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Bringing mold material thermophysical data up to speed: because of the ever-growing functionality of casting process modeling programs, mold material thermal input data have been evaluated and redefined.


With the rapid increase in advancements in physics-based mold mold, name for certain multicellular organisms of the various classes of the kingdom Fungi, characteristically having bodies composed of a cottony mycelium. The colors of molds are caused by the spores, which are borne on the mycelium.  filling and solidification so·lid·i·fy  
v. so·lid·i·fied, so·lid·i·fy·ing, so·lid·i·fies

v.tr.
1. To make solid, compact, or hard.

2. To make strong or united.

v.intr.
 simulation software Simulation software is based on the process of imitating a real phenomenon with a set of mathematical formulas. It is, essentially, a program that allows the user to observe an operation through simulation without actually running the program. , the need to bring material thermal properties up to speed has be come readily apparent. Constant advances in simulation technology have helped drive the increasing functionality and use of simulation tools, and thus, have placed a new emphasis on the quality" and accuracy of the current material property thermal datasets.

The generic thermal data for mold material commonly used is more than 20 years old. Not surprisingly, output data accuracy for simulation programs is severely affected by the inaccuracies in the mold material thermal input data. With all the changes in binder binder: see combine.


An earlier Microsoft Office workbook file that let users combine related documents from different Office applications. The documents could be viewed, saved, opened, e-mailed and printed as a group.
 technology and the advent of more sophisticated measurement devices, an obvious need to quantify Quantify - A performance analysis tool from Pure Software. , as accurately as possible, the thermal characteristics of several mold material types exists.

This article details the results of an evaluation of mold materials' thermal properties to establish a baseline The horizontal line to which the bottoms of lowercase characters (without descenders) are aligned. See typeface.

baseline - released version
 for the type of binder system and silica silica or silicon dioxide, chemical compound, SiO2. It is insoluble in water, slightly soluble in alkalies, and soluble in dilute hydrofluoric acid. Pure silica is colorless to white.  sand morphology morphology

In biology, the study of the size, shape, and structure of organisms in relation to some principle or generalization. Whereas anatomy describes the structure of organisms, morphology explains the shapes and arrangement of parts of organisms in terms of such
 specific to green sand and resin-bonded sand mold materials. The project focused on five different sand samples (Table 1), including chemically bonded urethane urethane (yoor´ithān´),
n ethyl carbamate used as an anesthetic agent for laboratory animals, formerly used as a hypnotic in humans.
 molding sand--core (CBUMS-C), chemically bonded urethane molding sand--mold (CBUMS-M), chemically bonded shell molding sand--mold (CBSMS-M), chemically bonded furan furan: see furfural.  molding sand--core (CBFMS-C), chemically bonded furan molding sand--mold (CBFMS-M), green sand machine molded mold 1  
n.
1. A hollow form or matrix for shaping a fluid or plastic substance.

2. A frame or model around or on which something is formed or shaped.

3. Something that is made in or shaped on a mold.
 (GS-MM) and green sand--high-pressure molding sand (Founding) a kind of sand containing clay, used in making molds.

See also: Molding
 (GS-HPMS).

Getting Started

In general, the thermal property database for cast metals appears to be accurate and growing daily. Likewise, thermal properties for insulating and exothermic exothermic /exo·ther·mic/ (-ther´mik) marked or accompanied by evolution of heat; liberating heat or energy.

ex·o·ther·mic or ex·o·ther·mal
adj.
1.
 riser sleeves have been developed in recent years and also appear to be accurate. Thermal properties for mold materials, on the other hand, have not been evaluated in decades. Extensive measurements were made between 1950 and 1985, and a significant array of mold material thermal properties has been documented. But recent work has shown that old information may underestimate the thermal heat transfer of some molding materials.

In general, it is recommended that metalcasting facilities test their specific molding media composition for thermal properties to obtain the most accurate dataset See data set.  particular to their respective operation. However, that is not always practical, so a need exists to define a new, more accurate set of general thermal properties for various molding materials.

