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Computer modeling of wire and cable extrusion.


Many extrusion process engineers never get the opportunity to design an extruder screw, given that prices for custom-made replacements can rival the cost of a new SUV. Improved screw designs for wire and cable extrusion have typically come from extruder equipment manufacturers or polymer compound suppliers, whose main focus has been on pelletized plastics. Over the past 35 years, a variety of screw designs for plastics extrusion Plastics extrusion is a high volume manufacturing process in which raw plastic material is melted and formed into a continuous profile. Extrusion produces items such as pipe/tubing, weather stripping, window frames, plastic sheeting, adhesive tape and wire insulation.  have been developed and marketed, typically centered around the classic metering-type geometry with a deep feed section, tapered ta·per  
n.
1. A small or very slender candle.

2. A long wax-coated wick used to light candles or gas lamps.

3. A source of feeble light.

4.
a.
 transition section and shallow metering section. Most of the design effort has focused on improving mixing by various means, ranging from simple mixing pins imbedded imbedded,
adj See embedded.
 in the screw channel to a fluted mixing section attached to the discharge end of the screw. Other types, such as barrier flight screws, compression-relief and two-stage designs have been used, each with varying degrees of success.

Rubber extruder screw design, by comparison, has received relatively little attention. Generally speaking, rubber screws fall into two categories, including the traditional constant channel depth, varying pitch, double-flighted design and the constant pitch, varying channel depth, double-flighted metering type design. Intensive shear mixing sections are usually not employed on wire and cable rubber extruders, as the high discharge pressures Discharge pressure (also called high side pressure or head pressure) is the pressure generated on the output side of a gas compressor in a refrigeration or air conditioning system.  and compound viscosities commonly seen would lead to excessive extrudate temperatures. And since the processing of strip-fed rubber normally requires a double-flighted screw for proper feeding, the potential design variables here are fairly constrained con·strain  
tr.v. con·strained, con·strain·ing, con·strains
1. To compel by physical, moral, or circumstantial force; oblige: felt constrained to object. See Synonyms at force.

2.
.

Many processors have put their efforts into developing pelletized versions of their rubber compounds. However, this usually involves adding plastics, mineral fillers or other materials which "stiffen stiff·en  
tr. & intr.v. stiff·ened, stiff·en·ing, stiff·ens
To make or become stiff or stiffer.



stiff
" the formulation to facilitate pelletizing Pelletizing or pelletising is the process of compressed or molding of product into the shape of a pellet. A large range of different products are pelletized including chemicals, iron ore, animal compound feed, and more. . These additives often have an undesirable effect on the physical characteristics of the final product. Also, the material may still not be suitable for bulk storage and handling and may not feed well at the extruder. Rubber-insulated wire and cable producers often find it necessary to just live with the inconveniences associated with strip fed materials.

Although there are a number of commercially-available computer programs for modeling pelletized plastics extrusion, which can be of great utility in screw design, the cost of the software and the effort and expense required to obtain the numerous compound flow and frictional variables necessary to run the programs tend to deter many processors, particularly the smaller ones. The author's own experience with these programs is that they can provide valuable information regarding the relative effects changes in screw geometry and/or compound characteristics will have on the process. However, absolute accuracy in terms of predicting extruder output, extrudate temperature, stability or degree of mixing is not possible, for a number of reasons which will be discussed later. Most extrusion process engineers find such programs interesting and fairly useful for understanding extrusion, but not as tools suitable for frequent use in day-to-day problem-solving. And pelletized plastic extrusion models do not work very well when applied to rubber (and strip-fed rubber in particular).

When dealing with strip-fed rubber materials, a different approach is required. As it turns out, many of the problems associated with modeling plastics extrusion are not encountered with rubber. However, rubber compounds tend to have some more complex rheological rhe·ol·o·gy  
n.
The study of the deformation and flow of matter.



rheo·log
 characteristics which must be taken into account. In order to understand the rubber extrusion process, one invariably in·var·i·a·ble  
adj.
Not changing or subject to change; constant.



in·vari·a·bil
 has to make some comparisons to plastics extrusion.

