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Maybe it's not as crosslinked as you think. (Keeping up with Compounding).


Compounders frequently check cure levels in crosslinked compounds by measuring torque in a curemeter or rheometer rhe·om·e·ter
n.
An instrument for measuring the flow of viscous liquids, such as blood.
. The assumption is that torque is proportional to crosslink density. But a computer simulation model calibrated with real crosslink data shows this method grossly overestimates crosslink density.

Robert Johnston, research associate at DuPont Dow Elastomers LLC (Logical Link Control) See "LANs" under data link protocol.

LLC - Logical Link Control
 in Freeport, Texas, reported his surprising results at the SPE SPE - Software Practice and Experience  ANTEC meeting in San Francisco in May. Data were obtained with the company's SimPolyMod software. Johnston worked with four grades of DuPont Dow's Engage ethylene-octene polyolefin elastomer elastomer (ĭlăs`təmər), substance having to some extent the elastic properties of natural rubber. The term is sometimes used technically to distinguish synthetic rubbers and rubberlike plastics from natural rubber. . He found that torque tests can't distinguish actual crosslinks from elastically active, trapped entanglements, which also affect properties, and entanglements of dangling chains, which contribute little to material al properties. Tel: (800) 853-5515, www.dupont-dow.com
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Copyright 2002, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Comment:Maybe it's not as crosslinked as you think. (Keeping up with Compounding).
Publication:Plastics Technology
Article Type:Brief Article
Geographic Code:1USA
Date:Aug 1, 2002
Words:125
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