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Gas transport properties in chlorosulfonated polyethylene-acrylate based adhesives.



INTRODUCTION

Gas separation by means of polymer membranes has been for the past two decades among the most dynamic fields of applied science, as research has been able to greatly improve the performance of polymeric materials (1-5). For the last 30 years, development has followed the trend of seeking polymeric structures that in themselves show good permeability and permselectivity properties. Thus, several correlations between structure and gas transport properties have been described (3, 6-10), and it is nowadays well known that chain rigidity enhances selectivity and diminishes permeability, whereas interchain spacing increases the permeability of polymers. In this way, open structures with rigid backbones and bearing polar groups, which selectively enhance the solubility of the gases, have proved to be the most successful polymeric structures for gas separation. In particular, polyimides, polyetherimides, polysulfones and related polymers (11-15) present the best combination of properties, and are used in the formulat ion of numerous commercial polymeric structures.

Some new polymer families with increased spacing and rigidity are being introduced as high performance gas separation materials (16-18), though these structural features cannot be augmented without limit. On the other hand, the polymeric materials that have proved to be the best for gas separation present a series of drawbacks, the most important of which are their price and occasional difficulty in film preparation, as they are often difficult to dissolve and have high glass transition temperatures. Hence, alternative ways to produce materials with good transport properties and that are cheaper and easier to handle are beginning to be studied. Blends of inorganic compounds and polymeric matrices have lately been tested, showing interesting combination of properties (12, 19-21). The effect of miscibility miscibility (miˈ·s·biˑ·l  and inmiscibility of polymeric blends is also being explored as a means of modifying the transport coefficients (22, 23). For example, it has been shown that in polycarbonate/polymethyl methacrylate methacrylate /meth·ac·ry·late/ (meth-ak´ri-lat) an ester of methacrylic acid, or the resin derived from polymerization of the ester. See also acrylic resins, under resin.  blends, p ermeability and diffusivity Dif`fu`siv´i`ty

n. 1. Tendency to become diffused; tendency, as of heat, to become equalized by spreading through a conducting medium.
 increase as the mixture becomes immiscible immiscible /im·mis·ci·ble/ (i-mis´i-b'l) not susceptible to being mixed.

im·mis·ci·ble
adj.
Incapable of being mixed or blended, as oil and water.
. This behavior has been related to the effect of the mixing at a molecular level on the local chain motions (22). Carriers are also being extensively used to improve the properties of otherwise "dull" but inexpensive polymers (24). Crosslinking also appears to be a means of improving the properties of polymer membranes (25, 26). An interesting approach to the improvement of the end-properties of materials as gas separators is the use of polymers that together with reasonable selectivity to a particular pair of gases can be prepared in very thin films with good mechanical properties. In this way, the small thickness can compensate for low permeabilities, as the gas flow depends inversely upon thickness. In this connection, photocuring offers several advantages for fabricating membranes. First, photocurable resins can be formulated solvent-free, eliminating voids due to solvent evaporation and other shortcomings regarding the well-known lack of reproducibility caused by the use of solvent cast films for gas separation. As a matter of fact, the type of solvent and the drying process are among the factors of greatest influence on the performance of a gas separation membrane (3). Second, photocuring enables the preparation of layers polymerized onto an adequate porous substrate. UV-photoinduced polymerization polymerization

Any process in which monomers combine chemically to produce a polymer. The monomer molecules—which in the polymer usually number from at least 100 to many thousands—may or may not all be the same.
 has been rarely used to produce membranes for gas separation although it is widely used in other applications, for instance, coatings, adhesives, and inks (27, 28).

In a previous work (29) we presented results on the gas transport properties of a Loctite formulation (Loctite 350[R]) based on aliphatic aliphatic /al·i·phat·ic/ (al?i-fat´ik) pertaining to any member of one of the two major groups of organic compounds, those with a straight or branched chain structure.

al·i·phat·ic
adj.
 polyurethanes and a mixture of acrylic and methacrylic monomers (called [L.sub.PU] hereafter), which showed interesting gas separation properties, especially as regards the pair of gases [O.sub.2]/[N.sub.2]. The permselectivity of membranes prepared from this formulation to this pair of gases is about 4.6 at 25[degrees]C, and it increases at lower temperatures. Because of their other special properties, adhesivity and the possibility to coat a variety of supports with fine layers, survey through these polymers appears interesting.

