Bell Labs Scientists Create Record-Breaking, High-Temperature Organic Superconductor Out of Carbon Bucky Balls.

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MURRAY HILL, N.J.--(BUSINESS WIRE)--Aug. 30, 2001

Bell Labs experiment doubles temperature at which bucky balls

exhibit no resistance to flow of electricity, raising hope

for loss-free organic electronics

Scientists from Lucent Technologies' (NYSE: LU) Bell Labs have shown that soccer ball-shaped carbon molecules known as bucky balls can act as superconductors at relatively warm temperatures, raising hopes for inexpensive, power loss-free organic electronics and other practical applications such as quantum computers.

The discovery is described in an article published today by the journal Science on their Science Express web site (www.sciencexpress.org).

Superconductors are materials in which the resistance to the flow of electricity vanishes below a certain temperature. The Bell Labs team was able to demonstrate that bucky balls acted as superconductors below 117 Kelvin (minus 249 degrees Fahrenheit), which is more than double the previous temperature record of 52 Kelvin (minus 366 degrees Fahrenheit) set last year.

Cold as the new temperature may sound, it is warm enough for the bucky ball superconductors to function while cooled by liquid nitrogen instead of the much more expensive liquid helium.

"This result makes bucky balls infinitely more interesting to study," said Federico Capasso, physical research vice president at Bell Labs. "This shows that bucky balls may live up to their initial promise of being a material that will be very important to technology."

Bucky balls are named after American inventor R. Buckminster Fuller, since they resemble the geodesic domes that Fuller designed. They are large molecules made up of 60 carbon atoms. In 1991, a Bell Labs team first showed that bucky balls can act as superconductors at very low temperatures when mixed with potassium.

A Bell Labs team led by physicist Hendrik Schon inserted molecules of chloroform and bromoform (a chemical molecule similar to chloroform but with bromine atoms instead of chlorine atoms) in between bucky balls to create a "stretched" bucky ball crystal where the bucky ball molecules were spaced further apart than usual since the chloroform and bromoform molecules were wedged amidst them. This had the effect of lowering the electronic and molecular attraction between neighboring bucky ball molecules in the crystal. By building a sensitive electronic device known as a field effect transistor and connecting it to the crystal, the Bell Labs scientists were able to produce superconductivity in the bucky ball crystal at a record-breaking temperature of minus 249 degrees Fahrenheit.

"I'm surprised, I didn't expect the temperature to go up so much," said Professor Peter Littlewood, head of theory of condensed matter physics research at the University of Cambridge, U.K., and a former Bell Labs researcher. "It's a very clean result."

The only other known superconductors that work at this and higher temperatures are copper oxide superconductors. These, however, have other problems; the physics that governs copper oxide superconductors is non-conventional and not well understood, and they tend to be expensive. Nonetheless, they have already been used commercially to make powerful magnets, microwave filters and superconducting wires for power transmission systems. The bucky ball superconductors, on the other hand, are potentially less expensive, and the physics is better understood, since bucky ball superconductors seem to act as conventional superconductors.

"Our results show that high temperature superconductivity is not restricted to copper oxides," said Schon. "As research continues, we can expect other surprises in the form of new materials and so on in superconductivity."

Other researchers involved in this work were Bell Labs scientists Christian Kloc and Bertram Batlogg (who is also affiliated with the Solid State Physics Laboratory in ETH-Zurich in Switzerland).

Bell Labs research continues to push the frontiers of technology. With 27,000 employees in 25 countries, Bell Labs is the world's largest R&D organization dedicated to communications and the leading source of new communications technologies. Bell Labs has generated more than 28,000 patents since 1925 and has played a pivotal role in inventing or perfecting key communications technologies, including transistors, digital networking and signal processing, lasers and fiber-optic communications systems, communications satellites, cellular telephony, electronic switching of calls, touch-tone dialing, and modems. Bell Labs scientists have received six Nobel Prizes in Physics, nine U.S. Medals of Science and six U.S. Medals of Technology. For more information about Bell Labs, visit its Web site at http://www.bell-labs.com.

Lucent Technologies, headquartered in Murray Hill, N.J., USA, designs and delivers networks for the world's largest communications service providers. Backed by Bell Labs research and development, Lucent relies on its strengths in mobility, optical, data and voice networking technologies as well as software and services to develop next-generation networks. The company's systems, services and software are designed to help customers quickly deploy and better manage their networks and create new, revenue-generating services that help businesses and consumers. For more information on Lucent Technologies, visit its Web site at http://www.lucent.com.

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