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A nanoscale coating reflects almost no light.


The velvet background on a painting of Elvis looks black because it reflects so little light. But getting a surface to reflect no light at all is surprisingly difficult. Now, researchers have created a virtually reflectionfree surface by coating it with filaments only a few billionths of a meter thick.

Improved antireflective surfaces might have many uses. For example, they could eliminate light-wasting reflections in fiber-optic telecommunications, or the surfaces could brighten low-power light-emitting diode (LED) lamps.

Applied to a clear surface, the coating would make alens absorb more light, increasing its transparency. On an opaque surface, the filaments would make a silicon solar cell solar cell, semiconductor devised to convert light to electric current. It is a specially constructed diode, usually made of silicon crystal. When light strikes the exposed active surface, it knocks electrons loose from their sites in the crystal. , for example, almost perfectly absorbing.

The coating creates "really a new class of materials,' says E. Fred Schubert, a member of the research team at Rensselaer Polytechnic Institute Rensselaer Polytechnic Institute, at Troy, N.Y.; coeducational; founded and opened 1824 as Rensselaer School; chartered 1826. It was called Rensselaer Institute from 1837 to 1861.  in Troy, N.Y.

Schubert and his colleagues set out to minimize light's reflections. Light rebounds when it strikes the boundary between two materials that have different "refractive indices Many materials have a well-characterized refractive index, but these indices depend strongly upon the frequency of light. Therefore, any numeric value for the index is meaningless unless the associated frequency is specified. "--measures of how fast light travels through the substances. For example, sunlight bounces off the surface of a pond because light travels more slowly in water than in air. The greater the difference between the refractive indices of any two materials, the more light is reflected.

To prevent reflections, the team put a transparent piece of aluminum nitride nitride

Any of a class of chemical compounds in which nitrogen is combined with an element of similar or lower electronegativity, such as boron, silicon, and most metals. Some examples of nitrides include boron nitride, calcium nitride, aluminum nitride, and cyanogen.
 in a vacuum and coated the surface with five layers of nanoscale At nanometer size. Any device only a few nanometers in size is nanoscale. See nanotechnology and nanometer.  filaments made either of silicon dioxide silicon dioxide: see silica.


(SiO2) A hard, glassy mineral found in such materials as rock, quartz, sand and opal. In MOS chip fabrication, it is used to create the insulation layer between the metal gates of the top layer and the silicon elements below.
 or titanium dioxide. Each layer resembles a rug with the yarns leaning at 450. Together, the five layers are only about 700 nanometers thick--the wavelength of red light. The individual filaments are 20 to 30 nm wide, the team reports in the March Nature Photonics Nature Photonics, published by the Nature Publishing Group (NPG), is a scientific journal publishing high-quality original research related to optoelectronics, laser science, imaging, communications and other areas of photonics. The journal was launched in January 2007. .

By altering the spacing between the filaments, the scientists gave each layer a slightly different refractive index A property of a material that changes the speed of light, computed as the ratio of the speed of light in a vacuum to the speed of light through the material. When light travels at an angle between two different materials, their refractive indices determine the angle of transmission . The top layer has so much space between filaments that its refractive index is nearly the same as that of air. The filaments in the other four layers are progressively denser, so the layers have increasing refractive indices. The bottom layer's index of 2.15 is the same as that of the underlying surface.

This staggered transition replaces an abrupt boundary with gradual ones, greatly reducing the reflection of light. At its surface, the coating has a refractive index of 1.05, which is dose to air's index of 1.0. Even transparent solids such as glass have indices of at least 1.4.

The low-reflection coating works for Visible light and all other wavelengths between near ultraviolet and near infrared.

"It certainly is an improvement over the existing state of the art," comments Sri Sridhar, who studies nanophotonies at Northeastern University Northeastern University, at Boston, Mass.; coeducational; founded 1898 as a program within the Boston YMCA, inc. 1916, university status 1922, fully independent of the YMCA 1948.  in Boston.

The current coating has a faint blue tinge, however. Schubert says that this results from diffraction, not reflection. He explains that the thickness of the layers happens to equal the wavelength of the blue light. His team is currently making the layers thinner to avoid this problem.
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Title Annotation:The New Black
Author:Barry, P.
Publication:Science News
Date:Mar 3, 2007
Words:491
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