Polymer rheology and melt conveying models

Plastics and rubbers both behave as non-Newtonian fluids when heated to a fluid state and forced to flow. Where Newtonian fluids such as water or mineral oil exhibit a linear relationship between shear stress shear stress
n.
See shear.



shear stress

A form of stress that subjects an object to which force is applied to skew, tending to cause shear strain.
 [tau] and shear rate Shear rate is a measure of the rate of shear deformation:



For the simple shear case, it is just a gradient of velocity in a flowing material.
 [gamma] (i.e., their viscosity does not change with shear rate), the types of polymers used in wire and cable insulations exhibit a non-linear relationship--their viscosity decreases as shear rate increases. However, when a plot of log [tau] versus log [gamma] remains linear over a substantial range, the polymer may be classified as a simple "power law" fluid whose behavior can be defined by the Ostwald and de Waele flow model (ref. 1):

(1) [tau] = m x [[gamma].sup.n]

where m is defined as the flow consistency (viscosity) and n is the flow index. Equation 1 reduces to the Newtonian case when n = 1.

While the plastics used in wire and cable can often be treated as simple power law fluids, many of the rubber compounds cannot. In addition to the viscosity varying with shear rate, the flow index of a typical synthetic rubber synthetic rubber: see rubber.  compound also varies significantly with shear rate, further complicating the mathematical model
Note: The term model has a different meaning in model theory, a branch of mathematical logic. An artifact which is used to illustrate a mathematical idea is also called a mathematical model and this usage is the reverse of the sense explained below.
. However, all of the flow parameters needed for a rubber extrusion model can be readily obtained using a capillary capillary (kăp`əlĕr'ē), microscopic blood vessel, smallest unit of the circulatory system. Capillaries form a network of tiny tubes throughout the body, connecting arterioles (smallest arteries) and venules (smallest veins).  rheometer rhe·om·e·ter
n.
An instrument for measuring the flow of viscous liquids, such as blood.
, typically a simple die arrangement attached to a common Brabender lab extruder. By extruding and weighing samples of material at different pressures, the apparent shear rate [[gamma].sub.a] and apparent shear stress [[tau].sub.a] can be determined using the equations:

(2) [[tau].sub.a] = [DELTA]P R/2L

and (3) [[gamma].sub.a] = 4q/[pi][R.sup.3]

where R and L are the die radius and die length, [DELTA]P is the driving pressure, and q is the volumetric flow rate In fluid dynamics and hydrometry, the volumetric flow rate, also volume flow rate and rate of fluid flow, is the volume of fluid which passes through a given surface per unit time (for example cubic meters per second [m3 s-1 . The apparent viscosity [[mu].sub.a] is defined by the equation:

(4) [[mu].sub.a] = [pi][R.sub.4][DELTA]P/8qL

While it is normally assumed that the apparent shear stress is the true shear stress at the wall, die entrance and exit effects can introduce an error in determining the true pressure gradient In atmospheric sciences (meteorology, climatology and related fields), the pressure gradient (typically of air, more generally of any fluid) is a physical quantity that describes in which direction and at what rate the pressure changes the most rapidly around a particular location. . Several texts have shown a means of correcting for these effects (ref. 2).

The true shear rate at the wall is defined by the Mooney-Rabinowitsch

Rabinowitsch equation:

(5) [[gamma].sub.t] = [[gamma].sub.a] [3n' + 1 / 4n']

where, for true power law fluids, n' = n. Since most polymers, and robbers in particular, have non-constant power indices, it is necessary to confine laboratory measurements to narrow windows of shear rates at several points over the expected range of shear rates one expects to encounter in the extrusion process. When using the data for extruder process modeling, however, one has to account for the large differences between screw channel and flight clearance shear rates, and it becomes necessary to develop a mathematical model of the change in shear index with shear rate from the rheological data.