In this work, the results obtained with a crosslinked system based on Loctite 329[R] are presented. This is an acrylic adhesive characterized by its high toughness, which makes it very suitable for use in strength structural joints or in sheet steel where continuous or repeated loads are generated. The rough material is composed of a chlorosulfonated polyethylene binder (CSPE CSPE Chlorosulfonated Polyethylene
CSPE California Society of Professional Engineers
CSPE Client/Server Processing Environment
CSPE Communications System Planning Element
CSPE Certified Software Process Engineer (QAI Global Institute) 
) and a mixture of different acrylic and methacrylic monomers, which, upon polymerization, lead to a crosslinked network. The chlorine atoms and the chorosulfonic groups are reactive centers that generate, under certain conditions, crosslinking points between the binder chain and the polymerizing acrylic macroradical. This contributes to its mechanical strength and elastic properties when fully cured. This adhesive is usually used as a two-component thermally curable cur·a·ble
adj.
Capable of being cured or healed.
 adhesive, by mixing with room-temperature thermal activators. In this work we have introduced in the formulation a photochemical photochemical

in laser treatment, the laser light is absorbed and converted into chemical energy.
 initiator, which permits better control of th e polymerization reaction, through control of the incident light intensity. The gas transport properties of the membranes thus prepared, which will be called [L.sub.CSPE] hereafter, have been measured and the results compared to those previously obtained with [L.sub.PU].

EXPERIMENTAL

Materials

The transport properties have been tested using four gases supplied by Praxair. These are methane of purity 5.0, nitrogen and oxygen of purity 6.0, and carbon dioxide carbon dioxide, chemical compound, CO2, a colorless, odorless, tasteless gas that is about one and one-half times as dense as air under ordinary conditions of temperature and pressure.  of purity 4.8. Loctite 329 and phenyl-bis- (2,4,6-trimethylbenzoyl) phosphine phosphine

1. PH3, a toxic war gas called hydrogen phosphide.

2. a coal tar dye; called Philadelphia yellow.
 oxide (Irg819) were generous gifts from Loctite and Ciba SC, respectively.

The composition of Loctite 329 was found to include 36% w/w of a chlorosulfonated polyethylene polymer (Scheme 1), which acts as a binder, and a mixture of different methacrylic monomers, including methyl methacrylate methyl methacrylate
(meth´il methak´rilāt),
n an acrylic resin, CH2 = C(CH3)COOCH3, derived from methyl acrylic acid. Monomer is the single molecule and polymer is the polymerization product.
 as a main constituent (52% w/w of the adhesive composition).

Sample Preparation and Photocrosslinking

Samples containing 1% w/w phenyl-bis-(2,4,6trimethylbenzoyl) phosphine oxide (Irg819) and Loctite 329 were prepared by mixing both components and stirring until a homogeneous solution was obtained. They were placed between two transparent polyethylene films (LDPE LDPE
abbr.
low-density polyethylene
, 80 [mu]m thick) and pressed with 2 X [10.sup.3] kg/c[m.sup.2] during 1 min using different spacers, which permits us to obtain membranes of different and reproducible thickness. The membranes used in this work were about 70 [mu]m thick. The samples were placed inside an ATLAS SUNTEST XSL (eXtensible Stylesheet Language) A standard from the W3C for describing a style sheet for XML documents. It is the XML counterpart to the Cascading Style Sheets (CSS) in HTML and is compatible with CSS2.  equipment, provided with Xenon xenon (zē`nŏn) [Gr.,=strange], gaseous chemical element; symbol Xe; at. no. 54; at. wt. 131.29; m.p. −111.9°C;; b.p. −107.1°C;; density 5.86 grams per liter at STP; valence usually 0.  lamps with a power output of 550W/[m.sup.2] and irradiated with polychromatic polychromatic /poly·chro·mat·ic/ (-krom-at´ik) many-colored.

