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Better magnetic refrigeration.


In some materials, a magnetic field can cause cooling.

Scientists have known about this phenomenon, the magnetocaloric effect Magnetocaloric effect

The reversible change of temperature accompanying the change of magnetization of a ferromagnetic or paramagnetic material. This change in temperature may be of the order of 1°C (2°F), and is not to be confused with the much
, since the turn of the century, when the technique was first used to cool liquid oxygen.

In essence, the effect works like this: Exposing a substance to a magnetic field causes its atoms to point in the same direction. When that magnetic field is taken away, the atoms rotate randomly. This change creates a cooling effect.

Near absolute zero, this effect works very well. Above 15 kelvins, however, existing materials don't cool effectively. The problem, says Robert D. Shull, a researcher at the National Institute of Standards and Technology National Institute of Standards and Technology, governmental agency within the U.S. Dept. of Commerce with the mission of "working with industry to develop and apply technology, measurements, and standards" in the national interest.  in Gaithersburg, Md., stems from inherent limitations in the cooled compounds.

"To increase the operating temperature of a magnetic refrigerator," he says, "we need new materials."

Shyll's group now reports making a new composite that shows a magnetocaloric effect three to four times larger than the effect exhibited by current materials. Made of gadolinium gadolinium (gădəlĭn`ēəm), metallic chemical element; symbol Gd; at. no. 64; at. wt. 157.25; m.p. 1,312°C;; b.p. 3,233°C;; sp. gr. 7.898 at 25°C;; valence +3. , gallium gallium (găl`ēəm), metallic chemical element; symbol Ga; at. no. 31; at. wt. 69.72; m.p. 29.78°C;; b.p. 2,403°C;; sp. gr. 5.904 at 29.6°C; (solid), 6.095 at 29.8°C; (liquid); valence +2 or +3. , iron, and oxygen, the new substance produces cooling at less frigid frigĀ·id
adj.
1. Extremely cold.

2. Persistently averse to sexual intercourse.
 temperatures, and it requires a less intense magnetic field, Shull says.

Household magnetic air conditioners Conditioners used on leather take many shapes and forms. They are used mostly to keep leather from drying out and deteriorating.

A very old and widely used conditioner is dubbin.
 and fridges remain a long way off. At present, magnetic cooling requires temperatures near absolute zero, making this technique impractical for home use. but Shull believes that, at least in theory, magnetically cooled ice cream "is possible."
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No portion of this article can be reproduced without the express written permission from the copyright holder.
Copyright 1994, Gale Group. All rights reserved. Gale Group is a Thomson Corporation Company.

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Title Annotation:magnetocaloric effect, magnetic field that causes cooling; composite made of gadolinium, gallium, iron and oxygen causes cooling at higher temperatures
Author:Lipkin, Richard
Publication:Science News
Article Type:Brief Article
Date:Apr 23, 1994
Words:225
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