A capillary die rheometer is also useful in determining a polymer's thermal sensitivity thermal sensitivity,
n See sensitivity, tooth.
. At any constant shear rate, the viscosity-temperature relationship is defined by the equation

(6) [mu] = [[mu].sub.o] exp exp
abbr.
1. exponent

2. exponential
[[a.sup.*](T - [T.sub.o])]

or alternatively

(7) m =[m.sub.o] exp[[a.sup.*](T - [T.sub.o])]

where [m.sub.o] is the apparent viscosity at T = [T.sub.o] and [gamma] = 1.

The temperature sensitivity factor [a.sup.*] defines how a material's viscosity changes with temperature. Plastics, especially the more crystalline types, tend to have much larger values for [a.sup.*] and are, therefore, more sensitive to spatial temperature gradients temperature gradient
n.
The rate of change of temperature with displacement in a given direction from a given reference point.



temperature gradient 
 within a flow channel. Rubber compounds, on the other hand, tend to exhibit smaller values for [a.sup.*], making their viscosity far less sensitive to temperature variations.

In the classical Newtonian superposition su·per·po·si·tion  
n.
1. The act of superposing or the state of being superposed: "Yet another technique in the forensic specialist's repertoire is photo superposition" 
 theory, isothermal i·so·ther·mal
adj.
Of, relating to, or indicating equal or constant temperatures.



isothermal, isothermic

having the same temperature.
 conditions are assumed, and the reduction in output due to back pressure is accounted for by the concept of a negative pressure flow up the extruder channel which opposes the down-channel drag flow imparted by the relative barrel to screw velocities. This concept is presented as:

Q (net flow rate) = [Q.sub.d] (drag flow) minus [Q.sub.p] (pressure flow)

Making the appropriate accommodations for screw geometry, the output equation becomes (ref. 3):

(8) Q = [F.sub.d][[pi].sup.2][D.sup.2]Nh(1- b/t)sin[phi]cos[phi]/2 - [F.sub.p][pi]D[h.sup.3] (1-pb/t)[sin.sup.2][phi][DELTA]P/12[mu][L.sub.m]

where [F.sub.d] and [F.sub.p] are drag and pressure flow shape factors to correct for the fact that more polymer melt will flow through a channel which is almost full than one which is completely full and D = barrel diameter; N = screw speed in RPMs; h = screw channel depth; p = number of flights; b = flight width; t = flight lead length; [phi] = helix Helix - A hardware description language from Silvar-Lisco.  angle of screw flights; [L.sub.m] = effective length of melt conveying section; and [mu] = melt viscosity.

Applying the above Newtonian analysis to almost any plastic or rubber extruder will yield results which grossly over-estimate the machine's output. Since the output of an extruder is the integral of the fluid velocity profile over the depth of the channel times the width of the channel, the equations for down-channel and cross-channel flow must be solved simultaneously by numerical iteration One repetition of a sequence of instructions or events. For example, in a program loop, one iteration is once through the instructions in the loop. See iterative development.

(programming) iteration - Repetition of a sequence of instructions.
 on a computer. Using the Runge-Kutta method as employed by Griffith (ref. 4), a graph of the reduced flow rate due to non-Newtonian behavior versus a dimensionless pressure gradient may be constructed. Figure 1 shows the ratio of the actual output rate, Q, to the calculated value of the Newtonian drag flow rate, [Q.sub.d], plotted against a dimensionless pressure gradient [G.sub.2]/cos[phi], where [G.sub.z] is defined by the equation:

[G.sub.z] = [h.sup.n+1]/m[([pi]DN/60).sup.n] [differential]P/[differential]z

where

(9) [differential]P/[differential]z [equivalent to] [DELTA]P sin[phi]/[L.sub.m]

The curves in figure 1 were plotted for a relatively narrow range of helix angle values, and isothermal conditions were assumed. While application of the isothermal approximation to a wide variety of polymers may not be appropriate, it is generally applicable to the rubber insulating and jacketing materials used in wire and cable products. The typically smaller values for [a.sup.*] common to most rubber compounds (as compared to plastics), along with the smaller barrel-screw temperature differences employed in rubber extrusion justify assuming isothermal conditions for calculating flow rates in the melt conveying zone (ref. 5).