Method of Analysis

Specific heat test measurements were performed using the Bunsen Ice Calorimeter calorimeter: see calorimetry.
calorimeter

Device for measuring heat produced during a mechanical, electrical, or chemical reaction and for calculating the heat capacity of materials.
. Density values, as a function of temperature, were obtained from thermal expansion thermal expansion

Increase in volume of a material as its temperature is increased, usually expressed as a fractional change in dimensions per unit temperature change.
 measurements of the mold material sample and mass change data (as determined from the specific heat measurements). The measurements were made in a dilatometer dil·a·tom·e·ter  
n.
An instrument used to measure thermal expansion and dilation in solids and liquids.



[dilate + -meter.
.

Thermal diffusivity In heat transfer analysis, thermal diffusivity (symbol: ) is the ratio of thermal conductivity to volumetric heat capacity.

 measurements were then performed by the laser flash instrument. Thermal diffusivity was calculated as a relation of this function and specimen SPECIMEN. A sample; a part of something by which the other may be known.
     2. The act of congress of July 4, 1836, section 6, requires the inventor or discoverer of an invention or discovery to accompany his petition and specification for a patent with specimens
 thickness.

Sampling guidelines guidelines,
n.pl a set of standards, criteria, or specifications to be used or followed in the performance of certain tasks.
 with respect to the size of the sample, collection, storage, packing and transportation were developed and followed. Samples of an approximate size of 3 x 5 x 5 in. were collected from the parting surface and stored in airtight air·tight  
adj.
1. Impermeable by air.

2. Having no weak points; sound: an airtight excuse.


airtight
Adjective

1.
 bags to preserve moisture.

New Guidelines

To accurate[y measure the thermal properties of mold materials, tests must be conducted on material taken from several locations on the sample to ensure valid results. In addition, thin slices of the material must be taken to conduct the thermal diffusivity tests. However, these samples can sometimes slump Slump

A temporary fall in performance, often describing consistently falling security prices for several weeks or months.
 at high temperatures and give false diffusivity Dif`fu`siv´i`ty

n. 1. Tendency to become diffused; tendency, as of heat, to become equalized by spreading through a conducting medium.
 readings. Some mold materials are nearly impossible to test because small samples undergo phase changes at high temperatures.

This study was not immune to problems of this nature. Of the seven mold materials tested, complete datasets will be presented for only five materials. Further evaluation is required on the remaining two datasets, primarily in the area of thermal diffusivity measurements. (Partial datasets including specific heat and density will be presented for these two materials).

Chemically Bonded Mold Materials

Comparisons were made between measurements for the chemically bonded materials (CBUMS-M, CBFMS-C and CBSMS-M) and a generic dataset for chemically bonded mold materials currently available in most simulation software packages.

The generic dataset for the thermal conductivity thermal conductivity

A measure of the ability of a material to transfer heat. Given two surfaces on either side of the material with a temperature difference between them, the thermal conductivity is the heat energy transferred per unit time and per unit
 values matches the CBUMS-M data. The CBFMS-C core sand molding material data have a lower thermal conductivity for temperatures below 1,400C (2,552F) ant slightly higher thermal conductivity for temperatures ranging from 1,5001,600C (2,732-2,912F). The CBSMS-M dataset has a slightly higher thermal conductivity at temperatures below 600C (1,112F) and significantly lower thermal conductivity at temperatures above 600C.

Specific heat values for CBUMS-M, CBFMS-C CBSMS-M and CBUMS-C datasets are slightly higher than the generic data. (Because the CBSMS-M data and the generic data were both measured on a differential scanning calorimeter, their datasets have a slightly different correlation trend at very low temperatures, as compared to the datasets measured using the Bunsen Ice Calorimetry calorimetry (kăl'ərĭm`ətrē), measurement of heat and the determination of heat capacity  method.)

The CBUMS-M, CBFMS-M and generic data share similar density traits. The density for the core sand samples (CBFMS-C and CBUMS-C) are about 1015% higher than the generic data, while the shell sand sample (CBSMS-M) density data are about 10% lower than the generic data.

While there are several ways to evaluate the new thermal data, a proven method involves pouring castings, taking thermocouple reading in the mold and sectioning solidified so·lid·i·fy  
v. so·lid·i·fied, so·lid·i·fy·ing, so·lid·i·fies

v.tr.
1. To make solid, compact, or hard.

