Applying the finite--volume method for solving the convection--dispersion equation in radial coordinates.Abstract The finite-control volume technique is used to solve the convection-dispersion equation in radial coordinates. In the dispersion dispersion, in chemistry dispersion, in chemistry, mixture in which fine particles of one substance are scattered throughout another substance. A dispersion is classed as a suspension, colloid, or solution. model presented, the dispersion coefficient is dependent on both velocity and diffusion coefficient. The finite-control volume scheme is shown to have negligible numerical dispersion. The code is verified by performing a convergence study to show that the numerical results are independent of the mesh and time-step sizes. The solution allows analyzing the dispersion transport of a slug in a steady radial flow from an injection well fully penetrating a homogeneous reservoir of uniform thickness and finite arial extent. Results show that the dispersive dispersive /dis·per·sive/ (-per´siv) 1. tending to become dispersed. 2. promoting dispersion. mixing zone does not necessarily grow in proportion with the square root of time for all times, unlike for the linear displacement. Results reveal a typical minimum of the dispersive mixing zone with time for radial displacement On vertical photographs, the apparent "leaning out," or the apparent displacement of the top of any object having height in relation to its base. The direction of displacement is radial from the principal point on a true vertical, or from the isocentre on a vertical photograph distorted . It appears that at some radial distance close to the wellbore, the dimensionless mixing zone decreases with the square root of time since there is an accumulation of the miscible miscible /mis·ci·ble/ (mis´i-b'l) able to be mixed. mis·ci·ble adj. Capable of being and remaining mixed in all proportions. Used of liquids. slug in this particular space domain. However, when the dissolution of the slug starts taking effect particularly at large distances away from the injection point, the mixing zone begins to increase with increasing square root of time. These results indicate that the optimal slug size of miscible displacement is time-dependent. At a fixed time value, the higher the value of dispersivity, the more mixing takes place, and hence the greater the concentration of the miscible fluid becomes. A higher dispersivity value aggravates the dissolution of the slug at the toe of the concentration profile, but gives rise to a larger concentration at the tail. The smaller the porosity porosity /po·ros·i·ty/ (por-os´it-e) the condition of being porous; a pore. po·ros·i·ty n. 1. The state or property of being porous. 2. value is, the larger the rate of change of concentration. This is expected since a smaller value of porosity acts like a choke (jargon) choke - To fail to process input or, more generally, to fail at any endeavor. E.g. "NULs make System V's "lpr(1)" choke." See barf, gag. on the porous medium A porous medium or a porous material is a solid (often called frame or matrix) permeated by an interconnected network of pores (voids) filled with a fluid (liquid or gas). Usually both the solid matrix and the pore network (also known as the pore space) are assumed to be and results on a greater degree of convective mixing than diffusion mixing. Keywords: dispersion, porous porous /por·ous/ (por´us) penetrated by pores and open spaces. po·rous adj. 1. Full of or having pores. 2. Admitting the passage of gas or liquid through pores. media, finite-volume method. Introduction Dispersion is the mixing of a solvent with in-situ hydrocarbon caused by the combined effects of diffusion and convection. Convection is induced by variation in the velocity field caused by the tortuous tor·tu·ous adj. Having many turns; winding or twisting. tortuous adjective Referring to complexly twisted thing. Cf Tortious. flow path of the porous medium. Diffusion occurs as a consequence of a concentration gradient concentration gradient n. The graduated difference in concentration of a solute per unit distance through a solution. Noun 1. . Dispersion phenomena arise in a variety of applications such as heat flow in material, transport of pollutants pollutants see environmental pollution. in aquifers The following is a partial list of aquifers around the world. A of aquifers is also available. North America Canada
v. dis·si·pat·ed, dis·si·pat·ing, dis·si·pates v.tr. 1. To drive away; disperse. 2. effects in miscible displacements. It affects the amount of solvent mixing with the in-situ oil to promote miscibility miscibility (miˈ·s When one fluid is miscibly displacing another in a porous medium and when the displacement is stable, the following convection-dispersion equation describes the overall transport and mixing of incompressible in·com·press·i·ble adj. Impossible to compress; resisting compression: mounds of incompressible garbage. in fluids flowing through a porous medium: [phi] [partial derivative partial derivative In differential calculus, the derivative of a function of several variables with respect to change in just one of its variables. Partial derivatives are useful in analyzing surfaces for maximum and minimum points and give rise to partial differential ]C/[partial derivative]t + u [nabla]C = [phi][nabla]. (K[nabla]C) (1) In this notation, C is the concentration which is a function of time (t) and position, u is the superficial velocity (Darcy velocity), and K is the dispersion coefficient. For the linear system with constant dispersion coefficient, various analytical solutions based on the error function are established. These solutions differ according to according to prep. 1. As stated or indicated by; on the authority of: according to historians. 2. In keeping with: according to instructions. 