pol·y·chro·mat·ic or pol·y·chro·mic or pol·y·chro·mous
adj.
Having or exhibiting many colors.
 light for 6 min, which allowed the system to photopolymerize until limiting conversion was obtained. The residual monomer was removed by immersion of the membrane in chloroform chloroform (klôr`əfôrm) or trichloromethane (trī'klôrōmĕth`ān), CHCl3 , for 24 h and vacuum drying vacuum drying
n.
Removal of liquid material from a solution or mixture under reduced air pressure, which results in drying at a lower temperature than is required at full pressure.
 until a constant weight was reached. These amorphous membranes will be called [L.sub.CSPE] hereafter.

Dynamic Mechanical Analysis, DMA (1) (Digital Media Adapter) See digital media hub.

(2) (Document Management Alliance) A specification that provides a common interface for accessing and searching document databases.
 

An attempt to determine the transitions and relaxations of the material by differential scanning calorimetry Differential scanning calorimetry or DSC is a thermoanalytical technique in which the difference in the amount of heat required to increase the temperature of a sample and reference are measured as a function of temperature.  has been made, but no clear variations of the specific heat could be detected. DMTA DMTA Dynamic Mechanical Thermal Analysis
DMTA Davis Music Teachers' Association
DMTA Demented Minds Think Alike
DMTA Digital Media Teaching Aids
DMTA Diversity-Multiplexing Tradeoff Analysis
 measurements have been performed with this same scope. The tensile dynamic mechanical spectra were obtained in a Polymer Laboratories Thermal Sciences Dynamic Mechanical Analyzer. The measurements were carried out in tension mode between -90[degrees]C and 100[degrees] using a heating rate of 1.5[degrees]C/min at four frequencies. 1, 3, 10 and 30 Hz. The probes were parallelepipeclic bars of dimensions 0.10 x 2.2 x 15.3 [mm.sup.3].

Permeation Measurements

A lab-made permeator was used, consisting of a gas cell in the middle of which the polymer membrane was placed. This membrane separates the upstream and downstream chambers. For the simplified equations relating the gas flow through the membrane to the transport coefficients to be valid, the downstream pressure must be kept very low, negligible as compared to the upstream. This is accomplished by thorough evacuation of the downstream, prior to any measurement, by means of an Edwards turbomolecular pump A turbomolecular pump is a type of vacuum pump, superficially similar to a turbopump, used to obtain and maintain high vacuum. These pumps work on the principle that gas molecules can be given momentum in a desired direction by repeated collision with a moving solid surface. . At the low-pressure side, an MKS (Mortice Kern Systems Inc., Waterloo, Ontario, www.mks.com) A software company that specializes in programming tools and utilities for a variety of platforms. For example, its RCS system for Windows, OS/2 and Unix is a version control software package.  Baratron type 627B absolute pressure transducer Pressure transducer

An instrument component which detects a fluid pressure and produces an electrical, mechanical, or pneumatic signal related to the pressure.
 measures the pressure increase, while at the upstream a Gometrics pressure detector is used to control the gas pressure at which the experiment is performed. The Baratron 627B can be used in the pressure range 1 torr torr (tōr),
n a unit of pressure equivalent to 0.001316 atmosphere; named after the physicist Torricelli. Also called
mm Hg.
 to [10.sup.-4] torr. The Baratron is connected via an MKS power supply/readout unit to the PC, which records the pressure increase at given time intervals. The whole setup is temperature controlled in the range 20[degrees]C to 80[degrees]C by means of a water bath.

Prior to any measurement, vacuum is maintained overnight in order to remove any residual solvent from the membrane and to attain a downstream pressure that is as low as possible. Before any permeation experiment is performed, a measurement of the pressure increase due to imperfect vacuum isolation of the downstream chamber is recorded. This blank experiment is then subtracted from the permeation experiment performed immediately after in order to calculate the gas transport coefficients from the corrected pressure curves. In that way the pressure increase is related solely to the gas diffusing across the membrane. Pressure data are recorded every 5 s.

