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Dye sublimation printing: durable color decoration for 3D parts.


Dye sublimation sublimation, in chemistry
sublimation (sŭblĭmā`shən), change of a solid substance directly to a vapor without first passing through the liquid state.
, a dye-transfer process The dye transfer process is a continuous-tone color photographic printing process, popularized by the Eastman Kodak Company in the 1940s. It is sometimes referred to by such generic names as wash-off relief printing and dye imbibition transfer printing.  that got its start in the 1960s for use in textiles, has advanced in recent years to provide wear-resistant, full-color surface decoration of flat objects like mouse pads and tiles. Even more recently, it has proved applicable to three-dimensional products.

Developed by Kolorfusion International, Inc., the technology allows for transfer of a full spectrum of colors, shades, and designs to a variety of surfaces, including plastics, metals and glass. The company holds the process patents for the 3D decorating technology, which it uses for custom decorating and also licenses to others.

Applicable to any shape or size of part, the process requires no special tooling. It causes dyes to penetrate the surface of the polymer so that the impregnated im·preg·nate  
tr.v. im·preg·nat·ed, im·preg·nat·ing, im·preg·nates
1. To make pregnant; inseminate.

2. To fertilize (an ovum, for example).

3.
 images are highly resistant to wear. Kolorfusion can supply clear coatings for further protection. According to according to
prep.
1. As stated or indicated by; on the authority of: according to historians.

2. In keeping with: according to instructions.

3.
 company president Steve Nagelle, the dyes and coatings have shown superb durability and uv resistance in commercial plastics products such as archery bows, gun stocks, all-terrain vehicle all-ter·rain vehicle  
n. Abbr. ATV
A small, open motor vehicle having one seat and three or more wheels fitted with large tires. It is designed chiefly for recreational use over roadless, rugged terrain.
 (ATV (1) (Advanced TV) An early name for the digital TV standard proposed by the Advisory Committee on Advanced Television Service (ACATS). See ACATS. See also ATV Forum.

(2) (Analog TV) Refers to the NTSC, PAL and SECAM analog TV standads.
) components, bottle chillers, cooling canisters, snowboards, flashlights, and sunglasses clips.

The process is poised for wider application with the recent start-up in Shenzhen, China, of Kolorfusion's second decorating facility and with Kolorfusion's new marketing alliance with DuPont Engineering Polymers. DuPont's PBT PBT Provider Backbone Transport (networking technology adding determinism to ethernet)
PBT Polybutylene Terephthalate
PBT Profit Before Tax
PBT Paper Based Test (education) 
, PET, acetal acetal /ac·e·tal/ (as´e-t'l)
1. any of a class of organic compounds formed by combination of an aldehyde molecule and two alcohol molecules.

2.
, and nylon resins are among those that are suited to the process. Such engineering resins provide new opportunities for the process in consumer electronics, power tools, appliances, sporting goods Noun 1. sporting goods - sports equipment sold as a commodity
commodity, trade good, good - articles of commerce

sports equipment - equipment needed to participate in a particular sport
, and automotive components.

How it works

When the dyes are heated in this transfer process, they vaporize va·por·ize
v.
To convert or be converted into a vapor.


Vaporize
To dissolve solid material or convert it into smoke or gas.
, and if they are in close proximity to a suitable substrate, such as a plastic or coating, the vapors penetrate the adjacent substrate by around 0.002 in. up to 0.25 in. The plastic substrate must be able to withstand temperatures of 280 to 375 F necessary to vaporize the dye.

Since the dyes are transparent, the substrate should be light in color--white, light gray, or beige. If the plastic substrate is translucent, it will remain translucent after coloring. "The lighter the substrate color, the better the result of this process," Nagelle says. He adds that the dyes will penetrate a black substrate but will not be visible.

When first used in textiles, this process allowed a printer to make a design on paper and then heat transfer it to knits or weaves. Explains Nagelle, "For flat-surface decoration such as snowboards, the design is first printed on paper, and then a hot press impregnates the paper design into the substrate." For 3D decoration, Kolorfusion typically prints the design on an air permeable and flexible textile-based medium called Kolortex. This is then placed around the object, which is put into a high-temperature film bag from which the air is pulled, forcing the textile to tighten around the substrate. The vacuum bag with the part is then placed in an oven for 5 to 40 min.

