane (yoor´ithān´),
n ethyl carbamate used as an anesthetic agent for laboratory animals, formerly used as a hypnotic in humans.
, epoxy and polyester acrylates, and unsaturated unsaturated /un·sat·u·rat·ed/ (un-sach´ur-at?ed)
1. not holding all of a solute which can be held in solution by the solvent.

2. denoting compounds in which two or more atoms are united by double or triple bonds.
 polyesters.

With increasing regulation on solvent usage, significant advances have been made in waterborne oligomers for UV coatings. Existing waterborne UV-curable coatings provide films with lower solids, but achieve VOC emissions as low as 0.2 pounds per gallon. However, as is the case with conventional waterbornes, additional time and energy are required to remove the water from these coatings, and the finishes are more susceptible to flaws created by improper application and curing.

While the oligomer oligomer /ol·i·go·mer/ (ol´i-go-mer) a polymer formed by the combination of relatively few monomers.
oligomer (
 resin is the backbone structure, there are many other components that complete the UV-coating formulation. Multifunctional monomers are the "link" to oligomers that form the molecular network during the exposure of radiant energy radiant energy
n.
Energy transferred by radiation, especially by an electromagnetic wave.


radiant energy
Noun
. As the number of reactive groups increase, the higher the cross-linked density and the tighter the coating film. Although increasing cross-linked density is the primary function of a multifunctional monomer monomer (mŏn`əmər): see polymer.
monomer

Molecule of any of a class of mostly organic compounds that can react with other molecules of the same or other compounds to form very large molecules (polymers).
, a majority of these co-reactants are relatively low in viscosity and also serve a dual function as a diluent diluent /dil·u·ent/ (dil´oo-int)
1. causing dilution.

2. an agent that dilutes or renders less potent or irritant.


dil·u·ent
adj.
Serving to dilute.

n.
 in reducing viscosity. Other components of UV coatings include additives, pigments and fillers, similar to other wood coatings, which are designed to obtain desirable flow, leveling, curing and color characteristics.

While not new - UV coatings have been in existence for more than 25 years and are used extensively in Europe - they have been slow to catch on domestically. One reason for this is that, traditionally, most of the U.S. furniture industry has finished products manually using overhang lines and track-on-ceiling or tow-cart conveyor systems. In addition, wood products produced in the U.S. are typically assembled first and then finished, while in Europe wood furniture is often finished knocked-down, then assembled after finishing.

Consumer taste and technology advances, too, have played a role in the reluctance of U.S. wood manufacturers to implement the technology. The graceful, curing styles and intricate details typical of the U.S. residential furniture market are not conducive to flat-line finishing with highly-viscous UV coatings, white the more boxy box·y  
adj. box·i·er, box·i·est
Resembling a box, especially in simplicity or rectangularity.



boxi·ness n.
, squared-off furniture popular in Europe is easily flat-line finished. Similarly, the wide variety of color not of the white race; - commonly meaning, esp. in the United States, of negro blood, pure or mixed.

See also: Color
 options U.S. producers must carry to satisfy consumer preferences has prevented UV technology from being an economic alternative.

Due to recent advances in spray technology these systems are now being employed at cabinet shops and furniture manufacturers across the country.

Since UV coatings are generally formulated with little or no use of the aromatics, esters and ketones Ketones
Poisonous acidic chemicals produced by the body when fat instead of glucose is burned for energy. Breakdown of fat occurs when not enough insulin is present to channel glucose into body cells.

Mentioned in: Diabetic Ketoacidosis, Urinalysis
 (solvents required to keep liquid coatings in solution until the finish has cured in oil- or gas-fired convection ovens) VOC emissions are typically negligible. Curing is a free-radical, photoinitiating process, in which the coating is exposed to UV light. Photoinitiator chemicals in UV coatings quickly absorb the ultraviolet light and start a rapid chemical reaction which is often completed in as little as five seconds. Because the liquid coating is entirely converted into a solid, there are virtually no emissions.

Equipment Advances

While UV coatings can be applied by airless or conventional spray guns, reverse roll coaters or curtain coaters, they are always applied using automated processes. Spray lines typically provide about 50 to 75 percent transfer efficiency, while roll coater lines can achieve 100 percent transfer efficiency. According to according to
prep.
1. As stated or indicated by; on the authority of: according to historians.

2. In keeping with: according to instructions.

3.
 equipment manufacturers, roller and curtain coater systems are becoming popular for flat-panel production, while spray systems are being used for shaped and three-dimensional pieces.

New automatic, computer-controlled, carousel-type robotic spraying units with a photo eye "read" the substrate and fire the precise amount of coating to an exact configuration. Also providing exceptional finishing capabilities are reciprocating sprayers which use separate heads that traverse the conveyor and employ the photoeye technology within an enclosed structure.

The new application technologies make it increasingly likely that manufacturers who already make limited use of UV coatings will expand the use of these systems to more intricate or detailed furniture. Kitchen cabinet manufacturers, for example, who already use UV coatings on end panels are likely to find that equipment advances now make it practical for them to apply UV coatings to doors.

Costs/Benefits

While the investment required in UV application equipment is steep, the potential benefits are tremendous. Costs to outfit a UV coating line typically range from $50,000 at the very low end to $1 million, depending on the sophistication so·phis·ti·cate  
v. so·phis·ti·cat·ed, so·phis·ti·cat·ing, so·phis·ti·cates

v.tr.
1. To cause to become less natural, especially to make less naive and more worldly.

2.
 of the system. It is not unusual for a manufacturer to recoup that investment in a relatively short time from production benefits.

For example, a 500-foot finishing line, with 25 employees using conventional spray-applied coatings, could be shortened to 90 feet and would require only two or three employees if redesigned for UV coatings. Production time in such a scenario would be reduced from 1.5 hours to 10 to 20 minutes or less. In addition, energy costs can be lowered and virtually all VOCs eliminated.

Chuck Susnis is the chemical coatings market development manager for the Sherwin-Williams Co. of Cleveland, OH.
COPYRIGHT 1998 Vance Publishing Corp.
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 1998, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Title Annotation:Finishing Newsfront
Author:Susnis, Chuck
Publication:Wood & Wood Products
Date:Apr 1, 1998
Words:1085
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