As there is a certain scatter of the experimental data, a large number of experiments were performed, and permeation measurements were done roughly every two degrees. Calculation of the transport coefficients was performed from the straight line characteristic of the steady state of gas diffusion through the membranes.

RESULTS AND DISCUSSION

Figure 1 shows the elastic modulus of [L.sub.CSPE] between -90[degrees]C and 100[degrees]C. A strong relaxation appears at roughly -20[degrees]C, corresponding to the soft chlorosulfonated polyethylene segments. After the relaxation, there is a continuous decrease of the elastic modulus, which makes it difficult to measure transport properties over 45[degrees]C, but no other relaxations up to 100[degrees]C can be seen.

P, D and S in the Temperature Range 20[degrees]C-45[degrees]C

The values of the permeability, diffusion and solubility (S=P/D) coefficients at 25[degrees]C are collected in Table 1. Figures 2 and 3 show the temperature evolution of the permeability and diffusivity coefficients in Arrhenius coordinates. At this moment, equipment shortcomings make it impossible to measure under 20[degrees]C, and owing to owing to
prep.
Because of; on account of: I couldn't attend, owing to illness.

owing to prepdebido a, por causa de 
 the material's mechanical properties, no measurements over 50[degrees]C were performed. Experimental measurements were thus limited to a small range, from 20[degrees]C to 45[degrees]C. In that range, Arrhenius behavior is followed by both permeation and diffusion coefficients.

As shown in Fig. 3, the activation energy of permeation for carbon dioxide is much smaller than for the other three gases because of the low value of the heat of solution [DELTA][H.sub.s]. The heat of solution can be either positive or negative, depending on the gas condensability con·dense  
v. con·densed, con·dens·ing, con·dens·es

v.tr.
1. To reduce the volume or compass of.

2. To make more concise; abridge or shorten.

3. Physics
a.
 and its ability to interact with the polymer. Among the gases tested, carbon dioxide has the lowext [DELTA][H.sub.s], and thus, as [E.sub.p] = [E.sub.d] + [DELTA][H.sub.s], the activation energy for this gas is the lowest. On the other hand, the solubility of [O.sub.2] and C[H.sub.4] varies little in that temperature range, whereas that of C[O.sub.2] diminishes clearly. This last behavior is characteristic of gases that interact with the polymer matrix, those bearing negative values of the heat of solution.

While oxygen, carbon dioxide, and methane measurements were quite straightforward in that little experimental dispersion of the data was found, nitrogen data are much more scattered and a great number of measurements were necessary to obtain reliable variations of the transport coefficients with temperature. The reason for this peculiar behavior of nitrogen is still unclear.

Permselectivity

Table 2 shows the results on permselectivity at 25[degrees]C and 1 atm. The experimental data are obtained by simply calculating the ratio of experimental permeabilities ([O.sub.2]/[N.sub.2] and [CO.sub.2]/[CH.sub.4]) measured at the same temperature. On the other, hand it is possible to define an experimental permselectivity equation [alpha]([O.sub.2]/[N.sub.2]) and [alpha]([CO.sub.2]/[CH.sub.4]), by dividing the permeation Arrhenius equations derived from the representations in Fig. 3:

[alpha](A/B) = [P.sub.0](A)/[P.sub.0](B) [e.sup.[-([E.sub.A] - [E.sub.B])/RT]] (1)

As in the case of [L.sub.PU], the negative temperature coefficients in the Arrhenius equations and the activation energy balance lead to a diminishing of both [alpha]([O.sub.2]/[N.sub.2]) [alpha]([CO.sub.2]/[CH.sub.4]) with temperature.

