Chemical rings act as a minirotor.Taking a step toward the creation of molecule-scale motors for equally tiny tasks, researchers have made rings of organic molecules on which one or two smaller chemical rings rotate like charms on a bracelet. In the version with two small rings, the scientists can control the direction of the rings' rotation. David A. Leigh of the University of Edinburgh (body, education) University of Edinburgh - A university in the centre of Scotland's capital. The University of Edinburgh has been promoting and setting standards in education for over 400 years. and his colleagues synthesized syn·the·sized adj. 1. Relating to or being an instrument whose sound is modified or augmented by a synthesizer. 2. Relating to or being compositions or a composition performed on synthesizers or synthesized instruments. the interlocking interlocking /in·ter·lock·ing/ (-lok´ing) closely joined, as by hooks or dovetails; locking into one another. interlocking Obstetrics A rare complication of vaginal delivery of twins; the 1st rings in solutions. Each large ring contains three or four different chemical groups, or stations, where the small rings are temporarily held in place by hydrogen bonding hydrogen bonding Interaction involving a hydrogen atom located between a pair of other atoms having a high affinity for electrons; such a bond is weaker than an ionic bond or covalent bond but stronger than van der Waals forces. . In the July 10 Nature, Leigh and his coworkers report that they can control the small rings' attraction to these stations using light, heat, or chemicals. In rotors with just one small ring--a molecular system called a [2]catenane--the researchers can direct the small ring to the station they choose. However, the team can't designate which direction the small ring will travel around the big ring. In a rotor rotor: see generator; motor, electric. with two small rings, called a [3]catenane A catenane is a mechanically-interlocked molecular architecture consisting of two or more interlocked macrocycles. The interlocked rings cannot be separated without breaking the covalent bonds of the macrocycles. Catenane is derived from the Latin catena meaning "chain". , each small ring blocks the other's movement backward on the big ring. The small rings therefore always move in the same direction. Many researchers are aiming to create molecular motors that can operate, for example, tiny valves, switches, pumps, and other parts in drug-delivery systems or in computer-chip-size laboratories (SN: 11/9/02,p.291). The new catenane structures could be used to make surfaces that change color, stickiness, and other properties depending on the relative positions of the rings, suggests Leigh.--J.G. |
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