3. the boundary conditions boundary condition n. Mathematics The set of conditions specified for behavior of the solution to a set of differential equations at the boundary of its domain. imposed. Chase [2] presented a finite-element numerical solution for the physical problem discussed. However, Chase [2] concluded that, even with a finite-element method, significant numerical dispersion could still exist. Numerical solutions to fluid-flow equations, usually nonlinear A system in which the output is not a uniform relationship to the input. nonlinear - (Scientific computation) A property of a system whose output is not proportional to its input. partial-differential equations, are generally obtained by making discrete approximations to derivatives. Whether finite-difference or finite-element methods are used, these approximations always introduce truncation errors Noun 1. truncation error - (mathematics) a miscalculation that results from cutting off a numerical calculation before it is finished miscalculation, misestimation, misreckoning - a mistake in calculating that often can distort the accuracy and stability of the solution. The truncation error is often referred to as numerical dispersion because, to lowest order, it can be represented as a second spatial derivative term added to any true dispersion term in the problem. Artificial smearing Smearing is a term used in rock climbing. It is the practice of using the sole of a shoe against a flat rock face. Smearing can be one of the most insecure and technical techniques used in climbing, requiring a combination of leg/ankle tension, foot placement, and good as a result of numerical dispersion can render the numerical solution meaningless. [3-5] For miscible displacement in radial geometry, a number of authors interested in the stability of displacements in porous media solved the convection dispersion equation analytically and numerically with various degrees of simplicity. Tan and Homsy [6] employed a quasi-steady-state analysis. They showed that the unfavorable viscosity gradient resulted in an algebraically al·ge·bra·ic adj. 1. Of, relating to, or designating algebra. 2. Designating an expression, equation, or function in which only numbers, letters, and arithmetic operations are contained or used. 3. growing perturbation perturbation (pŭr'tərbā`shən), in astronomy and physics, small force or other influence that modifies the otherwise simple motion of some object. The term is also used for the effect produced by the perturbation, e.g. , rather than the exponential 1. (mathematics) exponential - A function which raises some given constant (the "base") to the power of its argument. I.e. f x = b^x If no base is specified, e, the base of natural logarthims, is assumed. 2. behavior known from rectilinear rec·ti·lin·e·ar adj. Moving in, consisting of, bounded by, or characterized by a straight line or lines: following a rectilinear path; rectilinear patterns in wallpaper. displacements. Pankiewitz and Meiburg [7] extended this analysis to fluid combinations that give rise to non-monotonic viscosity profiles, which they found to be destabilizing. Riaz and Meiburg [8] reported on the stability of axial axial /ax·i·al/ (ak´se-al) of or pertaining to the axis of a structure or part. ax·i·al adj. 1. Relating to or characterized by an axis; axile. 2. and helical helical /hel·i·cal/ (hel´i-k'l) spiral (1). hel·i·cal adj. 1. Of or having the shape of a helix; spiral. 2. Having a shape approximating that of a helix. perturbations in three-dimensional displacements. Yortsos [9] incorporated the effects of equilibrium adsorption adsorption, adhesion of the molecules of liquids, gases, and dissolved substances to the surfaces of solids, as opposed to absorption, in which the molecules actually enter the absorbing medium (see adhesion and cohesion). and showed the existence of a mathematical transformation that related radial flows to rectilinear ones. Tang tang, in zoology tang: see butterfly fish. and Peaceman [5] reported both analytic and a numerical solutions for the convection-dispersion problem for the case when the dispersion coefficient was only dependent on velocity but did not depend on diffusion. Their numerical solution which used a time-implicit, centered-in-space difference scheme gave results that compared almost exactly with their analytic solution. The emphasis of their study was on the type of boundary condition used at the wellbore, though. They reported that the concentration profiles were insensitive to whether the constant concentration, or the flux boundary condition was used. The purpose of this research is to apply the finite-volume technique [10] (Patankar technique) to obtain a numerical solution for the radial convection-dispersion equation. The work of Tang and Peaceman [5] is extended by including the effects of both velocity and diffusion in the dispersion coefficient. An analytic solution for this problem becomes very difficult to obtain because a number of coefficients of the convection-dispersion partial differential equation partial differential equation In mathematics, an equation that contains partial derivatives, expressing a process of change that depends on more than one independent variable. are variable. The application of Patankar technique for solving this problem associated with miscible displacement becomes unique since it eliminates the effects of numerical dispersion. The new formulation allows to study the effects of petrographic pe·trog·ra·phy n. The description and classification of rocks. pe·trog ra·pher n. properties like porosity, tortuosity tortuosityn. 1. The quality or condition of being tortuous; twistedness or crookedness. 