Minimum and maximum values of solubility selectivity reported in the literature (30) for the gas pair [O.sub.2]/[N.sub.2] are 0.1 and 3.7 respectively, while for diffusivity selectivity the values range from 1.1 to 8.6. [L.sub.CSPE] has a solubility selectivity at 25[degrees]C of 1.9 and a diffusivity selectivity of 2.3, i.e., solubility selectivity is slightly over the average but the diffusivity selectivity of this polymer is not very high, which is not surprising if it is considered that the rigidity of the chain segments of the binder must be very low. On the other hand, permeability is small because of crosslinking, and surprisingly, [L.sub.CSPE] and [L.sub.PU] show very similar diffusivity, solubility and permeability selectivities. The greatest differences are found in the values of permeability, which are about three times lower for the former than for the latter. This is due to the smaller diffusion coefficients, i.e., to the lower fractional free volume existing in the [L.sub.CSPE] system as compare d to that of [L.sub.PU].

Transport Coefficients in Relation to the Gas Nature and to the Polymer Structure

Correlations between the gas transport properties and the structure of the polymeric membranes have been described since the first half of the past century (6, 9, 10, 30-32). For example, it has been stated that the activation energy of diffusion frequently varies linearly with the square of the kinetic diameter of the gas:

[E.sub.d] = c[d.sup.2.sub.c] - f (2)

where c is a measure of flexibility and f of the separation between chains. This correlations holds for the data presented in this work, as shown in Fig. 4, and a value of c = 655 [calmol.sup.-1] [[Angstrom angstrom (ăng`strəm), abbr. Å, unit of length equal to 10−10 meter (0.0000000001 meter); it is used to measure the wavelengths of visible light and of other forms of electromagnetic radiation, such as ultraviolet ].sup.2] is found, which is characteristic of flexible polymers. [L.sub.PU], on the other hand, had a c = 1270 [calmol.sup.-1] [[Angstrom].sup.2], characteristic of a more rigid medium (9).

These parameters are in agreement with the chemical composition of both crosslinked systems. The different nature of the binder in both adhesives introduces important structural differences, as shown for example by the different mechanodynamical behavior of both samples. In [L.sub.CSPE], which can be considered an elastomer elastomer (ĭlăs`təmər), substance having to some extent the elastic properties of natural rubber. The term is sometimes used technically to distinguish synthetic rubbers and rubberlike plastics from natural rubber. , a strong relaxation related to the chlorosulfonated polyethylene appears at roughly -20[degrees]C. [L.sub.PU] has, on the other hand, a strong relaxation peaking at 70[degrees]C.

The higher density of [L.sub.CSPE] as compared to [L.sub.PU] is easy to explain, as the reactivity of the CSPE binder is greater than that of the aliphatic polyurethane. Both formulations have been polymerized up to limiting double bond conversion (around 65%-70%), which means that both possess the same degree of polymerization The degree of polymerization, or DP, is the number of repeat units in an average polymer chain at time t in a polymerization reaction [1]. The length is in monomer units. The degree of polymerization is a measure of molecular weight.  of the acrylic monomer. But given that both formulations include only monofunctional monomers, crosslinking reactions can only take place through a coupling reaction of a growing acrylic macroradical with a reactive site of the binder. As shown in Scheme 2 in the case of [L.sub.CSPE], three different reactions can lead to reactive sites in the binder structure: (a) direct photolysis photolysis

Breakdown of molecules into smaller units via absorption of light. Flash photolysis, an experimental technique developed by Manfred Eigen, Ronald George Weyford Norrish, and George Porter, studies short-lived chemical intermediates formed in many photochemical
 of the C-C1 bond of the binder, given its high photochemical lability lability /la·bil·i·ty/ (lah-bil´i-te)
1. the quality of being labile.

2. in psychiatry, emotional instability.


lability

the quality of being labile.
, (b) direct photolysis of the chlorosulfonic group and (c) direct hydrogen atom abstraction in the binder chain by the photoinitiator radicals.

In all cases, radical centers are efficiently formed in the binder chain, which can couple with the growing methacrylic radical, giving a certain degree of crosslinking for the same degree of polymerization. Full analysis of the photocuring reaction has been recently described (33) and the role played by the photoinitiator and the binder is discussed therein.