2. To make strong or united.

v.intr.
 feeders. The theory is that if the fee pipe can be predicted accurately i conjunction with the temperature profile in the molding material, then the molding material thermal data are probably accurate. This theory also implies that the thermal data for the feeding system also must be accurate, along with the heat transfer coefficients The heat transfer coefficient is used in calculating the convection heat transfer between a moving fluid and a solid in thermodynamics. The heat transfer coefficient is often calculated from the Nusselt number (a dimensionless number).  between the metal and the sleeve
Sleeve (O. Eng. slieve, or slyf, a word allied to slip, cf. Dutch sloof) is that part of a garment which covers the arm, or through which the arm passes or slips.
, an the sleeve and the mold.

One example of this involves purely insulating riser sleeve on a cub casting that is poured in low-carbon alloy alloy (ăl`oi, əloi`) [O. Fr.,=combine], substance with metallic properties that consists of a metal fused with one or more metals or nonmetals.  steel at 1,560C (2,840F). The molding material is chemically bonded with urethane, and the riser sleeve is 4 x 6-in. insert sleeve that is top risered on a 5.5-in. cube cube, in geometry, regular solid bounded by six equal squares. All adjacent faces of a cube are perpendicular to each other; any one face of a cube may be its base. The dimensions of a cube are the lengths of the three edges which meet at any vertex. . Several identical castings were poured in several molds and thermocouples were placed at the riser sleeve outer diameter (sleeve/ mold interface) and at 0.25 in. and 0.5 in. deep in the molding material.

Simulations were conducted using the CBUMS-M molding material thermal data to measure the performance results of feed safety margin. (The feed safety margin is defined as the distance from the bottom of the pipe to the riser/casting interface divided by the poured height of the riser.) The predicted results (Figs. 1-2), show a 13.3% safety margin, which compares well with the 14.99% actual results. To be sure that the prediction is entirely correct, the thermocouple data are compared as well (Figs. 3-4)

[FIGURES 1-4 OMITTED]

The measured and predicted temperature results are nearly identical throughout the entire time range (approximately 1.5 hrs.). It appears that the CBUMS-M thermal dataset allows the simulation program to accurately predict the feed performance and the temperature profile in the mold.

For comparison purposes, the identical simulation was conducted using the generic chemically bonded mold material dataset. In this case, the generic mold material thermal data give a slightly conservative answer, and the result is a negative safety margin (for a cube that is tightly rigged rig  
tr.v. rigged, rig·ging, rigs
1. To provide with a harness or equipment; fit out.

2. Nautical
a. To equip (a ship) with sails, shrouds, and yards.

b.
). The differences between the thermal data have slightly altered the feed prediction result.

In general, the predicted versus measured comparison is quite good and would normally be considered to have good agreement. However, for this case, the agreement is even better when the CBUMS-M data are used.

Simulations were not conducted using the CBFMS-C and CBSMS-M data because feeding and temperature data were not available to conduct side-by-side comparisons for this configuration using chemically bonded fine core sand or shell molding sand. However, based on the quality of the data and the relative similarity Similarity is some degree of symmetry in either analogy and resemblance between two or more concepts or objects. The notion of similarity rests either on exact or approximate repetitions of patterns in the compared items.  to the CBUMS-M thermal data, it can be assumed that these datasets are accurate.

Green Sand Mold Materials

Comparisons also were made between measurements for the green sand bonded materials (GSMM GSMM or the Good Samaritan Medical Ministry is a non-profit, non-denominational Christian non-governmental organization (NGO) which organizes yearly summer missions to Vietnam.  and GS-HPS) and a genetic dataset for green sand bonded mold materials currently available in most simulation software packages.

A comparison of the thermal conductivity values revealed that the shape and absolute values are quite different between the generic data and the new GS-MM data. The GS-HPMS has a much higher thermal conductivity than the other green sand datasets.

The specific heat data are very similar between the datasets, with the exception of the GS-MM having significantly higher values at temperatures above 1,200C (2,192F). Neither the cause nor the consequences of this difference were evaluated in the study, but it is possible that specific heat values at the higher temperatures may be higher than reality for this molding material.