2. A bent or twisted part, passage, or thing. , dispersivity on the dispersion phenomenon in general. Model Formulation For the linear system with constant dispersion coefficient, various analytical solutions, based on the error function, are established for Equation (1). These solutions differ according to the boundary conditions imposed. [1,11] In radial coordinates, Equation (1) is transformed into the following mathematical statement Noun 1. mathematical statement - a statement of a mathematical relation math, mathematics, maths - a science (or group of related sciences) dealing with the logic of quantity and shape and arrangement : [phi][partial derivative]C/[partial derivative]t + u [partial derivative]C/[partial derivative]r = [phi]/r [partial derivative]/[partial derivative]r([rK.sub.r] [partial derivative]C/[partial derivative]r) (2) subject to the initial condition C = 0, for t = 0 for all radii ra·di·i n. A plural of radius. radii Noun a plural of radius (3) With the far boundary condition C = 0, when r [right arrow] [infinity] at all time (4) And the inlet inlet /in·let/ (-let) a means or route of entrance. pelvic inlet the upper limit of the pelvic cavity. thoracic inlet the elliptical opening at the summit of the thorax. flux boundary condition: 2[pi][Hr.sup.*.sub.w](uC - [alpha]u [partial derivative]C/[partial derivative]r) = [iC.sub.J] (5) where H is the reservoir thickness, [r.sup.*.sub.w] is the wellbore radius, [alpha] is the dispersivity, and "i" is the injection rate. In this analysis, we consider only the continuous injection case: [C.sub.J] = 1 (6) For this simple geometry, the Darcy velocity at any radius is given by the injection rate divided by the cross sectional area available for flow as follows: u = i/2[pi]Hr (7) In this analysis, the dimensionless variables are defined as: [t.sub.D] = [integral]idt/[V.sub.p] (8) [C.sub.D] = C - [C.sub.I]/[C.sub.J] - [C.sub.I] (9) [r.sub.D] = r/[r.sub.e] (10) In this notation [C.sub.I] is the initial concentration and [C.sub.I] is the injected concentration. Since r.sup.*.sub.e] >> [r.sup.*.sub.w], the following approximation approximation /ap·prox·i·ma·tion/ (ah-prok?si-ma´shun) 1. the act or process of bringing into proximity or apposition. 2. a numerical value of limited accuracy. for the pore pore (por) a small opening or empty space. alveolar pores openings between adjacent pulmonary alveoli that permit passage of air from one to another. volume is used: [V.sub.P] [approximately equal to] [pi][r.sup.*2.sub.e] H [phi] (11) Taking the derivatives of Equations (8) and (9), and substituting expressions for the derivatives (dt) and (dr) into Equation (2), and using an approximation for the pore volume given by Equation (11), we obtain the following: [MATHEMATICAL EXPRESSION A group of characters or symbols representing a quantity or an operation. See arithmetic expression. NOT REPRODUCIBLE IN ASCII ASCII or American Standard Code for Information Interchange, a set of codes used to represent letters, numbers, a few symbols, and control characters. Originally designed for teletype operations, it has found wide application in computers. ] (12) The above formulation identifies a non-dimensional group which may be termed as the Local Peclet number given by [NL.sub.pe] = ru/[phi][K.sub.r] (13) Further development of the right-hand-side derivative of Equation (12) leads to the following non-dimensional convection-diffusion equation: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (14) Equation (14) identifies a second non-dimensional term [N.sub.R] given by [N.sub.R] = 1/[r.sub.D][K.sub.r] [partial derivative][K.sub.r]/[partial derivative][r.sub.D] (15) [N.sub.R] is a non-dimensional rate of change of radial dispersion coefficient with respect to radius. Both [NL.sub.pe] and [N.sub.R] are a function of radius. An average Peclet number, which is defined as the ratio of convective to dispersive transport, is therefore deduced from Equation (13), and is given by the following expression: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (16) Similarly, an average non-dimensional rate of change of radial dispersion coefficient with respect to radius ([[bar.N].sub.R]) is given by [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (17) Substituting the expression of NR from Equation (15) into Equation (17), and using the approximation ([r.sup.*2.sub.e] - [r.sup.*2.sub.w]) [approximately equal to] [r.sup.*2.sub.e] in the limit when [r.sup.*.sub.e] is large compared to [r.sup.*.sub.w], we obtain the following expression: [[bar.N].sub.R] = ln [K.sub.re]/[K.sub.rw] (18) where [K.sub.re] and [K.sub.rw] are the dispersion coefficients at [r.sup.*.sub.e] and [r.sup.*.sub.w], respectively. In general, the radial dispersion coefficient [K.sub.r] is defined by [K.sub.r] = [D.sub.m]/[phi][F.sup.*] + [alpha]u (19) In this notation, [D.sub.m] is the molecular diffusion coefficient, [F.sup.*] is the resistivity resistivity Electrical resistance of a conductor of unit cross-sectional area and unit length. The resistivity of a conductor depends on its composition and its temperature. formation factor, and [alpha] is the dispersivity. We use Pirson's model [12] that relates tortuosity to the resistivity formation factor and rock porosity to rewrite re·write v. re·wrote , re·writ·ten , re·writ·ing, re·writes v.tr. 1. To write again, especially in a different or improved form; revise. 