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NaB[H.sub.4] + 2[H.sub.2]O [right arrow] 4[H.sub.2] NaB[O.sub.2].


Little did we know when watching the television show Death Valley Days just how much it would predict the Future. Host Ronald Reagan became the 40th president, and the main ingredient in "20 Mule Team Borax borax or sodium tetraborate decahydrate (sō`dēəm tĕ'trəbôr`āt dĕk'əhī`drāt), chemical compound, Na2B4O7·10H2O; sp. gr. 1. "--the show's sponsor--is a prime contender For powering automotive Fuel cells. Who knew?

"The main question concerning Fuel cells has been, 'Where do you get the hydrogen?'," says Tom Moore, vice president of DaimlerChrysler's Liberty Technical Affairs. Where indeed, and at what cost? Gasoline reformer Fuel cells have start-up emissions. Methanol reformers are subject to corrosion, and the fuel burns with an invisible Flame. Storing hydrogen under pressure requires a large tank which places limits on vehicle range.

Sodium borohydride Sodium borohydride, also known as sodium tetrahydroborate, has the chemical formula NaBH4. This white solid, usually encountered as a powder, is a specialty reducing agent used in the manufacture of pharmaceuticals and other organic and inorganic compounds. , on the other hand, is non-toxic, comes in powder form, and Forms a non-combustible slurry slurry,
n a thin mixture of insoluble material floating in liquid.


slurry

solids in suspension. Used as a method of feeding pigs—slurry is pumped through fixed lines and delivered to troughs by hoses equipped with gasoline pump fittings.
 when mixed with water. Passing this mixture through a ruthenium ruthenium (rthē`nēəm), metallic chemical element; symbol Ru; at. no. 44; at. wt. 101.07; m.p. about 2,310°C;; b.p. about 3,900°C;; sp. gr. 12.  catalyst Frees the hydrogen to run the fuel cell, and leaves a hydrogendepleted borax slurry as its "waste" product. This remnant can be re-hydrogenated [currently via a natural gas-powered process] to turn it into fuel again.

Millennium Cell, Inc. (Eatontown, N.J.).) is working with Moore's group to perfect this "hydrogen on demand" process For automotive use. Rex Luzader, v.p. of Business Development--Transportation at Millennium says recyclability is just one advantage sodium borohydride has over its competitors. "The reaction is easily controlled through the catalyst and reactor configuration," he says. Turning the pump off isolates the fuel From the catalyst. And the catalyst can be used many, many times. Plus, the storage tank doesn't require any special materials, and doesn't have to contain high pressures." The tank is unique, however.

"We developed a dual-bladder fuel tank," says Moore, "to hold the residue created by this process." Refueling pushes the filtrate filtrate /fil·trate/ (fil´trat) a liquid or gas that has passed through a filter.

fil·trate
v.
To put or go through a filter.

n.
 out of the second bladder and into a collection tank, where it is held until returned for reprocessing Reprocessing may refer to:
  • Nuclear reprocessing
  • Recycling
. "Unlike gasoline, the tankers won't return to the refinery empty," says Moore, "so the trip back is value-added." And vehicle dynamics Vehicle dynamics refers to the dynamics of vehicles, here assumed to be ground vehicles.

For two-wheeled vehicles see Bicycle and motorcycle dynamics. For the dynamics of air vehicles see Aerodynamics.
 are more consistent due to the retention of the residue. There is no dramatic weight variation between "Full" and "empty".

The technology currently is undergoing testing in a Chrysler minivan. "Technically, the vehicle is a hybrid," says Moore, "because the fuel cell recharges a lithium-ion battery Lithium-ion batteries (sometimes abbreviated Li-ion batteries) are a type of rechargeable battery commonly used in consumer electronics. They are currently one of the most popular types of battery for portable electronics, with one of the best energy-to-weight ratios, no  pack that provides power for the wheels." Early testing has shown the van to be capable of 0-60 mph in 16 sec., the equivalent of 30 mpg, and of 300 miles on a tank of, well, slush slush  
n.
1. Partially melted snow or ice.

2. Soft mud; slop; mire.

3. Nautical Grease or fat discarded from a ship's galley.

4. A greasy compound used as a lubricant for machinery.
. That tank, by the way, holds 54 gallons of new fuel, up to 40 gallons of residue, and is located between the rear axle and bumper under the van floor.

Ironically, U.S. Borax, Former sponsor of Death Valley Days, owns most of the borax reserves in the world. There are 600 million metric tons of known borax reserves (dry lake beds are the greatest source), and estimates predict the 50 million vehicles currently on the road would use 20 million tons of borax each year, most of which would be recycled.
COPYRIGHT 2002 Gardner Publications, Inc.
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2002, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Title Annotation:Hydrogen source Borax, fuel cell developemnt
Comment:NaB[H.sub.4] + 2[H.sub.2]O [right arrow] 4[H.sub.2] NaB[O.sub.2].(Hydrogen source Borax, fuel cell developemnt)
Author:Sewyer, Christopher A.
Publication:Automotive Design & Production
Article Type:Brief Article
Geographic Code:1USA
Date:Mar 1, 2002
Words:506
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