"We can now make digital designs and transfer them onto the part. If a user provides us with a design, we can can the design digitally or receive it electronically and then use ink-jet technology to print the image onto Kolortex and transfer it onto the part," Nagelle notes.

He says the process was developed as an alternative to the dipping process developed by Cubic Printing of Japan and licensed to others for about 20 years. That method involves floating a preprinted film on a pool of liquid, allowing the film to dissolve and leaving a floating layer of inks into which the substrate is dipped. "This is a very expensive process and not as durable as dye sublimation, as it does not penetrate the part. Compared with the dip process, we are anywhere from 20% to 40% lower in cost," explains Nagelle.

The Kolorfusion process boasts several other advantages over the dip process. It does not require robotics, an artisan, or special training or fixturing. "Ours is a non-skilled, easy process whose cycle time depends on the substrate and size of the object. Typically our process can take from as little as 3 min up to 40 min. Its suitability will depend on how much capacity you need: You need more people for loading and unloading when you have large volumes and larger part areas to decorate. In general, the process is well suited to smaller volumes and to manufacturing in Asia where labor costs are lower."

Any shape or size

Initially, Kolorfusion aimed its process at outdoor applications such as archery and gun components and ATVs. With the DuPont alliance and the new China plant, Kolorfusion's aim is to use its process on plastic components from automotive to consumer electronics. Says Nagelle, "This could include a woodgrain look on side panels or on instrument panels or around gearshift consoles, where we would replace laminates. Consumer appliances, computer cases, or even cell phones, where film-insert molding and dip coating are used, are other areas that look promising because of the new China facility."

The largest plastic part decorated thus far is the 4 x 7 ft TPO (Twisted Pair Only) Refers to the use of twisted pair wire when other options are available. For example, a TPO suffix at the end of 3com Ethernet adapter model numbers indicates the card has only an RJ45 connector.  cab on the Polaris Ranger ATV from Polaris Industries Polaris Industries manufactures a full line of all-terrain vehicles (ATV), snowmobiles, Ranger utility vehicles in 2wd, 4wd or 6wd, Victory Motorcycles and EU rated quadcycles. Polaris no longer manufactures personal water craft or sportboats. Based in Medina, Minnesota. , Plymouth, Mich. Since early 2003, Kolorfusion has been printing "miles of Kolortex" for this application, says Nagelle. Polaris precoats the plastic part to reduce the gloss, applies the dye-sublimation process, and follows that with a clear topcoat for extra uv protection.

Daisy Air Rifle Co., Rogers, Arkansas
For the surrounding metropolitan area (Northwest Arkansas) see Fayetteville-Springdale-Rogers metropolitan area
Rogers is a suburban city in Benton County, Arkansas, United States.
, opted for dye sublimation to replace the dip process for a camouflage decoration on the stock and forearm of one of its lines of air rifles. Daisy had to change the plastic from the original ABS, which would not withstand the Kolorfusion process temperatures, to a modified nylon. While the material cost almost doubled, Daisy says the lower cost of decorating with dye sublimation completely offset the increase in material costs.

Caddy A plastic container that holds a CD or DVD disc for added protection. The bare disc is placed in the caddy, and the caddy is inserted into the drive. A caddy is not a jewel case. A jewel case protects the disc for transportation. A caddy protects the disc while reading and writing.  Yo in Irvine, Calif., and PEK PEK Polyetherketone
PEK Beijing, China - Peking Capital Airport (Airport Code)
PEK Punctate Epithelial Keratopathy
 Systems in Windsor, Calif., have evaluated the Kolorfusion process to decorate bottle chillers and cooling canisters, respectively. Both companies are now aiming to produce these in China.

Archery equipment manufacturer Excalibur of Winnipeg, Manitoba, makes one of its crossbow models out of nylon, which is then decorated with dye sublimation. It also has a liquid polyurethane top-coat to provide a matte finish. This model uses a thermoset A polymer-based liquid or powder that becomes solid when heated, placed under pressure, treated with a chemical or via radiation. The curing process creates a chemical bond that, unlike a thermoplastic, prevents the material from being remelted. See thermoplastic.  fiberglass composite for the "limbs," which are also decorated with the Kolorfusion process.
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No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2005, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Title Annotation:Close-Up: DECORATING
Author:Sherman, Lilli Manolis
Publication:Plastics Technology
Date:Sep 1, 2005
Words:1054
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