2. Equation (19). Adapting the Finite-Volume Methodology In order to describe the finite-volume method in a classical way, we first use the general form of the diffusion-convection equation. Later, we apply this method on the governing equation of this manuscript. The generic conservation equation [10] for a general quantity [eta] is written as follows: [partial derivative]([rho][eta])/[partial derivative]/[partial derivative][x.sub.i] ([rho][u.sub.i][eta])-[partial derivative]/[partial derivative][x.sub.i]([GAMMA] [partial derivative][eta]/[partial derivative][x.sub.i]) = S' (20) Conservation of mass, momentum, and energy can be formulated in the form of the above equation, for which S' stands for the source term and [GAMMA] stands for the diffusion coefficient. In this method, the first step is the integration of the transport equation for quantity [eta] over a three-dimensional control volume V without any approximation. For simplicity, the method is illustrated by taking the steady-state case of Equation (20): [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (21) Next, Gauss's divergence theorem In vector calculus, the divergence theorem, also known as Gauss' theorem, Ostrogradsky's theorem, or Gauss-Ostrogradsky theorem is a result that relates the flow (that is, flux) of a vector field through a surface to the behaviour of the vector field inside the is applied to the left-hand-side of Equation (21) as follows: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (22) In this notation, [n.sub.i] is the unit vector In mathematics, a unit vector in a normed vector space is a vector (often a spatial vector) whose length, (or magnitude) is 1 (the unit length). A unit vector is often written with a superscribed caret or “hat”, like this normal to the surface element dA. This theorem theorem, in mathematics and logic, statement in words or symbols that can be established by means of deductive logic; it differs from an axiom in that a proof is required for its acceptance. transforms volume integrals of divergence divergence In mathematics, a differential operator applied to a three-dimensional vector-valued function. The result is a function that describes a rate of change. The divergence of a vector v is given by terms into surface integrals of fluxes all around the control volume. Applying Gauss' theorem leads to the following integrated conservation equation: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (23) In general, this equation cannot be solved analytically and a numerical solution will require that we need to transform it into an algebraic equation algebraic equation Mathematical statement of equality between algebraic expressions. An expression is algebraic if it involves a finite combination of numbers and variables and algebraic operations (addition, subtraction, multiplication, division, raising to a power, and . This transformation is called the discretization dis·cret·i·za·tion n. The act of making mathematically discrete. . It requires approximations to evaluate integrals and to perform interpolations. Next, the procedure is illustrated using cylindrical cyl·in·dri·cal adj. Of, relating to, or having the shape of a cylinder, especially of a circular cylinder. two-dimensional grid represented for the governing equation of this convection dispersion model (Equation (2)) which can be rearranged as follows: [partial derivative]C/[partial derivative]t + u/[phi] [partial derivative]C/[partial derivative]r = 1/r [partial derivative]/[partial derivative]r (r[K.sub.r] [partial derivative]C/[partial derivative]r) (24) From Equation (7), it is clear that [partial derivative]/[partial derivative]r (r u/[phi]) = 0 (25) By using Equation (25), Equation (24) can be re-arranged as follows: [partial derivative]C/[partial derivative]t + 1/r [partial derivative]/[partial derivative]r (r u/[phi] C) = 1/r [partial derivative]/[partial derivative]r (r [k.sub.r] [partial derivative]C/[partial derivative]r (27) The general transport equation, for planar A technique developed by Fairchild Instruments that creates transistor sublayers by forcing chemicals under pressure into exposed areas. Planar superseded the mesa process and was a major step toward creating the chip. , axisymmetric ax·i·sym·met·ric also ax·i·sym·met·ri·cal adj. Having symmetry around an axis: an axisymmetric cone. ax , radial flow where the fluid properties depend on the radius r only, is of the form: [partial derivative]([rho]C)/[partial derivative]t + 1/r [partial derivative]/[partial derivative]r (r [rho] [u.sub.r]C) = 1/r [partial derivative]/[partial derivative]r(r [k.sub.r] [partial derivative]C/[partial derivative]) (2) where [u.sub.r] is the intersticial velocity and [rho] is the fluid density. It is clear that Equation (26) is similar to Equation (27) with [u.sub.r] = u/[phi] and [rho] = 1. Using Equation (7), we can check that the continuity equation [partial derivative][rho]/[partial derivative]t + 1/r [partial derivative]/[partial derivative]r (r [u.sub.r]) = 0 is automatically satisfied. We re-write Equation (26) as follows: [partial derivative]C/[partial derivative]t + 1/r [partial derivative]/[partial derivative]r(r u/[phi] C - r [k.sub.r] [partial derivative]C/[partial derivative]r) = 0 (28) We denote de·note tr.v. de·not·ed, de·not·ing, de·notes 1. To mark; indicate: a frown that denoted increasing impatience. 2. [J.sub.r] = r u/[phi] C - r [k.sub.r] [partial derivative]C/[partial derivative]r. The variable [J.sub.r] denotes the radial flux per unit of circumferential circumferential /cir·cum·fer·en·tial/ (-fer-en´shal) pertaining to a circumference; encircling; peripheral. angle. It includes both the convective and diffusive dif·fu·sive adj. Characterized by diffusion. dif·fu sive·ly adv.dif·fu fluxes. Using [J.sub.r], Equation (28) can be re-written as follows: [partial derivative]C/[partial derivative]t + 1/r [partial derivative][J.sub.r]/[partial derivative]r = 0 (29) Since the flow is planar, axisymmetric and radial, and the fluid properties depend only on the radius r, we need only to consider a radial sector from r = [r.sup.*.sub.w] to r = [r.sup.*.sub.e] and spanning a small angle [DELTA][theta Theta A measure of the rate of decline in the value of an option due to the passage of time. Theta can also be referred to as the time decay on the value of an option. If everything is held constant, then the option will lose value as time moves closer to the maturity of the option. ]. A set of equally spaced N grid points are selected along the mid-line of the sector. Grid points 1 and N correspond to the nodes at r = [r.sup.