[FIGURE 1 OMITTED]

Although this type of numerical analysis numerical analysis

Branch of applied mathematics that studies methods for solving complicated equations using arithmetic operations, often so complex that they require a computer, to approximate the processes of analysis (i.e., calculus).
 is employed in various plastics extrusion models, it can only simulate what takes place in an extruder after the polymer is completely melted. The pelletized plastic extrusion process is, however, much more complicated. As melting of pellets begins to take place in the middle, transition zone of a plastics extruder, a pool of melt forms in the rear of the screw channel as a result of screw geometry. Ideally, and in a properly designed screw, this pool remains segregated from the unmelted pellets, gradually growing in size as material progresses down the channel. By the time it reaches the discharge end of the screw, the melt pool has completely replaced the solid plug of plastic pellets and is thermally homogenized ho·mog·e·nize  
v. ho·mog·e·nized, ho·mog·e·niz·ing, ho·mog·e·niz·es

v.tr.
1. To make homogeneous.

2.
a. To reduce to particles and disperse throughout a fluid.

b.
.

Unfortunately, this does not always take place in many plastics extruders. Extruders with poorly-designed screws can exhibit random and premature break-up of the solid plug, allowing the unmelted pellets to become dispersed in the melt pool, rather than remaining segregated from it. This is a primary cause of poor thermal mixing and output instability (surging) in plastics extruders. In common practice, the problem is addressed by screw cooling, which tends to stabilize the solid plug and prevent premature breakup breakup

The division of a company into separate parts. The most famous breakup to date was the 1984 division of AT&T (formerly, American Telephone & Telegraph Company). This breakup was intended to increase competition in the communications industry.
, and by the use of mixing devices, which add energy to help complete melting and thermally homogenize homogenize /ho·mog·e·nize/ (ho-moj´in-iz) to render homogeneous.

homogenize

to convert into material that is of uniform quality or consistency throughout; to render homogeneous.
 the melt prior to discharge.

The melting mechanism is very difficult to model, particularly as it applies to predicting heat transfer within the rotating melt pool, spatial segregation of the melt pool from the solid pellet pel·let
n.
1. A small pill; a pilule.

2. A small rod-shaped or ovoid mass, as of compressed steroid hormones, intended for subcutaneous implantation in body tissues to provide timed release over an extended period of time.
 plug, and breakup and mixing of the solid pellet plug. The strip-fed rubber extrusion process is much simpler to model, in this respect, since this melt pool/unmelted pellet segregation mechanism is not a factor. The rubber essentially goes from being a solid plug to a sheared sheared  
adj.
Shaped or finished by shearing, especially cut or trimmed to a uniform length: a sheared fur coat.

Adj. 1.
 fluid at some point in the process. Although there are ways to mathematically predict this, our own experience shows that including this analysis in a computer simulation is usually unnecessary, as the transition point can be estimated by empirical means.

Friction and the solids conveying mechanism

In both plastics and rubber extrusion, the transport mechanism of the solids conveying zone is treated as plug flow. In plug flow, the basic assumption is made that the polymer behaves as a solid, elastic mass, undergoing no internal shear, but slipping along the screw surface, dragged down-channel by friction with the extruder barrel. Figure 2a shows an idealized i·de·al·ize  
v. i·de·al·ized, i·de·al·iz·ing, i·de·al·iz·es

v.tr.
1. To regard as ideal.