As mentioned earlier, the binder of [L.sub.CSPE] is a chlorosulfonated polyethylene similar to Hypalon 40. A comparison of this elastomer and our polymeric system, which is crosslinked using a mixture of acrylic and methacrylic monomers, appears interesting. In the last decade, various studies on the properties of special rubbers have appeared (34-37), and among them studies including Hypalon 40. As an example, Table 3 shows the permselectivities and the solubility and diffusivity selectivities for a series of commercial elastomers, together with the permeability of oxygen. Butyl rubber and Hypalon 40 are very similar in all three selectivities and differ clearly from the rest of elastomers, and in fact, the permselectivity data for our sample is very similar to that of Hypalon 40. While at 35[degrees]C most of the rubbers show permselectivites in the range 2-3, those of butyl rubber, Hypalon 40 and [L.sub.CSPE] are near 4. In this adhesive, up to 52% by weight is methyl methacxylate. However, comparison to P MMA (Microcomputer Managers Association, Inc.) A membership organization with chapters throughout the U.S. that was devoted to educating personnel responsible for personal computers. It disbanded in 1996.

Mma - A fast Mathematica-like system, in Allegro CL by R. Fateman, 1991.
 gas transport coefficients (Table 3) shows that our sample's properties have very little to do with those of PMMA PMMA polymethyl methacrylate. . It seems that even if a 52% by weight is PMMA, this does not strongly affect the diffusion properties. The methacrylic monomers initiate their polymerization at the radicals generated on the chlorosulfonated polyethylene chain. As they are monofunctional monomers, they grow linearly and terminate when they find other radicals, i.e., very probably on the chiorosulfonated polyethylene. Apparently, while the binder retains some of its properties in the final crosslinked network this is not the case for the growing methacrylic polymer. This is in agreement with the absence of a PMMA glass transition in the DMTA spectrum (Fig. 1), and the coincidence of the relaxation observed at -20[degrees]C with that of Hypalon 40 (37). In fact, the effect of the polymerized methacrylic monomers on the transport properties seems to be rather that of a filler. As a comparison, for example, Hydrin (one of the ela stomers in Table 3) has on its own a permeability to oxygen of 1.05 barrer, and with a filler It decreases to 0.31 (37).

Table 4 lists the activation energies for diffusion and permeation, and the solution enthalpy enthalpy (ĕn`thălpē), measure of the heat content of a chemical or physical system; it is a quantity derived from the heat and work relations studied in thermodynamics.  as obtained from the Van't Hoff relation. Figure 5 is a plot of these three magnitudes as a function of the critical temperature of each gas for both crosslinked systems. In Fig. 6 the heats of solution for [L.sub.CSPE] and [L.sub.PU] appear, together with the data for a polyimide Pronounced "poly-ih-mid." A type of plastic (a synthetic polymeric resin) originally developed by DuPont that is very durable, easy to machine and can handle very high temperatures. Polyimide is also highly insulative and does not contaminate its surroundings (does not outgas).  from the literature (32). All three magnitudes follow similar trends in both adhesives, and the diffusion data of the two polymers obey the well-known linear free energy relation (10), as shown in Fig. 7.

The greatest difference in the results depicted in Fig. 5 is perhaps seen in the values of the heat of solution of the four gases in [L.sub.CSPE], which are lower than in [L.sub.PU], implying stronger interactions and lower heat of mixing between the gases and the polymer matrix. On the other hand, the smaller diffusion coefficients in [L.sub.CSPE] and the higher [E.sub.d], especially for oxygen and nitrogen, imply a denser structure in [L.sub.CSPE] than in [L.sub.PU]. In this connection, other authors (37) have pointed out that Hypalon 40 is, among the elastomers, one with a closely packed structure, which may account for the observations on the diffusion data (actual values and activation energies) found for [L.sub.CSPE].

The values of the transport coefficients in both adhesives indicate i) that specific chemical interactions are taking place in [L.sub.CSPE] that do not exist in [L.sub.PU], ii) that the free volume is higher in the latter and iii) that the chlorosulfonated polyethylene binder introduces flexibility and a higher density as compared with the aliphatic polyurethane. All these observations are in accordance with what we know about the chemical composition, microstructure mi·cro·struc·ture  
n.
The structure of an organism or object as revealed through microscopic examination.


microstructure
Noun

a structure on a microscopic scale, such as that of a metal or a cell
 and morphology of these materials.