*.sub.w] (the inner radius) and r = [r.sup.*.sub.e] (the outer radius), respectively. Grid points i such that N 1 < i < N correspond to the internal nodes. Control volumes are generated around each grid point. The first and last control volumes are the boundary control volumes. The remaining N-2 control volumes are the internal ones. A representative internal control volume, with center grid point P, is shown in Figure 1. The grid points E and W are the east and west neighbors, respectively, of the grid point P, in the radial direction. The grid points N and S are the north and south neighbors, respectively, of the grid point P, in the circumferential direction. The letters e, w, s and n represent the control volume faces. The control volume is assumed to be of unit thickness in the z-direction (out of the page). To obtain the discrete equations of the concentration C, we will integrate Equation (29) over the control volume shown in Figure 1 and over the time interval from time t to time t + [DELTA]t, with [DELTA]t being the integration time step. The values of C at time t, i.e. the old values of C, will be tagged with a superscript Any letter, digit or symbol that appears above the line. For example, 10 to the 9th power is written with the 9 in superscript (109). Contrast with subscript. 0. The values of C at time t + [DELTA]t, i.e. the new values of C, will be tagged with a superscript 1. Integrating Equation (29), we obtain the following expression: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (30) To carry out the integration in Equation (30), we assume that at any time t, the concentration C at P, [C.sub.P], prevails throughout the control volume. Therefore, Equation (30) is re-arranged as follows: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (31) [FIGURE 1 OMITTED] where [DELTA]r = [r.sub.e] - [r.sub.w] and [DELTA][theta] = [[theta].sub.n] - [[theta].sub.s]. In conformity with the fully implicit scheme, we assume that the value [C.sup.1.sub.P] prevails throughout the control volume over the entire time step [DELTA]t. Similar assumptions are also made for the neighbor control volumes. Equation (31) can hence be re-written as follows: [MATHEMATICAL EXPRESSION NOT REPRODUCIBLE IN ASCII] (32) where [J.sup.1.sub.e] = [J.sup.1.sub.r] (r = [r.sub.e]) and [J.sup.1.sub.w] = [J.sup.1.sub.r] (r = [r.sub.w]) are the total fluxes of the concentration per unit of circumferential angle, at time t + [DELTA]t, at the east and west faces of the control volume, respectively. Substituting Equation (31) and Equation (32) into Equation (30) and dividing by [DELTA][theta] [DELTA]t, we obtain the following: ([C.sup.1.sub.P] - [C.sup.0.sub.P) [r.sub.P] [DELTA]r/[DELTA]t + [J.sup.1.sub.e] - [J.sup.1.sub.w] 0 (33) From here on, we omit o·mit tr.v. o·mit·ted, o·mit·ting, o·mits 1. To fail to include or mention; leave out: omit a word. 2. a. To pass over; neglect. b. the superscript 1, i.e. variables without superscript refer to the corresponding values at the new time t + [DELTA]t. Equation (33) can be re-written as ([C.sub.P] - [C.sup.0.sub.P]) [r.sub.P] [DELTA]r/[DELTA]t + [J.sub.e] - [J.sub.w] = 0 (34) Applying the continuity equation, in the case of incompressible, planar, axisymmetric radial flow, for our control volume, we obtain the following: [r.sub.e] [DELTA][theta] [u.sub.e]/[phi] = [r.sub.w] [DELTA][theta] [u.sub.w]/[phi] (35) where [u.sub.e] = u(r = [r.sub.e]) and [u.sub.w] = u(r = [r.sub.w]). We define F = r v/[phi] and D = [k.sub.r] r/[DELTA]r . F indicates the strength of convection and D is a diffusion conductance term. [F.sub.e] and [D.sub.e] are the values of F and D at the east face of the control volume, respectively. [F.sub.w] and [D.sub.w] are the corresponding values at the west face of the control volume. Equation (35) can be re-written as [F.sub.e] = [F.sub.w] (36) Using Equation (36), Equation (34) can be re-written as ([C.sub.P] - [C.sup.0.sub.P]) [r.sub.P] [DELTA]r/[DELTA]t + ([J.sub.e] - [F.sub.e] [C.sub.P]) - ([J.sub.w] - [F.sub.w] [C.sub.P]) = 0 (37) The Patankar Peclet number [??] is given ad [??] = F/D F/D Flight Director F/D Focal Length to Diameter Ratio F/D Filter Demineralizer F/D Field of Drawing (engineering drawings) . Patankar [10] introduced [J.sup.*.sub.e] = [J.sub.e]/[D.sub.e] and [J.sup.*.sub.w] = [J.sub.w]/[D.sub.w]. Using these latter expressions, Equation (37) can be re-written as follows: ([C.sub.P] - [C.sup.0.sub.P]) [r.sub.P] [DELTA]r/[DELTA]t + ([J.sup.*.sub.e] - [[??].sub.e] [C.sub.P])[D.sub.e] - ([J.sup.*.sub.w] - [[??].sub.w] [C.sub.P])[D.sub.w] = 0 (38) Patankar [10] proved that for the uniaxial uniaxial /uni·ax·i·al/ (u?ne-ak´se-al) 1. having only one axis. 2. developing in an axial direction only. uniaxial 1. having only one axis. 2. developed in an axial direction only. case with constant conductance, at the face between two consecutive grid points i and i+1, the following relationship: [J.sup.*] = B x [C.sub.i] - A x [C.sub.i+l] (39) where A and B are dimensionless coefficients that are functions of the Peclet number [??]. The same result can be approximated fairly accurately to our case of radial flow provided that [DELTA]r/r is kept small enough. Patankar [10], also, proved that B = A + [??] (40) and A([??]) = A ([absolute value of [??]])+ Max (-[??], 0) (41) and B([??]) = A ([absolute value of [??]])+ Max ([??], 0) (42) Applying Equation (39) and Equation (40) to the east face of our control volume, i.e. nodes i and i+1 corresponding to the P and E grid points, respectively, we obtain the following: [J.sup.*.sub.e] - [[??].sub.e] [C.sub.P] = (A([[??].sub.e])+[[??].sub.e]) [C.sub.P] - A([[??].sub.e]) [C.sub.E] - [[??].sub.e] [C.sub.P] = A([[??].sub.e])([C.sub.P] - [C.sub.E]) (43) Similarly, Equations (39) and (40) are applied to the west face of the control volume, i.e. nodes i-1 and i corresponding to the W and P grid points, respectively. The following expression is obtained: [J.sup.