2. To make or envision as ideal.

v.intr.
1.
 "unwrapped" model for the solids conveying mechanism. The upper plate, representing the barrel surface, moves with a velocity Vb across the screw channel at an angle equal to the helix angle [phi]. The plug slides down-channel with a velocity of Vp/sin [phi], where Vp is the axial axial /ax·i·al/ (ak´se-al) of or pertaining to the axis of a structure or part.

ax·i·al
adj.
1. Relating to or characterized by an axis; axile.

2.
 plug velocity. The angle [theta Theta

A measure of the rate of decline in the value of an option due to the passage of time. Theta can also be referred to as the time decay on the value of an option. If everything is held constant, then the option will lose value as time moves closer to the maturity of the option.
] is the angle of movement of the plug relative to the barrel. The volumetric volumetric /vol·u·met·ric/ (vol?u-met´rik) pertaining to or accompanied by measurement in volumes.

vol·u·met·ric
adj.
Of or relating to measurement by volume.
 throughput [Q.sub.s] is defined by the equation (ref. 6):

(10) [Q.sub.s] = [[pi].sup.2]NhD(D - h)[tan[phi] tan[theta]/tan[phi] + tan[theta]](1 - pb / [pi] (D - h) sin[phi])

The last term of the equation is a correction factor for flight width. The angle [theta] is a complex function of the screw geometry and friction that is too involved to discuss in this article. However, the term [tan[phi] tan[theta] / tan[phi] + tan[theta]] is a determining factor in the solids conveying rate, and is frequently shown plotted against the helix angle to illustrate the latter's effect on extruder feeding, as shown in figure 2b. The curves in 2b were plotted for a particular screw diameter and feed channel depth, and where [f.sub.s] (polymer coefficient of friction coefficient of friction
n. pl. coefficients of friction
The ratio of the force that maintains contact between an object and a surface and the frictional force that resists the motion of the object.
 with screw) equals [f.sub.b] (coefficient of friction with barrel). In practice, the values for [f.sub.s] and [f.sub.b] are almost never equal, given the differences in barrel and screw temperatures and relative surface velocities, and tend to change anyway as the material moves down-channel and internal extruder pressure develops.

[FIGURE 2 OMITTED]

Finding the right values for [f.sub.s] and [f.sub.b] can be problematic, even though laboratory instruments designed for testing solid polymer frictional properties are commercially available. Duplicating the exact roughness of extruder screw and barrel surfaces, pressure conditions and other factors is not possible, and the cost of such equipment can be prohibitive to management. An alternative is to measure the open discharge output of an extruder with a constant channel depth or low-compression screw and use these data to estimate the effective coefficients of friction. Although the accuracy may be limited, my experience has shown the data obtained in this manner to be useful for approximating the relative magnitude of change in solids conveying capacity that a change in screw geometry would cause.

In the days before computers facilitated feed rate and melt conveying capacity calculations, screw designers relied on simple rules of thumb to determine compression ratios compression ratio

Degree to which the fuel mixture in an internal-combustion engine is compressed before ignition. It is defined as the volume of the combustion chamber with the piston farthest out divided by the volume with the piston in the full-compression position (
, helix angles and channel depths. They recognized early-on that an extruder operating in a feed-restricted, or starved starve  
v. starved, starv·ing, starves

v.intr.
1. To suffer or die from extreme or prolonged lack of food.

2. Informal To be hungry.

3. To suffer from deprivation.
 condition (where the melt pumping capacity exceeds the feeding capacity) tends to surge badly. They also recognized that screws with excessive compression ratios had their own problems, such as bailing-up at the feed throat of a strip-fed rubber extruder, or pushing unmelted pellets through a pelletized plastic extruder. Since pelletized materials have about half the bulk density of strip-fed rubbers, plastic screws had to have higher compression ratios to compensate. The old 3:1 or 4:1 compression ratio for plastics and 2:1 or 2.5:1 ratio for strip-fed rubber still dominate the thinking of many screw designers, as does the practice of making the flight lead equal to the screw diameter for plastics, or one and a half times the diameter on a rubber screw.