The density curves all show the same trend and are all within about 5% of each other, with the exception of some high density values for the generic dataset at low temperatures. In general, it appears that the density data are very similar between the datasets.

The GS-MM and GS-HPMS datasets have not been validated val·i·date  
tr.v. val·i·dat·ed, val·i·dat·ing, val·i·dates
1. To declare or make legally valid.

2. To mark with an indication of official sanction.

3.
 using actual metalcasting facility trials so a validation See validate.

validation - The stage in the software life-cycle at the end of the development process where software is evaluated to ensure that it complies with the requirements.
 exercise should first be conducted using simulation and a known casting result to evaluate the predicted feed results when using this new data.

Also, some programs require large values of specific heat for green sand materials at approximately the 100C (212F) data point. When inputting the new thermal data, the same specific heat values used previously with the generic dataset for points at 100C must be incorporated.

Continuing Studies

Accurate thermal data for all aspects of the casting process are required to provide reliable predictions from casting process simulation programs. The mold material genetic thermal data used by most simulation engineers was in need of re-evaluation in order to keep up with advances in simulation technology.

The thermal data comparisons show slight differences in thermal conductivity. specific heat and density data between the new data and the genetic datasets. While both sets of data yielded reasonable answers, the new data provides a more accurate prediction.

But this research must be continually con·tin·u·al  
adj.
1. Recurring regularly or frequently: the continual need to pay the mortgage.

2.
 updated. The coming years promise to provide even more advances in simulation technology, and the mold material thermal data cannot be allowed to lag for 20 years again. Not only that, but work still needs to be done on the current data. The effect of different sand fineness, shape and size distribution, and different binder addition levels on the thermophysical properties needs to lie studied. Also, similar data need to be developed tot non-silica based substrate The base layer of a structure such as a chip, multichip module (MCM), printed circuit board or disk platter. Silicon is the most widely used substrate for chips. Fiberglass (FR4) is mostly used for printed circuit boards, and ceramic is used for MCMs.  materials. such as zirconia, chromite chromite (krō`mīt), dark brown to black mineral. It is an iron-chromium oxide, FeCr2O4, with traces of magnesium and aluminum.  and olivine olivine (ŏlĭv`ēn), an iron-magnesium silicate mineral, (Mg,Fe)2SiO4, crystallizing in the orthorhombic system.  as well as for pure silica for the lost foam process.
Table 1. Sand Samples Tested from Production Metalcasting Facilities

Sand Acronym   Description

CBUMS-C        Chemically Bonded Urethane Molding Sand-Core (fine)
CBUMS-M        Chemically Bonded Urethane Molding Sand-Mold (coarse)
CBUMS-M        Chemically Bonded Shell Molding Sand-Mold (coarse)
CBFMS-C        Chemically Bonded Furan Molding Sand-Core (fine)
CBFMS-M        Chemically Bonded Furan Molding Sand-Mold (coarse)
GS-MM          Green Sand-Machine Molded
GS-HPMS        Green Sand-High-Pressure Molding Sand

Table 2. New Material Data for CBUMS-M

Temperature    Thermal Diff.        Density       Specific Heat
    (C)       ([cm.sup.2]/sec)   (g/[cm.sup.3])     (J/kg-K)

     22              --              1.488             --
    100           0.00474            1.482            1118
    200           0.00435            1.475            1114
    300           0.00407            1.468            1160
    400           0.00388            1.462            1178
    500           0.00379            1.456            1196
    600           0.00380            1.448            1214
    700           0.00389            1.442            1232
    800           0.00408            1.437            1250
    900           0.00435            1.433            1268
   1000           0.00470            1.428            1285
   1100           0.00513            1.422            1303
   1200           0.00563            1.417            1321
   1300           0.00621            1.413            1339
   1400           0.00686            1.401            1356
   1500           0.00758            1.382            1374
   1600           0.00836            1.360            1392

Temperature   Therm Cond.
    (C)         (W/m-K)

     22           --
    100          0.785
    200          0.732
    300          0.693
    400          0.668
    500          0.660
    600          0.668
    700          0.691
    800          0.733
    900          0.790
   1000          0.863
   1100          0.951
   1200          1.054
   1300          1.175
   1400          1.303
   1500          1.439
   1600          1.582