*.sub.e] - [[??].sub.e] [C.sub.P] = (A([[??].sub.e])+[[??].sub.e]) [C.sub.P] - A([[??].sub.e]) [C.sub.E] - [[??].sub.e] [C.sub.P] = A([[??].sub.e])([C.sub.P] - [C.sub.E]) (43) By substituting Equation (43) and Equation (44) into Equation (38), Equation (38) is rearranged as follows: ([C.sub.P] - [C.sup.0.sub.P]) [r.sub.P] [DELTA]r/[DELTA]t + A([??].sub.e])[D.sub.e]([C.sub.P] - [C.sub.E]) - B([[??].sub.w] [D.sub.w] ([C.sub.w] - [C.sub.P]) = 0 (45) Using Equations (41), (42), and the definition of the Peclet number, we obtain: A([[??].sub.e])[D.sub.e] = (A([[absolute value of [??]].sub.e])+ Max(-[[??].sub.e],0))[D.sub.e] = A([[absolute value of [??]].sub.e])[D.sub.e] + Max(-[F.sub.e],0) (46) and B([[??].sub.w])[D.sub.w] = (A([[absolute value of [??]].sub.w])+ Max(-[[??].sub.w],0))[D.sub.w] = A([[absolute value of [??]].sub.w])[D.sub.w] + Max([F.sub.w],0) (47) Using Equations (46) and (47), Equation (45) can be re-arranged in the following general format: [a.sub.P] [C.sub.P] = [a.sub.E] [C.sub.E] + [a.sub.W] [C.sub.W] + b (48) where [a.sub.E] = (A([[absolute value of [??]].sub.e])[D.sub.e] + Max(-[F.sub.e],0) (49a) [a.sub.W] = (A([[absolute value of [??]].sub.w])[D.sub.w] + Max([F.sub.w],0) (49b) [a.sup.0.sub.P] = [r.sub.P] [[DELTA]r/[DELTA]t (49c) b = [C.sup.0.sub.P] [a.sup.0.sub.P] (49e) [a.sub.P] = [a.sub.E] + [a.sub.W] + [a.sup.0.sub.P] (49e) The choice of A([absolute value of [??]]) depends on the scheme to be used. [10] Our results are obtained using the Exponential (exact) scheme, given by: A([[absolute value of [??]]=[absolute value of [??]]/exp[absolute value of [??]]-1 (50) A total of N-2 linear, algebraic equations of type Equation (48) are generated for the N-2 internal nodes. The remaining 2 equations are obtained from the boundary conditions. The boundary condition at r = [r.sup.*.sub.w] is given by Equation (5) and implies the following: (1 + [alpha]/dr)[C.sub.1] - a/dr [C.sub.2] = 1 (51a) and the boundary condition at r = [r.sup.*.sub.e] gives [C.sub.N] = 0 (51b) Equations (48), (51a) and (51b) constitute a system of N linear, algebraic equations and N unknown C values corresponding to the concentrations at the present time (the old values of C are assumed known). This system of equations is solved using the TriDiagonal Matrix Algorithm The tridiagonal matrix algorithm (TDMA), also known as the Thomas algorithm, is a simplified form of Gaussian elimination that can be used to solve tridiagonal systems of equations. A tridiagonal system may be written as The procedure described above allows the calculation of the concentration solution at time t + [DELTA]t given the concentration solution at time t . Starting from the known concentration values at time t = 0, i.e. [C.sub.i] = 0, for 1 [less than or equal to] i [less than or equal to] N, the concentration solution is obtained at time t = [DELTA]t. Next, the concentration solution is computed at t = 2 [DELTA]t, using the concentration solution at time t = [DELTA]t. The procedure can be repeated till the desired final time is reached. [FIGURE 2 OMITTED] Discussion Profiles of concentration of injected miscible fluid are presented as a function of dimensionless time and radius in Figures 2 through 10. The space domain has been divided into 600 increments whereas the time step was updated every one second. A time step less than one second, and a discretization of the space domain in more than 600 increments did not change the concentration profiles. [FIGURE 3 OMITTED] [FIGURE 4 OMITTED] Figure 2 shows the profiles of concentration versus radius for early, intermediate, and late times. At an early time, the dimensionless concentration at the wellbore face is much less than unity. At an intermediate time this concentration increases progressively to a value of one. At late times, the displacement front is well established and keeps moving to the reservoir external boundary with a degree of smearing that increases with increasing radius. This front dissipation Dissipation See also Debauchery. Breitmann, Hans lax indulger. [Am. Lit.: Hans Breitmann’s Ballads] Burley, John wasteful ne’er-do-well. [Br. Lit. is more visible in Figure 3. At a fixed time, closer radii to the wellbore face have a sharper front than those radii farther away in the direction of the reservoir boundary. [FIGURE 5 OMITTED] [FIGURE 6 OMITTED] In line with expectation, the rate of change of concentration with time decreases as the dimensionless radius value increases (Figure 3). Figure 4 illustrates the effect of dispersivity ([??]) on the concentration profile at a fixed radius value. At a fixed time value, the higher the value of dispersivity, the more mixing takes place, and hence the greater the concentration of the miscible fluid becomes. Figure 5 reveals the effect of this mixing on the displacement front. A higher dispersivity value aggravates the dissolution of the slug at the toe of the concentration profile, but gives rise to a larger concentration at the tail. [FIGURE 7 OMITTED] [FIGURE 8 OMITTED] [FIGURE 9 OMITTED] [FIGURE 10 OMITTED] Figure 6 displays the effect of porosity on the concentration profile. The smaller the porosity value is, the larger the rate of change of concentration. This is expected since a smaller value of porosity acts like a choke on the porous medium and results therefore on a greater degree of convective mixing than diffusion mixing. This concept is even reasserted in Figure 7 that shows a snapshot of the displacement front behavior. The smaller the value of porosity is, the steeper the displacement front becomes. Figures 8 and 9 display the effect of volumetric flow rate In fluid dynamics and hydrometry, the volumetric flow rate, also volume flow rate and rate of fluid flow, is the volume of fluid which passes through a given surface per unit time (for example cubic meters per second [m3 s-1 on the concentration history and profile, respectively. The higher the injection rate value is, the faster the buildup build·up also build-up n. 1. The act or process of amassing or increasing: a military buildup; a buildup of tension during the strike. 