Unfortunately, such designs may not be suitable for a particular material. Double-flighted rubber screws, in particular, may have output stability problems associated with their characteristically long flight leads. The helix angle for such screws is often outside the optimum range for solids conveying capacity, and a feed-restricted operating condition results.

Application to design and problem solving problem solving

Process involved in finding a solution to a problem. Many animals routinely solve problems of locomotion, food finding, and shelter through trial and error.
 

Many traditional rubber screw designs can allow the extruder to operate in a feed-restricted mode under certain operating conditions. As mentioned earlier, the larger helix angle common to double-flighted rubber screws is often the cause. This, coupled with the low compression ratios of most rubber screws, can make the output rate highly sensitive Adj. 1. highly sensitive - readily affected by various agents; "a highly sensitive explosive is easily exploded by a shock"; "a sensitive colloid is readily coagulated"  to ever-present feed rate fluctuations. The ramifications ramifications nplAuswirkungen pl  of feed-restricted operation are often observed in the extrusion of larger polymer cross sections where head pressures are low. Minor variations in compounding or mixing, or the amount of lubricant Lubricant

A gas, liquid, or solid used to prevent contact of parts in relative motion, and thereby reduce friction and wear. In many machines, cooling by the lubricant is equally important.
 used, can have a significant effect on extruder output rate or stability that cannot be explained by traditional laboratory tests, such as Mooney viscosity.

The dramatic effect of screw design on performance can best be illustrated by the cable diameter recording charts shown in figures 3a, 3b and 3c. In figure 3a, the recording instrument was located at a CV line where medium voltage, 500 MCM (MultiChip Module or MicroChip Module) A chip package that contains several bare chips mounted close together on a substrate (base) of some kind.  copper power cable was being insulated in·su·late  
tr.v. in·su·lat·ed, in·su·lat·ing, in·su·lates
1. To cause to be in a detached or isolated position. See Synonyms at isolate.

2.
 with a strip-fed EPDM rubber EPDM rubber (ethylene propylene diene monomer rubber) is an elastomer which is characterized by wide range of applications. EPDM rubber is used in vibrators and seals; glass-run channel; radiator, garden and appliance hose; tubing; washers; belts; and electrical insulation. . The severe surging in diameter being experienced could not be associated with machinery speed or temperature control. This line had a history of chronic output variability, and a recent run had shown a 20% drop in output when changing to a batch of rubber mixed with a slightly outside of normal lot of raw polymer. However, the Mooney viscosity of the rubber was well within specified tolerances, and other lab results were good.

[FIGURE 3 OMITTED]

In the particular run charted in figure 3a, lowering the extruder output rate had no effect on the surging. The line's 4-1/2" primary extruder had a metering type, constant pitch, double-flight screw design which worked well in other plant CV lines insulating smaller wire and cable constructions with higher head pressures. This suggested that the machine might be operating in a feed-restricted condition. Computer simulations of the melt conveying capacity also indicated this to be the case, yielding calculated theoretical output values that were significantly higher than what was actually being observed at the extruder.

From previous screw design efforts, it was known that simply increasing the screw's compression ratio by deepening the feed section of this basic design created feeding problems, while decreasing the metering section channel depth would cause unacceptable increases in melt temperature. As an alternative, a new screw was designed, retaining the existing channel depths, section lengths and compression ratio, but with a slightly shorter flight lead to give a helix angle that simulations said would increase the feed rate. The new design resulted in a significant improvement in output stability, as shown in figure 3b.

The output rate with the new screw was also 18-20% higher than with the old design, even though decreasing the flight lead reduced theoretical melt conveying capacity. The magnitude of the operating performance improvements was particularly surprising, given the slight (two or three degree) change in helix angle. In continuation of this initial design effort, additional work was conducted to improve extruder feeding characteristics and to optimize strip material frictional proper: ties.

