Mineral filler pore structure and paper properties.Application: Knowing filler and paper porosity characteristics, one can adjust a papermaking pa·per·mak·ing n. The process or craft of making paper. pa per·mak process to control structural and optical properties of paper. Mineral fillers scatter light by virtue of the light-scattering surfaces that become available when filler is incorporated in the dried fiber web. This capacity is the filler's opacifying efficiency, which is a function of particle size Particle size, also called grain size, refers to the diameter of individual grains of sediment, or the lithified particles in clastic rocks. The term may also be applied to other granular materials. , shape, and refractive index A property of a material that changes the speed of light, computed as the ratio of the speed of light in a vacuum to the speed of light through the material. When light travels at an angle between two different materials, their refractive indices determine the angle of transmission . Our goal was to assess how different mineral fillers influence light-scattering capacity as well as bulk, air permeability, and burst strength. Therefore, we carried out porosity studies on mineral fillers that have different particle shapes and different degrees of particle aggregation Particle aggregation in materials science is direct mutual attraction between particles (atoms or molecules) via van der Waals forces or chemical bonding. When there are collisions between particles in fluid, there are chances that particles will attach to each other and . Results The mineral fillers studied did show scattering coefficients over a wide range, which was expected since they have different morphologies, particle size distributions The particle size distribution[1] ("PSD") of a powder, or granular material, or particles dispersed in fluid, is a list of values or a mathematical function that defines the relative amounts of particles present, sorted according to size. , and specific surface areas. Internal voids determine the light-scattering ability of the filler. In this study, we found that the pore size range of 1.0-0.01 [micro]m corresponds best with light scattering. This result means that the number of pores of small size is decisive. The synthesis of a PCC PCC prothrombin complex concentrate. scalenohedral or rhombohedral filler could be controlled to increase the amount of internal voids in the range of 1-0.01 [micro]m in order to achieve higher light-scattering capacity. Conclusions Mercury-intrusion porosimetry is a useful tool for evaluating mineral fillers and paper porosity. Data obtained for commercial paper fit well with data obtained for papers produced in the laboratory, which means that pore size distributions of commercial and lab papers are similar. Precipitated calcium carbonate calcium carbonate, CaCO3, white chemical compound that is the most common nonsiliceous mineral. It occurs in two crystal forms: calcite, which is hexagonal, and aragonite, which is rhombohedral. (PCC) fillers having scalenohedral habit were particularly effective in producing pores of acceptable size. The two PCC fillers studied were optically superior to the PCC rhombohedral filler. Ground calcium carbonate filler was less effective because it has a great number of pores of large sizes. Valho and Games are professors in Departamento de Geociencias, Universidade de Aveiro, 3810 Aveiro, Portugal, Santos is a professor in Departamento de Engenharia Quimica Industrial, Institute Politecnico de Tomar, 2300 Tomar, Portugal. Address correspondence to Velho by email at jvelho@clix.pt |
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