2. of the displacement front is. This observation indicates that the influence of velocity induced dispersion is more important for large rate values for this homogeneous isotropic Refers to properties that do not differ no matter which direction is measured. For example, an isotropic antenna radiates almost the same power in all directions. In practice, antennas cannot be 100% isotropic. porous medium, in line with expectation. The effect of tortuosity on the front history is displayed in Figure 10.. [FIGURE 11 OMITTED] [FIGURE 12 OMITTED] Low tortuosity values can have a slight stabilizing influence on the displacement. At a relatively low injection rate, the tortuosity value did not appear to influence the rate of change of concentration, though [FIGURE 13 OMITTED] [FIGURE 14 OMITTED] Figures 11 through 14 display plots of the dimensionless mixing zone as a function of the square root of time. The plots vary the dispersivity, injection rate, porosity, and the tortuosity values, respectively. These Figures show that the dispersive mixing zone does not necessarily grow in proportion with the square root of time for all times, unlike the linear displacement. These results reveal a typical minimum of the dispersive mixing zone with time for radial displacement. It appears that at some radial distance close to the wellbbore, the dimensionless mixing zone decreases with the square root of time since there is an accumulation of the miscible slug in this particular space domain. [FIGURE 15 OMITTED] [FIGURE 16 OMITTED] However, when the dissolution of the slug starts taking effect, particularly at large distances away from the injection point, the mixing zone begins to increase with increasing square root of time. This result may be inferred from a plot of dispersive mixing zone as a function of the average Peclet number (Figure 15). At an early time, the dispersive mixing zone displays a minimum locus. However, at late times there is an apparent monotonic monotonic - In domain theory, a function f : D -> C is monotonic (or monotone) if for all x,y in D, x <= y => f(x) <= f(y). ("<=" is written in LaTeX as \sqsubseteq). increase of the dispersive mixing zone. The latter result is consistent with an increasing growth rate of instability with increasing Peclet number. These results indicate that the optimal slug size of miscible displacement is time-dependent. [FIGURE 16b OMITTED] [FIGURE 16c OMITTED] [FIGURE 16d OMITTED] Figures 16a through 16d display a comparison between the solution of the model presented in this study and Tang and Peaceman [5] solution. At relatively high injection rate (0.1 [m.sup.3]/sec to 0.01 [m.sup.3]/sec) there is a reasonable agreement between the two solutions. However, as the injection rate decreases (from 0.01 [m.sup.3]/sec to 0.0001 [m.sup.3]/sec) the disparity between the two solutions increases. This is not a surprising result since the dispersion coefficient, in Tang and Peaceman model, is only a function of velocity and does not account for diffusion effects; Whereas, in the model presented in this study, the dispersion coefficient accounts for diffusion as well. At relatively low flow rates, the mixing between the insitu crude and solvent become diffusion dominated, a fact that aggravates the disparity between our solution and Tang and Peaceman solution. Conclusions The finite-control volume technique is used for optimizing the accuracy of the numerical solution to the convection-dispersion equation in radial coordinates. This technique is favored because it is known to eliminate the detrimental effects of numerical dispersion. The convection-dispersion equation arises in the simulation of Enhanced Oil Recovery Enhanced Oil Recovery (EOR) is a generic term for techniques for increasing the amount of oil that can be extracted from an oil field. Using EOR, 30-60 %, or more, of the reservoir's original oil can be extracted [1] compared with 20-40% [2] (EOR EOR - exclusive or ) processes where front smearing resulting from numerical dispersion can distort the behavior of the miscible displacement process. This front smearing can, for instance, lead to false predictions of breakthrough times. Our solution should allow to better estimate the optimum slug size for miscible displacement projects in hydrocarbon reservoirs. This in return allows a better estimate of the total amount of solvent needed to maintain miscibility conditions at the displacement front in the bulk of the reservoir, leading to better reservoir management and to a more adequate economic forecast of EOR processes. The optimal slug size appears to be time-dependent. The profile of dimensionless mixing zone versus the square root of dimensionless time displays a minimum locus. This result appears to be unique for radial displacement. Acknowledgments This work was supported by Kuwait University Despite this dramatic increase, the fiscal year 1998/1999 decreased by about 10.5 million Kuwaiti Dinars by the fiscal year 1999/2000, ensuring the preservation of the university's resources. Future Plans Kuwait University has just planned a new 10 year project. Research Grant No. [EP01/05]. References [1] Lake, L.W., 1989, Enhanced Oil Recovery, Prentice Hall Prentice Hall is a leading educational publisher. It is an imprint of Pearson Education, Inc., based in Upper Saddle River, New Jersey, USA. Prentice Hall publishes print and digital content for the 6-12 and higher education market. History In 1913, law professor Dr. : Englewood Cliffs, New Jersey Englewood Cliffs