Figure 3c illustrates the improved output stability achieved through these optimization efforts. In addition to the obvious savings gained through reduced material usage, the improved diameter control was critical to the quality of power cable products manufactured on the line, particularly those which required the application of an extruded insulation shield at a separate operation.

In the years since this development work, the author has encountered numerous instances of feed-related output variability in both strip-fed rubber and pelletized plastics. Computer models have been invaluable tools for predicting the effects of screw design, polymer compound rheological and frictional properties, and other process variables on rubber extruder performance. They have also been useful for developing a better understanding of the extrusion process for both rubber and plastics.

In addition to calculating extruder throughput, computer modeling can also predict extrudate temperatures and horsepower horsepower, unit of power in the English system of units. It is equal to 33,000 foot-pounds per minute or 550 foot-pounds per second or approximately 746 watts.  requirements for different screw designs under various operating conditions using the non-Newtonian flow analysis described above in combination with numerical heat transfer and power dissipation Dissipation
See also Debauchery.

Breitmann, Hans

lax indulger. [Am. Lit.: Hans Breitmann’s Ballads]

Burley, John

wasteful ne’er-do-well. [Br. Lit.
 analyses. Such programs calculate the energy added or removed though barrel/screw heating or cooling and frictional shear energy generated in the screw channel and the barrel/flight clearances. The absence of the complex plastics melting mechanism in rubber extrusion greatly simplifies the analysis and facilitates accuracy. The program used in the design of the improved rubber screw discussed here produced numbers which correlated exceptionally well with operating data from the extruder. Although the development of the software and associated laboratory work to quantify material rheological and frictional variables was very time-consuming and expensive, the improvements in output stability and material usage on just one CV line justified the investment.

Unfortunately, the competitive environment under which the wire and cable industry must operate tends to limit the resources available for such efforts today. Most domestic manufacturers find it necessary to focus their process engineering on supporting cost-cutting initiatives like Lean Manufacturing Lean manufacturing is the production of goods using less of everything compared to mass production: less human effort, less manufacturing space, less investment in tools, and less engineering time to develop a new product.  and Six-Sigma, often to the neglect of basic process design and development work.

References

(1.) Williams, D.J., Polymer Science Polymer science or macromolecular science is the subfield of materials science concerned with polymers, primarily synthetic polymers such as plastics. The field of polymer science includes researchers in multiple disciplines including chemistry, physics, and engineering.  and Engineering, pp. 353-355, Prentice-Hall, Inc., New Jersey, 1971.

(2.) ibid., p. 363.

(3.) Bernhardt, Earnest C., Ed., et. al., Processing of Thermoplastic Materials thermoplastic materials

materials used in making casts for broken limbs. Malleable when warmed in hot water or heated with a hairdrier, very quick setting and very strong, e.g. Hexcelite.
, p. 215, Van Nostrand Reinhold Publishing, New York New York, state, United States
New York, Middle Atlantic state of the United States. It is bordered by Vermont, Massachusetts, Connecticut, and the Atlantic Ocean (E), New Jersey and Pennsylvania (S), Lakes Erie and Ontario and the Canadian province of
, 1959.

(4.) Tadmor, Z. and Klein, I., Engineering Principles of Plasticating Extrusion, pp. 267-277, Van Nostrand Reinhold Publishing, New York, 1970.

(5.) Pearson, J.R.A., Mechanical Principles of Polymer Melt Processing, pp. 84-89, Pergamon Press, Oxford, 1965.

(6.) Tadmor, Z and Klein, I., Engineering Principles of Plasticating Extrusion, p. 57, Van Nostrand Reinhold Publishing, New York, 1970.

E. Alan McCaslin, consultant
COPYRIGHT 2005 Lippincott & Peto, Inc.
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2005, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Author:McCaslin, E. Alan
Publication:Rubber World
Date:Jul 1, 2005
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