Table 3. New Material Data for CBFMS-C

Temperature    Thermal Diff.        Density       Specific Heat
    (C)       ([cm.sup.2]/sec)   (g/[cm.sup.3])     (J/kg-K)

     22                --            1.565              --
    100           0.00293            1.561            1045
    200           0.00303            1.557            1071
    300           0.00304            1.553            1096
    400           0.00298            1.548            1120
    500           0.00290            1.542            1143
    600           0.00283            1.535            1167
    700           0.00278            1.530            1191
    800           0.00279            1.526            1215
    900           0.00290            1.522            1238
   1000           0.00313            1.518            1262
   1100           0.00351            1.512            1285
   1200           0.00408            1.508            1309
   1300           0.00486            1.503            1333
   1400           0.00588            1.498            1356
   1500           0.00718            1.493            1380
   1600           0.00879            1.488            1404

Temperature   Therm Cond.
    (C)         (W/m-K)

     22             --
    100          0.478
    200          0.505
    300          0.517
    400          0.516
    500          0.511
    600          0.507
    700          0.507
    800          0.517
    900          0.547
   1000          0.600
   1100          0.682
   1200          0.805
   1300          0.973
   1400          1.194
   1500          1.479
   1600          1.836

Table 4. New Material Data for CBSMS-M

 Temperature      Thermal Diff.        Density       Specific Heat
     (C)         ([cm.sup.2]/sec)   (g/[cm.sup.3])     (J/kg-K)

       22            0.008561           1.357             790
      100            0.007795           1.355             910
      200            0.006914           1.354            1015
      300            0.006148           1.351            1076
      400            0.005497           1.343            1120
      500            0.004961           1.335            1154
      600            0.00454            1.326            1181
      700            0.004233           1.318            1205
      800            0.004041           1.312            1225
      900            0.003964           1.305            1243
     1000            0.004002           1.298            1259
     1100            0.004154           1.285            1273
     1200            0.004422           1.281            1286
     1300            0.004804           1.276            1298
     1400             0.0053            1.271            1310
     1500            0.005912           1.266            1320
     1600            0.006639           1.261            1330

 Temperature   Therm Cord.
     (C)         (W/m-K)

       22        0.9178
      100        0.9614
      200        0.9503
      300        0.8942
      400        0.8269
      500        0.7641
      600        0.7111
      700        0.6721
      800        0.6494
      900        0.6428
     1000        0.6537
     1100        0.6796
     1200        0.7285
     1300        0.7958
     1400        0.8822
     1500        0.9879
     1600        1.1131

Table 5. New Material Data for GS-MM

 Temperature      Thermal Diff.        Density       Specific Heat
     (C)         ([cm.sup.2]/sec)   (g/[cm.sup.3])     (J/kg-K)

       22               --              1.404             --
      100            0.00413            1.392             953
      200            0.00390            1.380             994
      300            0.00361            1.367            1035
      400            0.00330            1.363            1076
      500            0.00298            1.358            1117
      600            0.00267            1.352            1158
      700            0.00239            1.348            1198
      800            0.00216            1.345            1239
      900            0.00202            1.342            1280
     1000            0.00196            1.339            1321
     1100            0.00203            1.335            1362
     1200            0.00223            1.332            1403
     1300            0.00259            1.329            1444
     1400            0.00314            1.326            1485
     1500            0.00388            1.323            1526
     1600            0.00484            1.320            1567

 Temperature   Therm Cond.
     (C)         (W/m-K)

       22           --
      100         0.548
      200         0.535
      300         0.511
      400         0.484
      500         0.452
      600         0.418
      700         0.386
      800         0.360
      900         0.347
     1000         0.347
     1100         0.369
     1200         0.417
     1300         0.497
     1400         0.618
     1500         0.783
     1600         1.001

Table 6. New Material Data for GS-HPMS
                                                Specific    Therm
Temperature     Thermal Diff.       Density       Heat      Cond.
    (C)       ([cm.sup.2]/sec)   g/[cm.sup.3]   (J/kg-K)   (W/m-K)