is a borough in Bergen County, New Jersey, United States. As of the United States 2000 Census, the borough population was 5,322. The borough houses the world headquarters of CNBC and the American headquarters of Unilever. . [2] Chase, C.A., 1971, "Finite-Element Analysis of Single Well Backflow backflow /back·flow/ (-flo) reflux or regurgitation (1). pyelovenous backflow drainage from the renal pelvis into the venous system occurring under certain conditions of back pressure. Tracer Test in a Homogeneous Reservoir," SPE SPE - Software Practice and Experience Annual Meeting, New Orleans New Orleans (ôr`lēənz –lənz, ôrlēnz`), city (2006 pop. 187,525), coextensive with Orleans parish, SE La., between the Mississippi River and Lake Pontchartrain, 107 mi (172 km) by water from the river mouth; founded , October 1971; Paper 3485. [3] Peaceman, D.W., 1977, Fundamentals of Numerical Reservoir Simulation Reservoir simulation is an area of reservoir engineering in which computer models are used to predict the flow of fluids (typically, oil, water, and gas) through porous media. , Elsevier Scientific Publishing Company, New York New York, state, United States New York, Middle Atlantic state of the United States. It is bordered by Vermont, Massachusetts, Connecticut, and the Atlantic Ocean (E), New Jersey and Pennsylvania (S), Lakes Erie and Ontario and the Canadian province of . [4] Settari, A., and Price, H.S., 1977, "Development and Application of Variational Methods for Simulation of Miscible Displacement in Porous Media," SPE Journal, June issue, p. 228. [5] Tang, D.H.E., and Peaceman, D.W., 1987, "New Analytical and Numerical Solutions for the Radial Convection-Dispersion Problem," SPE Reservoir Engineering Reservoir engineering is a branch of petroleum engineering, typically concerned with maximizing the economic recovery of hydrocarbons from the subsurface. Of particular interest to reservoir engineers is generating accurate reserves estimates for use in financial reporting , August Issue, p. 343. [6] Tan, C.T., and Homsy, G.M., 1987, "Stability of Miscible Displacement in Porous Media: Radial Source Flow," Phys. Fluids, 30, p. 1239. [7] Pankiewitz, C., and Meiburg, E., 1999, "Miscible Porous Media Displacements in the Quarter Five-Spot Configuration. Part 3. Non-Monotonic Viscosity Profiles," Journal of Fluid Mechanics The Journal of Fluid Mechanics is a leading scientific journal in the field of fluid mechanics. It publishes original work on theoretical, computational and experimental aspects of the subject. , 388, p.171. [8] Riaz, A., and Meiburg, E. Radial Source Flows in Porous Media: Linear Stability Analysis of Axial and Helical Perturbations in Miscible Displacements. Phys. Fluids 2003, 15, 938. [9] Yortsos, Y.C. Stability of Displacement Processes in Porous Media in Radial Flow Geometries. Phys. Fluids 1987, 30, 2928. [10] Patankar, S.V. Numerical Heat Transfer and Fluid Flow, Taylor and Francis, 1980. [11] Peters, E .J, Gharbi, R., and Afzal, N. A Look at Dispersion in Porous Media Through Computed Tomography Computed tomography (CT scan) X rays are aimed at slices of the body (by rotating equipment) and results are assembled with a computer to give a three-dimensional picture of a structure. Imaging. Journal of Petroleum Science and Engineering 1996, 15, 23. [12] Garrouch, A.A., Ali, L., and Qasem, F. Using Diffusion and Electrical Measurements Electrical measurements Measurements of the many quantities by which the behavior of electricity is characterized. Measurements of electrical quantities extend over a wide dynamic range and frequencies ranging from 0 to 1012 Hz. to Assess Tortuosity of Porous Media. Industrial Engineering and Chemistry Research Journal 2001, 40, 4363. A. A. Garrouch Petroleum Engineering Department, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait M. M. Al-Dousari Petroleum Engineering Department, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait
Nomenclature
A dimensionless coefficient
B dimensionless coefficient
C concentration
[C.sub.D] dimensionless concentration
[C.sub.I] initial concentration
[C.sub.J] injected concentration
[C.sub.P] concentration C at point P
dA surface element
[D.sub.e] diffusion conductance value at the east face of the
control volume
[D.sub.m] molecular diffusion coefficient
[F.sup.*] resistivity formation factor
[F.sub.e] convection strength value at the east face of the
control volume
H reservoir thickness
[J.sub.r] radial flux per unit of circumferential angle
i volumetric injection rate
K dispersion coefficient
[K.sub.r] radial dispersion coefficient
[K.sub.re] dispersion coefficients at [r.sup.*.sub.e]
[K.sub.rw] dispersion coefficients at [r.sup.*.sub.w]
N number of grid points
[n.sub.i] unit vector normal to the surface element dA
[NL.sub.pe] local Peclet number
[N.sub.pe] average Peclet number
[N.sub.R] local non-dimensional rate of change of radial
dispersion coefficient with respect to radius
[[bar.N].sub.R] average non-dimensional rate of change of radial
dispersion coefficient with respect to radius
P Patankar definition of Peclet number
r radius
[r.sub.D] dimensionless radius
[r.sub.P] radius at P
[r.sup.*.sub.e] drainage radius
[r.sup.*.sub.w] wellbore radius
S' source term
t time
[t.sub.D] dimensionless time
u superficial velocity
[u.sub.e] superficial velocity value at the east face of the
control volume
[u.sub.r] interstitial velocity
[u.sub.w] superficial velocity value at the west face of the
control volume V three-dimensional control volume
[V.sub.P] pore volume
Greeck Symbols
[??] dispersivity
[phi] porosity
[??] general quantity
[GAMMA] diffusion coefficient
[??] angle
[rho] fluid density
Subscripts
e, w, n, s east, west, north and south face of the control
volume
p at point P.
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ra·pher n.
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