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New process purifies high-temp ceramics.


How annoying when a dinner plate cracks in the dishwasher. But what if that dinner plate were part of a jet engine?

Under intense heat and pressure, ceramics can crack. A big difference between household ceramics (like teacups
For the drinking vessel, see teacup.


The Teacups are an amusement ride that have a rotating floor. Each set of teacups has a circular floor, or a motor that will turn 360 degrees.
 or sinks) and high-temperature ceramics (like engine parts or capacitors) is purity. For a ceramic to withstand big loads and temperatures (above 1,200 [degrees] C), it must be free of impurities.

Now, a new purification purification, in religion, the ceremonial removal of what the religion deems unclean. The usual agents of purification are water (as in baptism), bodily alteration (as in circumcision), and fire.  process promises to improve high-temperature ceramics. Developed at NASA's Lewis Research Center in Cleveland, the new method uses compounds derived from guanidine guanidine /gua·ni·dine/ (gwah´ni-den) the compound NHdbondC(NH2)2, a strong base found in the urine as a result of protein metabolism and used in the laboratory as a protein denaturant.  to remove sodium and potassium potassium (pətăs`ēəm), a metallic chemical element; symbol K [Lat. kalium=alkali]; at. no. 19; at. wt. 39.0983; m.p. 63.25°C;; b.p. 760°C;; sp. gr. .862 at 20°C;; valence +1.  residues that show up when the ceramics are fired in their molds.

"These [guanidine-derived] chemicals have direct use in the aerospace industry," says senior research chemist Warren H. Philipp, who invented the process. "We can use them to form lightweight, corrosion-resistant ceramic parts leading to more efficient aircraft engines and rocket motors." The process also may improve capacitors and superconductors, he says.

Typically, ceramic parts come from powders, which are mixed with solvents, poured into molds, and fired in kilns. Usually, some sodium and potassium residues remain, compromising the ceramic's integrity. Often this imperfection im·per·fec·tion  
n.
1. The quality or condition of being imperfect.

2. Something imperfect; a defect or flaw. See Synonyms at blemish.


imperfection
Noun

1.
 doesn't matter. But at high temperatures and stress, residues can cause cracks.

The new guanidine-based process, however, removes virtually all sodium or potassium residue residue n. in a will, the assets of the estate of a person who has died with a will (died testate) which are left after all specific gifts have been made. Typical language: "I leave the rest, residue and remainder [or just residue] of my estate to my grandchildren. . The result, says Philipp: purer, stronger, and more corrosion-resistant ceramic products.
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Title Annotation:new process uses guanidine-derived compounds to remove sodium and potassium residues in high temperature ceramics
Publication:Science News
Article Type:Brief Article
Date:Aug 21, 1993
Words:230
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