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Production of acetate-grade pulps by organic acid pulping and TCF Bleaching.


Application: Mills can produce high-purity pulps and cellulose derivatives such as cellulose acetate from Eucalyptus globulus or aspen wood via pulping in organic acid media (Milox or Acetosolv technologies) and TCF See Trenton Computer Festival.  bleaching.

This work deals with the production of high-purity pulps from Eucalyptus globulus or aspen wood via pulping in organic acid media (Milox or Acetosolv technologies) and totally chlorine free (TCF) bleaching. The selected delignification technologies cause extended delignification with limited cellulose alteration at comparatively low operating temperatures and pressures. The production of marketable by products (sugars, furfural furfural (fûr`fərəl) or furfuraldehyde (fûr'fərăl`dəhīd) [Lat.,=bran], C4H3 , acetic acid acetic acid (əsē`tĭk), CH3CO2H, colorless liquid that has a characteristic pungent odor, boils at 118°C;, and is miscible with water in all proportions; it is a weak organic carboxylic acid (see carboxyl group). , and sulphur-free lignin lignin (lĭg`nĭn), a highly polymerized and complex chemical compound especially common in woody plants. The cellulose walls of the wood become impregnated with lignin, a process called lignification, which greatly increases the strength and  fragments) and the susceptibility of pulps to TCF bleaching are also favorable characteristics of both pulping technologies.

The experimental work focused on the comparative susceptibility of pulps toward TCF bleaching using an optimized sequence [E(O)Z[C.sub.CP]P, to measure their potential as substrates for cellulose acetate production.

Following an alkaline extraction reinforced with oxygen [E(O)] stage, we subjected the pulp samples to an ozone (Z) stage and pH 2 using medium consistency operation. Cold caustic extraction (CCE CCE Cornell Cooperative Extension
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 stage) reduced the hemicellulose hem·i·cel·lu·lose
n.
Any of several polysaccharides that are more complex than a sugar and less complex than cellulose and found in plant cell walls.



hemicellulose

structural polysaccharide of plants.
 content of pulps. After this stage, Milox-processed Eucalyptus pulp presented the lowest kappa number (0.5); the best brightnesses were obtained for Milox-delignified pulps (85.9% and 85.8% for pulps from Eucalyptus and aspen, respectively). The treatments caused limited viscosity loss (23-31 mL/g).

The procedure for TCF-delignification of Milox-and Acetosolv-pulps from Eucalyptus and aspen considered in this work produced high-purity pulps suitable for the manufacture of cellulose derivatives. Among the possibilities examined, Milox-delignified pulps from aspen and Eucalyptus showed the best properties.

Dapia and Parajo are with the Department of Chemical Engineering, University of Vigo The University of Vigo (Galician: Universidade de Vigo) is a public university located in the city of Vigo, Galicia. There are three campuses:
  • Lagoas-Marcosende, between the municipalities of Vigo and Mos;
  • A Xunqueira, in Pontevedra;
 (Campus Ourense), Polytechnical Building, Ourense, Spain. Sixta, Borgards, and Harms are with Lenzing A.G. in Lenzing, Austria. Contact Parajo by e-mail at jcparajo@uvigo.es: or by fax at +34988387001.
COPYRIGHT 2002 Paper Industry Management Association
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Copyright 2002, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Title Annotation:Pulping: summary of peer-reviewed material
Author:Parajo, Juan Carlos
Publication:Solutions - for People, Processes and Paper
Date:May 1, 2002
Words:308
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