[FIGURE 1 OMITTED]

[FIGURE 2 OMITTED]

[FIGURE 3 OMITTED]

[FIGURE 4 OMITTED]

[FIGURE 5 OMITTED]

[FIGURE 6 OMITTED]

[FIGURE 7 OMITTED]
Table 1

Solubility, Permeability and Diffusivity Coefficients at 25[degrees]C
and 1 atm.

                           [O.sub.2]  [N.sub.2]  [CH.sub.4]  [CO.sub.2]

P (barrer)                  0.33       0.07        0.21        2.56
D*[10.sup.8] ([cm.sup.2]*   1.42       0.61        0.52        0.65
 [s.sup.-1]
S*[10.sup.4] [cm.sup.3]
 (STP)*[cm.sup.-3]*cm
 H[g.sup.-1]               24         13          40         394

1 barrer = [cm.sup.3] (STP) cm/[cm.sup.2] s cmHg X [10.sup.-10]
Table 2

Diffusivity, Solubility and Permeability Selectivity of [L.sub.CSPE].

Selectivity          [O.sub.2]/  [CO.sub.2]/  [N.sub.2]/
                     [N.sub.2]   [CH.sub.4]   [CH.sub.4]

[P.sub.1]/[P.sub.2]  4, 6           12.2         0.5
[D.sub.1]/[D.sub.2]     2.3          1.2         1.6
[S.sub.1]/[S.sub.2]     1.9          9.8         0.3
Table 3

Permselectivity, Solubility and Diffusivity of Commercial Elastomers
(37) and Commercial PMMA (3) at 35[degrees]C.

Polymer       P([O.sub.2])/  P([O.sub.2])  D([O.sub.2])/  S([O.sub.2])/
              P([N.sub.2])     (barrer)    D([N.sub.2])   S([N.sub.2])

Butyl rubber      3.80           2.89          1.90           2.01
Hypalon 40        3.80           2.37          2.08           1.81
Hypalon 45        3.30           4.20          1.41           2.30
Hydrin 100        2.30           1.05          1.80           1.33
Neoprene          2.97           8.83          1.90           1.57
ENR 76         2,22             10.90          1.29           1.72
EPDM              2.54          21.14          1.60           1.56
Kraton G1652      2.7           26.60          1.63           1.67
PMMA              7.8            0.06          5.01           1.55
[L.sub.CSPE]      3.8            0.33          1.9            2.0
Table 4

Activation Energy and Pre-exponential Factors of the Arrhenius
Temperature Dependence of the Permeability and Diffusivity Coefficients.

                                 [O.sub.2]  [N.sub.2]  [CH.sub.4]

[E.sub.d] [kJmol.sup.-1]           46.6       55           52
[E.sub.p] [kJmol.sup.-1]           46         57.7         49
[DELTA][H.sub.s] [kJmol.sup.-1]    -0.6        2.8         -6
[D.sub.0] [cm.sup.2][s.sup.-1]      2.6       37            6.8
[P.sub.0] barrer*[10.sup.-7]        5        147.2          8.6

                                 [CO.sub.2]

[E.sub.d] [kJmol.sup.-1]            44
[E.sub.p] [kJmol.sup.-1]            24.3
[DELTA][H.sub.s] [kJmol.sup.-1]    -19.6
[D.sub.0] [cm.sup.2][s.sup.-1]       0.33
[P.sub.0] barrer*[10.sup.-7]         0.048


ACKNOWLEDGMENT

We acknowledge financial support from the Consejeria de Cultura de la Communidad de Madrid (07M/0069/1998) and from the EU (BE97-4472).

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A large molecule composed of thousands of atoms.

Mentioned in: Gene Therapy

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P. TIEMBLO (*)

(*) Corresponding author. E-mail: ptiemblo@ictp.csic.es.
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Author:Tiemblo, P.; Guzman, J.; Riande, E.; Fernandez, A.; Bosch, P.
Publication:Polymer Engineering and Science
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Date:Jun 1, 2002
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