     22            --             1.395            --         --
    100            --             1.369           1147        --
    200            --             1.350           1152        --
    300            --             1.340           1157        --
    400            --             1.335           1160        --
    500          0.00621          1.331           1164       0.962
    600          0.00646          1.327           1168       1.001
    700          0.00641          1.324           1172       0.995
    800          0.00615          1.322           1176       0.956
    900          0.00580          1.320           1179       0.903
   1000          0.00546          1.318           1183       0.851
   1100          0.00522          1.316           1187       0.815
   1200          0.00519          1.313           1191       0.811
   1300          0.00547          1.313           1194       0.858
   1400          0.00616          1.308           1198       0.965
   1500          0.00737          1.297           1202       1.149
   1600          0.00920          1.286           1205       1.426

Table 7. New Material Data far CBFMS-M

Temperature       Density
    (C)        (g/[cm.sup.3)

     22            1.430
    100            1.425
    200            1.419
    300            1.413
    400            1.406
    500            1.398
    600            1.390
    700            1.387
    800            1.384
    900            1.382
   1000            1.379
   1100            1.376
   1200            1.367
   1300            1.359
   1400            1.351
   1500            1.343
   1600            1.335

Table 8. New Material Data for CBUMS-C

Temperature       Density       Specific Heat
    (C)        (g/[cm.sup.3])    (J/kg-K)

     22            1.548            --
    100            1.545           1021
    200            1.541           1058
    300            1.538           1094
    400            1.531           1130
    500            1.525           1165
    600            1.516           1201
    700            1.510           1236
    800            1.506           1271
    900            1.501           1306
   1000            1.497           1342
   1100            1.491           1377
   1200            1.486           1412
   1300            1.481           1447
   1400            1.476           1482
   1500            1.470           1518
   1600            1.465           1553


This article was adapted from a paper (02-080) presented at the 2002 Metalcasting Congress.

For More Information

"Thermal Distortion distortion, in electronics, undesired change in an electric signal waveform as it passes from the input to the output of some system or device. In an audio system, distortion results in poor reproduction of recorded or transmitted sound.  of Shell and Nobake Binder Systems," M.J. Keil. J. Rodriguez Rodriguez or Rodrigues (rōdrē`gəs), island (1996 est. pop. 34,883), 42 sq mi (109 sq km), in the Indian Ocean, c.350 mi (560 km) E of Mauritius, of which it is a dependency. , and S.N. Ramrattan AFS A distributed file system for large, widely dispersed Unix and Windows networks from Transarc Corporation, now part of IBM. It is noted for its ease of administration and expandability and stems from Carnegie-Mellon's Andrew File System.

AFS - Andrew File System
 Transactions, 1999.

Tony Midea Headline text

For a town in Greece see Midea, Greece.

Midea (美的電器 Shenzhen Stock Exchange Code 000786; Shanghai Stock Exchange Code 000527) is a Chinese electronics manufacturer located in Shunde, Guangdong.
 is a product development manager for Foseco Metallurgical met·al·lur·gy  
n.
1. The science that deals with procedures used in extracting metals from their ores, purifying and alloying metals, and creating useful objects from metals.

2.
 Inc., Cleveland Cleveland, former county, England
Cleveland, former county, NE England, created under the Local Government Act of 1972 (effective 1974). It was composed of the county boroughs of Hartlepool and Teeside and parts of the former counties of Durham and
. Midea has helped develop thermal datasets for all of Foseco's global feeding systems products. At the time this paper was originally published, Jiten V. Shah Shah is a Persian term for a monarch (ruler) that has been adopted in many other languages. This term is a Post Islamic Revolution term for monarchs in Iran which is replaced by valie faghih or Supreme Leader.  was with K+P Agile ag·ile  
adj.
1. Characterized by quickness, lightness, and ease of movement; nimble.

2. Mentally quick or alert: an agile mind.
, Naperville, Ill.
COPYRIGHT 2004 American Foundry Society, Inc.
No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 2004, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Author:Shah, Jiten V.
Publication:Modern Casting
Geographic Code:1USA
Date:Aug 1, 2004
Words:2887
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