In-mold coatings advance on many fronts.As reported previously, the latest news in in-mold coatings is a one-component topcoating system for thermoset A polymer-based liquid or powder that becomes solid when heated, placed under pressure, treated with a chemical or via radiation. The curing process creates a chemical bond that, unlike a thermoplastic, prevents the material from being remelted. See thermoplastic. polyester SMC SMC Saint Mary's College SMC Santa Monica College SMC Solaris Management Console SMC Smooth Muscle Cell SMC Small Magellanic Cloud (also see LMC) SMC Safety Management Certificate (maritime shipping) compression molding, which was introduced by Sherwin-Williams Co., Cleveland, at the recent SPI (1) (Stateful Packet Inspection) See stateful inspection. (2) (Service Provider Interface) The programming interface for developing Windows drivers under WOSA. Composites Institute conference (see PT, Jan. '91, p. 37). The company is already known for its vinyl ester-based, one-component in-mold black primer for automotive SMC. The new in-mold topcoats are non-automotive, polyester-based, and eliminate the need for priming. One series of topcoats is aimed primarily at sanitary ware, such as sinks and bathtubs. Another is an exterior durable line, for which applications in recreational equipment and building/construction supplies are in active development. The topcoats are composed of 100% solids with near-zero volatile emissions. The technology requires a metering and injection machine (sold by firms such as Morrell, Inc., Auburn Hills, Mich.), which is integrated into the SMC molding press. The topcoat reportedly mirrors the gloss level of tool surfaces. (CIRCLE 5) WORK ON RTM (1) (RealTime Model) Refers to a system or architecture that performs operations in real time. See real time. (2) (Release/Released To M , PULTRUSION Pultrusion is a continuous process of manufacturing of composite materials with constant cross-section whereby reinforcing fibers are pulled through a resin, possibly followed by a separate preforming system, and into a heated die, where the resin undergoes polymerization. That's only one of several new in-mold coatings developments in the works at Sherwin-Williams, according to plastics market manager John M. Clifford. The firm is now field testing a new faster curing system for thermosets thermosets, materials that can not be softened on heating. In thermosetting polymers, the polymer chains are joined (or cross-linked) by intermolecular bonding. Thermosets are usually supplied as partially polymerized or as monomer-polymer mixtures. , which will reduce cure times as much as 30-40%, overcome streaking problems, and offer a broader range of adhesion, according to Clifford. Besides SMC, Sherwin-Williams is pursuing new markets for its one-component systems in thermoset RTM, where they're said to eliminate the need for gelcoats, and in in-line coating of pultruded profiles for various exterior applications. In pultrusion, the coatings may be applied either inside the main forming die or downstream. Clifford notes that patents are being filed by processors working in this area. (CIRCLE 6) THERMOPLASTICS & RIM, TOO What's more, the company also is continuing work on a two-component, polyurethane-based in-mold coating for injection molded thermoplastic components, which may be unveiled later this year, after five years in development (see PT, Sept. '88, p. 81; Feb. '89, p. 14). Like SMC in-mold coatings, this application reportedly does not add to the mold cycle time and has two advantages over spray painting: no solvent emissions and 100% utilization of coating materials. Clifford emphasizes that the company is not yet ready to entertain customer inquiries on this technology, known as High Pressure Injection In-Mold Coating. Remaining obstacles, Clifford says, are primarily equipment-related. How to achieve efficient color changes is one aspect still being investigated. Sherwin-Williams has worked primarily with RIM machinery from Krauss-Maffei Corp., Florence, Ky. Clifford sees major thermoplastic opportunities outside of automotive--in off-road vehicles, lawn-and-garden equipment, and business machines. Down the road, EMI (ElectroMagnetic Interference) An electrical disturbance in a system due to natural phenomena, low-frequency waves from electromechanical devices or high-frequency waves (RFI) from chips and other electronic devices. Allowable limits are governed by the FCC. shielding may be a potential application. There is also significant automotive potential, such as thermoplastic instrument panels and bumper fascia. Clifford also says the thermoplastic system, once fully developed, could be applied to thermoset urethane urethane (yoor´ithān´), n ethyl carbamate used as an anesthetic agent for laboratory animals, formerly used as a hypnotic in humans. RIM, SRIM n. 1. Scum; refuse. and RTM (in applications where cure temperatures are too low for the one-component coatings). Current in-mold technology for RIM involves spraying a solvent paint into the open mold before injection. |
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