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Material mimics mother-of-pearl in form and substance. (Material Science).


Gleaming, iridescent ir·i·des·cent  
adj.
1. Producing a display of lustrous, rainbowlike colors: an iridescent oil slick; iridescent plumage.

2.
 mother-of-pearl possesses more than beauty. The material, technically called nacre nacre: see mother-of-pearl. , has strength and toughness that materials scientists envy because it's made of highly ordered layers.

Now, researchers have designed a synthetic material that mimics both nacre's internal architecture and its strength.

Nicholas Kotov of Oklahoma State University Oklahoma State University, at Stillwater; land-grant and state supported; coeducational; chartered 1890, opened 1891 as Oklahoma Agricultural and Mechanical College, renamed 1957.  in Stillwater and his colleagues modeled their material after natural mother-of-pearl, which gets its properties from a brick-and-mortar structure of calcium carbonate calcium carbonate, CaCO3, white chemical compound that is the most common nonsiliceous mineral. It occurs in two crystal forms: calcite, which is hexagonal, and aragonite, which is rhombohedral.  held together by a network of proteins. Natural nacre also benefits from so-called sacrificial ionic bonds between proteins, which break under stress but can reform.

Kotov and his coworkers programmed a robot to dip glass slides in alternating solutions of a negatively charged clay known as montmorillonite Montmorillonite is a very soft phyllosilicate mineral that typically forms in microscopic crystals, forming a clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite family, is a 2:1 clay, meaning that it has 2 tetrahedral sheets sandwiching a  and a positively charged polymer called PDDA PDDA Power Driven Decontamination Apparatus
PDDA Physicians Drug and Diagnosis Audit
, short for poly(diallydimethylammonium) chloride. This process built up hundreds of layers of clay and polymer, each one a few nanometers thick. The clay acted the part of bricks while the polymer played the mortar. What's more, the resulting film contained sacrificial bonds between PDDA chains. In mechanical tests, the material was as strong as nacre. The researchers describe their work in the June Nature Materials.

Kotov's team plans to improve the strength and other characteristics of the synthetic nacre. Eventually, the material could prove useful in the construction of artificial bones, body armor, and aircraft and automobile parts, Kotov says.--J.G.
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Publication:Science News
Article Type:Brief Article
Geographic Code:1USA
Date:Jun 21, 2003
Words:228
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